Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes

Merve Akbayrak; Ümran Ata; Tuğba Nur Aslan

EN TR

Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes

Öz

Zinc doped Silver Nanoparticles (Zn doped Ag NPs) were synthesized in this study to improve catalytic efficiency of Ag NPs. A controlled green synthesis was achieved with Polygonum cognatum extract by systematically varying zinc doping ratio (bare Ag NP, 1.6% Zn-doped Ag NP, and 9.0% Zn-doped Ag NP). Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES), Scanning Transmission Electron Microscopy (STEM), Energy Dispersive X-ray Spectroscopy (EDS), X-ray Fluorescence (XRF), X-ray Diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR) analyses verified the NP formation, its elemental content, crystal structure and successful incorporation of Zn into the Ag NP matrix. The catalytic activity of green synthesized Zn doped Ag NPs was investigated in the degradation of methyl orange (MO) and methylene blue (MB) using sodium borohydride (NaBH4) as a reducing agent. According to results, Zn doped Ag NPs exhibited superior catalytic performance compared to bare Ag NPs. The results indicate that the 9.0% Zn-doped Ag NP degraded MO 96.56% in 15 minutes at a rate constant (kapp) of 0.2199 min⁻¹ and turnover frequency (TOF) of 1.65 x 10⁻³ mol.g⁻¹ min⁻¹. In MB degradation, it reached 98.38% in 10 minutes with a kapp of 0.4445 min⁻1 and a TOF of 2.54 x 10-3 mol.g-1 min-1. For both dyes, increasing the doping amount of Zn from 1.6% to 9.0% greatly shortened reaction times and improved degradation efficiency. 9.0% Zn doped Ag NPs were found highly effective catalysts for the rapid and efficient degradation of toxic organic dyes. The findings of this study provide valuable insights into the tunability of silver nanoparticles’ activity through zinc doping, which will enable the development of more effective and customizable catalytic materials for environmental treatment and other applications.

Anahtar Kelimeler

Metyl Orange, Metylene Blue, Nanoparticles, Silver, Zinc

Gümüş Nanoparçacıklarına Çinko Katkılanmasının Toksik Organik Boyaların Bozunmasının Artırılmasına Etkilerinin İncelenmesi

Öz

Bu çalışmada, gümüş nanoparçacıkların katalitik verimliliğini artırmak amacıyla, Çinko katkılı Gümüş Nanoparçacıklar (Zn katkılı Ag NP'ler) sentezlenmiştir. Polygonum cognatum özütü ile çinko katkılama oranı sistematik olarak değiştirilerek (çıplak Ag NP, %1,6 Zn katkılı Ag NP ve %9,0 Zn katkılı Ag NP) kontrollü bir yeşil sentez yapılmıştır. Endüktif Eşleşmiş Plazma Optik Emisyon Spektroskopisi (ICP-OES), Taramalı Geçirimli Elektron Mikroskopisi (STEM), Enerji Dağılımlı X-Işını Spektroskopisi (EDS), X-ışını Floresansı (XRF), X-ışını Kırınımı (XRD) ve Fourier Dönüşümlü Kızılötesi Spektroskopisi (FTIR) analizleri, NP’lerin oluşumunu, elemental içeriğini, kristal yapısını ve Zn'nin Ag NP matrisine etkili bir şekilde dahil edildiğini doğrulamıştır. Yeşil sentezlenmiş Zn katkılı Ag NP'lerin, indirgeyici ajan olarak sodyum borohidrür (NaBH4) çözeltisi kullanılarak metil turuncusunun (MO) ve metilen mavisinin (MB) bozunmasındaki katalitik aktiviteleri araştırılmıştır. Sonuçlara göre, Zn katkılı Ag NP'ler çıplak Ag NP'lere kıyasla üstün katalitik performans sergilemiştir. Sonuçlar, %9,0 Zn katkılı Ag NP'nin MO'yu 15 dakika içinde 0,2199 dk-1 hız sabiti (kapp) ve 1,65 x 10-3 mol.g-1 dk-1 devir frekansı (TOF) ile %96,56 oranında parçaladığını göstermektedir. MB degradasyonunda parçalama yüzdesi, 0,4445 dk-1 kapp ve 2,54 x 10-3 mol.g-1dk-1 TOF ile 10 dakikada %98,38'e, ulaşmıştır. Her iki boya için de Zn katkılama miktarının %1,6'dan %9,0'a çıkarılması reaksiyon sürelerini büyük ölçüde kısaltmış ve bozunma verimliliğini artırmıştır. 9.0 % Zn katkılı Ag NP'lerin toksik organik boyaların hızlı ve verimli bir şekilde bozunması için oldukça etkili katalizörler olduğu bulunmuştur. Bu çalışmanın bulguları, çevresel arıtma ve diğer uygulamalar için daha etkili ve özelleştirilebilir katalitik malzemelerin geliştirilmesini sağlayacak olan çinko katkılama yoluyla gümüş nanopartiküllerin etkinliğinin ayarlanabilirliği hakkında değerli bilgiler sağlamaktadır.

Anahtar Kelimeler

Çinko, Gümüş, Metil Turuncusu, Metilen Mavisi, Nanoparçacık

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Elektroanalitik Kimya, Kataliz ve Reaksiyon Mekanizmaları, İnorganik Yeşil Kimya, Nanokimya

Bölüm

Araştırma Makalesi

Yazarlar

Merve Akbayrak
0000-0003-3283-2146
Türkiye

Ümran Ata
0000-0002-1071-6059
Türkiye

Tuğba Nur Aslan ^*
0000-0002-5516-3603
Türkiye

Erken Görünüm Tarihi

12 Ocak 2025

Yayımlanma Tarihi

30 Nisan 2025

Gönderilme Tarihi

8 Mayıs 2024

Kabul Tarihi

2 Ekim 2024

Yayımlandığı Sayı

Yıl 2025 Cilt: 7 Sayı: 1

IZ

https://izlik.org/JA98CW84FD

APA

Akbayrak, M., Ata, Ü., & Aslan, T. N. (2025). Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes. Necmettin Erbakan University Journal of Science and Engineering, 7(1), 56-76. https://izlik.org/JA98CW84FD

AMA

1.Akbayrak M, Ata Ü, Aslan TN. Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes. NEU Fen Muh Bil Der. 2025;7(1):56-76. https://izlik.org/JA98CW84FD

Chicago

Akbayrak, Merve, Ümran Ata, ve Tuğba Nur Aslan. 2025. “Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes”. Necmettin Erbakan University Journal of Science and Engineering 7 (1): 56-76. https://izlik.org/JA98CW84FD.

EndNote

Akbayrak M, Ata Ü, Aslan TN (01 Nisan 2025) Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes. Necmettin Erbakan University Journal of Science and Engineering 7 1 56–76.

IEEE

[1]M. Akbayrak, Ü. Ata, ve T. N. Aslan, “Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes”, NEU Fen Muh Bil Der, c. 7, sy 1, ss. 56–76, Nis. 2025, [çevrimiçi]. Erişim adresi: https://izlik.org/JA98CW84FD

ISNAD

Akbayrak, Merve - Ata, Ümran - Aslan, Tuğba Nur. “Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes”. Necmettin Erbakan University Journal of Science and Engineering 7/1 (01 Nisan 2025): 56-76. https://izlik.org/JA98CW84FD.

JAMA

1.Akbayrak M, Ata Ü, Aslan TN. Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes. NEU Fen Muh Bil Der. 2025;7:56–76.

MLA

Akbayrak, Merve, vd. “Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes”. Necmettin Erbakan University Journal of Science and Engineering, c. 7, sy 1, Nisan 2025, ss. 56-76, https://izlik.org/JA98CW84FD.

Vancouver

1.Merve Akbayrak, Ümran Ata, Tuğba Nur Aslan. Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes. NEU Fen Muh Bil Der [Internet]. 01 Nisan 2025;7(1):56-7. Erişim adresi: https://izlik.org/JA98CW84FD

Influence of Zinc Doping Ratio on Silver Nanoparticles Synthesized via Green Method for Enhanced Catalytic Degradation of Toxic Organic Dyes

Öz

Anahtar Kelimeler

Gümüş Nanoparçacıklarına Çinko Katkılanmasının Toksik Organik Boyaların Bozunmasının Artırılmasına Etkilerinin İncelenmesi

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Erken Görünüm Tarihi

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

IZ

Kaynak Göster