Preparation of Sodium Carboxymethly Cellulose Hydrogel for Controlled Release of Manganese Micronutrient

Öz

In order to use potential in the development of wheatgrass plant (Triticum Aestivum), carboxymethyl cellulose sodium salt (NaCMC) hydrogels were prepared. The characterization of synthesized hydrogels was examined. Water absorbency and gel content properties were influenced the amount of crosslinker in hydrogels. The water absorbency was negatively affected with crosslinker on the contrary gel content. The application of hydrogels improved the water retention capacity of soil. The manganese release was examined in water and soil and the release slowed down with crosslinker. Manganese-loaded hydrogels were used for growing the wheatgrass plant. The growing of plant was positively affected with using manganese-loaded hydrogels. These results suggest that manganese-loaded hydrogels could be utilized as a controlled fertilizer system in agriculture areas.

Anahtar Kelimeler

• sodium carboxymethyl cellulose
• manganese
• micronutrient
• hydrogel
• wheatgrass

Kontrollü Mangan Mikro Besin Elementi Salımı için Sodyum Karboksimetil Selüloz Hidrojelinin Hazırlanması

Öz

Sodyum karboksimetil selüloz (NaCMC) hidrojelleri, buğday çimi bitkisinin (Triticum Aestivum) büyümesinde potansiyel kullanım için hazırlandı. Su absorpsiyon ve jel içeriği (yüzdesi) özellikleri test edildi. Jel içeriği sonuçlarının aksine çapraz bağlayıcı içeriğinin arttırılmasıyla su absorpsiyonu azaltılmıştır. Hidrojellerin toprak uygulaması, toprağın su tutma kapasitesini arttırdı. Su ve toprakta hidrojellerin mangan salım davranışı incelendi ve salım değerleri çapraz bağlanma yoğunluğu ile azaldı. Mangan yüklü hidrojelin buğday çimi bitkisinin performansı üzerindeki etkisi de saksı deneyleri yapılarak incelenmiştir. Buğday çimi büyümesi, mangan yüklü hidrojellerin kullanılmasıyla belirgin olarak artmıştır. Hidrojellerin kullanılmasıyla bitki performansındaki artış, hazırlanan hidrojellerin tarım alanlarında kontrollü bir gübre sistemi olarak kullanılabileceğini göstermektedir.

Anahtar Kelimeler

• Sodyum karboksimetil selüloz
• mangan
• mikrobesin elementi
• hidrojel
• buğday çimi

Kaynakça

1. Referans1 Akalin G.O., Pulat M., “Preparation and characterization of κ-carrageenan hydrogel for controlled release of copper and manganese micronutrients” Polymer Bulletin, doi: 10.1007/s00289-019-02800-4, 17 pages, 2019.
2. Referans2 Jia X., Ma Z., Zhang G., Hu J., Liu Z., Wang H., Zhou F., “Polydopamine film coated controlled-release multielement compound fertilizer based on mussel-ınspired chemistry” Journal of Agricultural and Food Chemistry, 61, 2919−2924, 2013.
3. Referans3 Melaj M.A., Daraio M.E., “Preparation and characterization of potassium nitrate controlled-release fertilizers based on chitosan and xanthan layered tablets” Journal of Applied Polymer Science, 2422-2428, 2012.
4. Referans4 Ni B. Liu M., Lü S., “Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations” Chemical Engineering Journal, 155, 892–898, 2009.
5. Referans5 Raju K.M., Raju M.P., Mohan Y.M., “Synthesis of superabsorbent copolymers as water manageable materials” Polymer International, 52,768–772, 2003.
6. Referans6 Akalin G.O., Pulat M., “Preparation and characterization of nanoporous sodium carboxymethyl cellulose hydrogel beads” Journal of Nanomaterials, Article ID 9676949, 12 pages, 2018.
7. Referans7 Davidson D.W., Verma M.S., Gu F.X., “Controlled root targeted delivery of fertilizer using an ionically crosslinked carboxymethyl cellulose hydrogel matrix” SpringerPlus, 2(1),318-327, 2013.
8. Referans8 Shauk S.A., Qidwai A., Anwar F., Ullah I., Rashid U., “Effects of a novel poly (AA-co-AAM)/alznfe2o4/potassium humate superabsorbent hydrogel nanocomposite on water retention of sandy loam soil and wheat seedling growth” Molecules, 17,12587-12602, 2012.

9. Referans9 Albertsson A., Voepel J., Edlund U., Dahlman O., Söderqvist-Lindblad M., “Design of renewable hydrogel release systems from fiberboard mill wastewater” Biomacromolecules, 11,1406–1411, 2010.
10. Referans10 Yang, Y., Tong Z., Geng Y., Li Y., Zhang M.,, “Biobased polymer composites derived from corn stover and feather meals as double-coating materials for controlled-release and water-retention urea fertilizers” Journal of Agricultural and Food Chemistry, 61,8166−8174, 2013.
11. Referans11 Borges R., Prevot V., Forano C., Wypych F., “Design and kinetic study of sustainable potential slow-release fertilizer obtained by mechanochemical activation of clay minerals and potassium monohydrogen phosphate” Industrial & Engineering Chemistry Research, 56, 708−716, 2017.
12. Referans12 Patela S., Bajpaia A.K., Bajpaia J., Sainia R.K., Acharyab S, “Facile preparation of iron loaded calcium alginate nanocarriers and study of controlled release of iron” Journal of Environmental Chemical Engineering, 5,5337–5346, 2017.
13. Referans13 Zhang J., Liu R., Li A., Wang A, “Preparation, swelling behaviors, and slow-release properties of a poly(acrylicacid-co-acrylamide)/sodium humate superabsorbent composite” Industrial & Engineering Chemistry Research, 45, 48-53, 2006.
14. Referans14 Radhakrishnan R., Kumari B.D.R., “Pulsed magnetic field: A contemporary approach offers to enhance plant growth and yield of soybean” Plant Physiology and Biochemistry, 51, 139-144, 2012.
15. Referans15 Guo M., Liu M., Liang R., Niu A., “Granular urea-formaldehyde slow-release fertilizer with superabsorbent and moisture preservation” Journal of Applied Polymer Science, 99,3230–3235, 2006.