Hydrogen production and process optimization using thin film nickel catalyst in KBH4 hydrolysis

Bu makalenin ilk hali 14 Ekim 2022 tarihinde yayımlandı. https://dergipark.org.tr/tr/pub/ngumuh/article/1143291

Düzeltme Notu

Nigde Omer Halisdemir University Journal of Engineering Sciences, in the research article with DOI number “https://doi.org/10.28948/ngumuh.1143291”, it was understood that the images presented in Figures 2a and 2b by the author were inadvertently uploaded as incorrect images. The author apologizes to the readers for this mistake. Correct images and explanations of the article are presented in the content of the correction article, which was made in order to eliminate the faulty pictures in the article.

Abstract

In this study, nickel was coated as a thin film on the slide by magnetron sputtering and used as a catalyst for alkali potassium borohydride hydrolysis. The effects of parameters such as ambient temperature, catalyst amount, wt% KBH4 ratio, volume of HCl and wt% NaOH ratio rate on the hydrogen production rate in the catalytic hydrolysis of potassium borohydride solution were investigated in detail by response surface method. Process optimization was done using central composite design and the efficiency of the parameters was determined by analysis of variance. As a result of the model created, the optimum parameters for the maximum HGR value; ambient temperature 55 ˚C; 13% KBH4; 0.6% NaOH; Determined as 9 mL of 0.5 M HCl. The maximum hydrogen generation rate was calculated as 92.8 L/min g.

Keywords

• Potassium borohydride
• Hydrolysis
• Hydrogen production
• Nickel
• Magnetron sputtering

KBH4 hidrolizinde ince film nikel katalizörünü kullanarak hidrojen üretimi ve proses optimizasyonu

Bu makalenin ilk hali 14 Ekim 2022 tarihinde yayımlandı. https://dergipark.org.tr/tr/pub/ngumuh/article/1143291

Düzeltme Notu

Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, “https://doi.org/10.28948/ngumuh.1143291” DOI numaralı araştırma makalesinde yazar tarafından Şekil 2a ve 2b’de sunulan resimlerin sehven hatalı olarak yüklendiği anlaşılmıştır. Yapılan bu hatadan dolayı yazar, okuyuculardan özür dilemektedir. Makalede yer alan hatalı resimlerin giderilmesi amacıyla yapılan bu düzeltme yazısında makaleye ait doğru resimler ve açıklamalar içerikte sunulmuştur.

Öz

Bu çalışmada nikel, magnetron saçtırma işlemi ile lam üzerine ince bir film olarak kaplanmış ve alkali potasyum borhidrür hidrolizinde katalizör olarak kullanılmıştır. Ayrıca ortam sıcaklığı, katalizör miktarı, % KBH4 oranı, HCl hacmi ve % NaOH oranı gibi parametrelerin potasyum borhidrür çözeltisinin katalitik hidrolizinde hidrojen üretimi hızına olan etkileri de yanıt yüzey metodu ile ayrıntılı olarak incelenmiştir. Proses optimizasyonu merkezi kompozit dizaynı kullanılarak yapılmış ve parametrelerin etkinliği varyans analizi ile belirlenmiştir. Oluşturulan model sonucunda, maksimum HGR değeri için optimum parametreler; ortam sıcaklığı 55 ˚C; %13 oranında KBH4; %0.6 oranında NaOH; 9 mL 0.5 M HCI olarak belirlenmiştir. Maksimum hidrojen üretim hızı 92.8 L/dk. g olarak hesaplanmıştır.

Anahtar Kelimeler

• Potasyum borhidrür
• Hidroliz
• Hidrojen üretimi
• Nikel
• Magnetron sputter

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