BASIC YELLOW 28 REMOVAL BY ADSORPTION FROM AQUEOUS SOLUTIONS WITH NATURAL AND ACTIVATED PINE SAWDUST

Abstract

DOĞAL VE AKTİVE EDİLEN ÇAM TALAŞI İLE SUCUL ÇÖZELTİDEN ADSORPSİYONLA BAZİK SARI 28 GİDERİMİ

Öz

Bu çalışmada, ham ve kimyasal aktivasyon uygulanan çam talaşı kullanılarak Bazik Sarı 28 tekstil boyar maddesinin sulu çözeltiden adsorpsiyonu çalışılmıştır. Temas süresi, adsorbent madde dozajı, başlangıç boya konsantrasyonu ve kimyasal aktivasyonun verime etkisi belirlenen koşullarda çalışılmıştır. Kimyasal aktivasyon sonrası adsorbent karakterizasyonu için SEM, FTIR ve izoelektrik nokta belirleme yöntemlerinden yararlanılmıştır. Bazik Sarı 28 adsorpsiyonu için denge verisi Langmuir eşitliği ile daha iyi uyum göstermiştir, maksimum tek tabakalı adsorpsiyon kapasitesi Qo değeri 62,89 mg/g olarak bulunmuştur. Bazik Sarı 28’in adsorpsiyonu sözde ikinci derece kinetik model ile en iyi şekilde tanımlanmıştır. Aktive olan çam talaşının adsorbent olarak yeniden kullanılabilirliği test edilmiş, dördüncü döngüden sonra bile hala %90’nın üzerinde Bazik Sarı 28 boya giderimi olduğu görülmüştür. Elde edilen sonuçlar, talaşın H2SO4 ile aktivasyonu sonrasında elde edilen adsorbentin atık sulardan Bazik Sarı 28 tekstil boyasının adsorpsiyonla arıtılmasında etkin olarak kullanılabileceğini göstermiştir. Aktive edilen çam talaşı, düşük maliyetli üretim ve adsorpsiyon performansı ile sürdürülebilir uygulamalar için yüksek bir potansiyele sahiptir.

Anahtar Kelimeler

• Adsorpsiyon
• Basic Yellow 28
• Çam talaşı
• Kimyasal aktivasyon
• Tekstil boyası

Kaynakça

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