KAPYA BİBER ARTIĞI KULLANILARAK BİYOSORPSİYONLA ATIKSULARDAN NİKEL GİDERİMİ

Öz

Nikel, alıcı ortamlar için ciddi zararlı etkilere yol açabilen bir ağır metal olup, deşarj edilmeden önce uygun arıtım yöntemleri kullanılarak giderilmesi gerekmektedir. Bu amaçla, atıksulardan yeni bir biyosorbent materyali olan kapya biber çekirdeğinin nikel giderim performansını değerlendirmek için biyosorpsiyon çalışmaları gerçekleştirilmiştir. Bu çalışmada başlangıç pH değerinin, biyosorbent dozajının, başlangıç nikel konsantrasyonunun ve zamanın biyosorpsiyon üzerine olan etkileri araştırılmış, ayrıca kinetik ve denge analizleri de gerçekleştirilmiştir. Bu çalışmada kullanılan biyosorbent materyali 125 µm ile 250 µm aralığında yer almaktadır. Yapılan çalışmaların neticesinde biyosorpsiyon verilerinin yalancı ikinci derece reaksiyon kinetik modeli ile çok iyi bir şekilde tanımlandığı bulunmuş olup, Langmuir izoterm modelinin de deney sonuçları ile oldukça tutarlı olduğu anlaşılmıştır. Biyosorpsiyon çalışmasında optimum pH değerinin 5,5 olduğu tespit edilmiştir. Maksimum giderim verimi 28 g/L biyosorbent materyali kullanılarak elde edilmiştir. Maksimum biyosorpsiyon tutma kapasitesi 4,17 mg/g olarak hesaplanmıştır. Bu çalışma ile atıksulardan nikel iyonlarının giderimi için bu biyokütlenin bir potansiyele sahip olduğu bulunmuştur.

Anahtar Kelimeler

• nikel giderimi,biyosorpsiyon,kapya biber çekirdeği,izoterm,kinetik

Kaynakça

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