The Synthesis of Novel Heterocyclic Schiff Bases Microwave Assisted and Investigation of Saldeta/Salpyr Metal Complexes
Öz
2-(4-aminophenyl)-1H-benzimidazole obtained from literature studies was used as the outlet agent. The resulting compound reacted with Gentisaldehyde to get 2-(((4-(1H-benzoimidazoleyl)phenyl)imino)methyl)benzene-1,4-diol (25SAPBZ). Oxygen-bridging complexes were obtained by adding the [Fe(saldeta/salpyr)Cl] complex dissolved in ethanol to the (25SAPBZ) ligand. FTIR, elemental analyses, 1H/13C-NMR and FTIR of complex structures, elemental analyses, and magnetic susceptibility measurements of the obtained ligands were elucidated.
Anahtar Kelimeler
Kaynakça
- Z.E. Koç, Complexes of iron(III) and chromium(III) salen and salophen Schiff bases with bridging 1,3,5‐triazine derived multidirectional ligands, Journal of Heterocyclic Chemistry. 48 (2011), 769–775. doi:10.1002/jhet.577
- N.N. Makhova, L.I. Belen’kii, G.A. Gazieva, I.L. Dalinger, L.S. Konstantinova, V.V. Kuznetsov, A.N. Kravchenko, M.M. Krayushkin, O.A. Rakitin, A.M. Starosotnikov, L.L. Fershtat, S.A. Shevelev, V.Z. Shirinian, V.N. Yarovenko, Progress in the chemistry of nitrogen-, oxygen- and sulfur-containing heterocyclic systems, Russian Chemical Reviews. 89 (2019), 55–124. doi:10.1070/rcr4914
- P. Arora, V. Arora, H. Lamba, D. Wadhwa, Importance of heterocyclic chemistry: A review, International Journal of Pharmaceutical Sciences and Research. 2012 (2012). doi:10.13040/ijpsr.0975-8232.3(9).2947-54
- S.C. Celik, H. Vatansev, Z.E. Koc, Benzimidazole Schiff bases microwave assisted synthesis and the effect on leukemia cells with flow cytometry, Revue Roumaine De Chimie. 64 (2019) 615–623. doi:10.33224/rrch/2019.64.7.08
- C. Arslaner, S. Karakurt, Z.E. Koc, Synthesis of benzimidazole Schiff base derivatives and cytotoxic effects on colon and cervix cancer cell lines, Biointerface Research in Applied Chemistry. 7(4) (2017), 2103-2107
- Z.E. Koc, H. Bingol, A.O. Saf, E. Torlak, A. Coskun, Synthesis of novel tripodal-benzimidazole from 2,4,6-tris(p-formylphenoxy)-1,3,5-triazine: Structural, electrochemical and antimicrobial studies, Journal of Hazardous Materials. 183 (2010), 251–255. doi:10.1016/j.jhazmat.2010.07.018
- F. Jian, P. Zhao, Y. Li, X. Wang, Q. Yu, A combined computational and experimental approach for investigating a hydrogen‐bonded supermolecular compound comprising benzimidazole and malonic acid, International Journal of Quantum Chemistry. 108 (2007), 521–531. doi:10.1002/qua.21511
- Y. Wei, Y. Yu, K. Wu, Highly Stable Five-Coordinated Mn(II) polymer [Mn(Hbidc)]n (Hbidc=1H-Benzimidazole-5,6-dicarboxylate): Crystal structure, antiferromegnetic property, and strong long-lived luminescence, Crystal Growth & Design. 8 (2008), 2087–2089. doi:10.1021/cg800333g
- Ş. Uysal, Z.E. Koç, Synthesis and characterization of dendrimeric melamine cored [salen/salophFe(III)] and [salen/salophCr(III)] capped complexes and their magnetic behaviors, Journal of Hazardous Materials. 175 (2009), 532–539. doi:10.1016/j.jhazmat.2009.10.038
- M.A. Phillips, The formation of 2-substituted benziminazoles, Journal of the Chemical Society. (1928), 2393–2399. doi:10.1039/jr9280002393