REMOVAL OF ALIZARIN RED DYE USING HYDROXYAPATITE BY ADSORPTION PROCESS

Yıl 2018, Cilt: 7 Sayı: 1, 58 - 66, 31.01.2018

Deniz İzlen Çifçi

https://doi.org/10.28948/ngumuh.384840

Öz

   In this study, the removal of alizarin red dye by hydroxyapatite was
investigated with the adsorption process. The effects of shaking speed, pH,
hydroxyapatite dose and the initial dye concentration were studied on the
removal of dye. The adsorption of alizarin red dye using hydroxyapatite was
found to be more appropriate to the pseudo second order kinetic model and the
Freundlich isotherm model. The maximum adsorption capacity was obtained as
144.9 mg/g at pH 7 and 1 g/L hydroxyapatite after 150 minutes adsorption. As a
result, it is thought that hydroxyapatite can be used as an alternative
adsorbent to remove the anionic dyes such as alizarin red dye.

Anahtar Kelimeler

Adsorption, alizarin red S dye, anionic dye, hydroxyapatite

ALİZARİN KIRMIZI BOYASININ HİDROKSİAPATİT KULLANILARAK ADSORPSİYON PROSESİ İLE GİDERİMİ

Öz

  
Bu
çalışmada, hidroksiapatit ile alizarin kırmızı boyasının adsorpsiyon prosesiyle
giderimi araştırılmıştır. Çalışmada çalkalama hızının, çözelti pH değerinin,
hidroksiapatit miktarının ve başlangıç boya konsantrasyonun giderim verimi
üzerine etkisi ortaya konmuştur. Alizarin kırmızı boyasının hidroksiapatit ile
adsorpsiyonu yalancı ikinci dereceden kinetik modele ve Freundlich izoterm
modeline daha uygun olduğu görülmüştür. Maksimum adsorpsiyon kapasitesi pH 7’de,
1 g/L hidroksiapatit ile 150 dakika adsorpsiyon sonucunda 144,9 mg/g olarak
elde edilmiştir. Sonuç olarak, hidroksiapatitin alizarin kırmızı boyası gibi
anyonik boyaların gideriminde alternatif bir adsorbent olarak kullanılabileceği
düşünülmektedir.

Anahtar Kelimeler

Adsorpsiyon, alizarin kırmızı boyası, anyonik boya, hidroksiapatit, renk giderimi

Kaynakça

• [1] FAN, L., ZHANG, Y., LI, X., LUO, C., LU, F., QIU, H., “Removal of Alizarin Red from Water Environment Using Magnetic Chitosan with Alizarin Red as Imprinted Molecules”, Colloids and Surfaces B: Biointerfaces, 91, 250-257, 2012.
• [2] FAYAZI, M., GHANEI-MOTLAGH, M., TAHER, M.A., “The Adsorption of Basic Dye (Alizarin Red S) from Aqueous Solution onto Activated Carbon/γ-Fe2O3 Nano-Composite: Kinetic and Equilibrium Studies”, Materials Science in Semiconductor Processing, 40, 35-43, 2015.
• [3] GHOLIVAND, M.B., YAMINI, Y., DAYENI, M., SEIDI, S., TAHMASEBI, E., “Adsorptive Removal of Alizarin Red-S and Alizarin Yellow GG from Aqueous Solutions Using Polypyrrole-Coated Magnetic Nanoparticles”, Journal of Environmental Chemical Engineering, 3, 529-540, 2015.
• [4] GAUTAM, R.K., MUDHOO, A., CHATTOPADHYAYA, M.C., “Kinetic, Equilibrium, Thermodynamic Studies and Spectroscopic Analysis of Alizarin Red S Removal by Mustard Husk”, Journal of Environmental Chemical Engineering, 1, 1283-1291, 2013.
• [5] SRILAKSHMI, C., SARAF, R., “Ag-Doped Hydroxyapatite as Efficient Adsorbent for Removal of Congo Red Dye from Aqueous Solution: Synthesis, Kinetic and Equilibrium Adsorption Isotherm Analysis”, Microporous and Mesoporous Materials, 219, 134-144, 2016.
• [6] SMIČIKLAS, I.D., MILONJIĆ, S.K., PFENDT, P., RAIČEVIĆ, S., “The Point of Zero Charge and Sorption of Cadmium (II) and Strontium (II) Ions on Synthetic Hydroxyapatite”, Separation and Purification Technology, 18, 185-194, 2000.
• [7] ÇİFÇİ, D.I., “Enhancement of Methylene Blue Dye Adsorption by Fe-Hydroxyapatite Composite”, Advances in Environmental Research, 5(4), 225-235, 2016.
• [8] VALIZADEH, S., RASOULIFARD, M.H., DORRAJI, M.S.S., “Adsorption and Photocatalytic Degradation of Organic Dyes onto Crystalline and Amorphous Hydroxyapatite: Optimization, Kinetic and Isotherm Studies”, Korean Journal of Chemical Engineering, 33(2), 481-489, 2016.
• [9] NGUYEN, V.C., PHO, Q.H., “Preparation of Chitosan Coated Magnetic Hydroxyapatite Nanoparticles and Application for Adsorption of Reactive Blue 19 and Ni2+ Ions”, The Scientific World Journal, ID 273082, 1-9, 2014.
• [10] MAHMUD, K., ISLAM, M.A., MITSIONIS, A., ALBANIS, T., VAIMAKIS, T., “Adsorption of Direct Yellow 27 from Water by Poorly Crystalline Hydroxyapatite Prepared Via Precipitation Method”, Desalination and Water Treatment, 41(1-3), 170-178, 2012.
• [11] REHMAN, R., MAHMUD, T., ANWAR, J., SALMAN, M., SHAFIQUE, U., ZAMAN, W.U., ALI, F., “Removal of Alizarin Red S (Dye) from Aqueous Media by Using Alumina as an Adsorbent”, Journal Chemical Society of Pakistan, 33(2), 228-232, 2011.
• [12] SUJITHA, R.K., RAVINDHRANTH, K., “Extraction of Anionic Dye, Alizarin Red S, from Industrial Waste Waters Using Active Carbon Derived from the Stems of Achyranthes Aspera Plant as Bio-Adsorbent”, Der Pharma Chemica, 8(9), 63-73, 2016.
• [13] REHMAN, R., MAHMUD, T., “Sorptive Elimination of Alizarin Red-S Dye from Water Using Citrullus lanatus Peels in Environmentally Benign Way Along with Equilibrium Data Modeling”, Asian Journal of Chemistry, 25(10), 5351-5356, 2013.
• [14] LACHHEB, H., PUZENAT, E., HOUAS, A., KSIBI, M., ELALOUI, E., GUILLARD, C., HERRMANN, J.-M., “Photocatalytic Degradation of Various Types of Dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in Water by UV-Irradiated Titania”, Applied Catalysis B: Environmental, 39, 75-90, 2002.
• [15] IVANOV, V.M., ADAMOVA, E.M., FIGUROVSKAYA, V.N., “Acid-Base, Spectrophotometric, and Colorimetric Properties of 1,2-Dihydroxyantraquinonone-3-Sulfoacid (Alizarin Red S)”, Journal of Analytical Chemistry, 65(5), 473-481, 2010.
• [16] EPSTEIN, M., YARIV, S., “Visible-Spectroscopy Study of the Adsorption of Alizarinate by Al-Montmorillonite in Aqueous Suspensions and in Solid State”, Journal of Colloid and Interface Science, 263, 377-385, 2003.
• [17] POLUBESOVA, T., EPSTEIN, M., YARIV, S., LAPIDES, I., NIR, S., “Adsorption of Alizarinate–Micelle Complexes on Na-Montmorillonite”, Applied Clay Science, 24(3-4), 177-183, 2004.
• [18] HOU, H., ZHOU, R., WU, P., WU, L., “Removal of Congo Red Dye from Aqueous Solution with Hydroxyapatite/Chitosan Composite”, Chemical Engineering Journal, 211-212, 336-342, 2012.
• [19] BARKA, N., QOURZAL, S., ASSABBANE, A., NOUNAH, A., ICHOU, Y.A., “Adsorption of Disperse Blue SBL Dye by Synthesized Poorly Crystalline Hydroxyapatite”, Journal of Environmental Sciences, 20, 1268-1272, 2008.
• [20] ABDULLAH, M.A., CHIANG, L., NADEEM, M., “Comparative Evaluation of Adsorption Kinetics and Isotherms of a Natural Product Removal by Amberlite Polymeric Adsorbents”, Chemical Engineering Journal, 146, 370-376, 2009.
• [21] LI, D. LIU, Q., MA, S., CHANG, Z., ZHANG, L., “Adsorption of Alizarin Red S onto Nano-Sized Silica Modified with -Aminopropyltriethoxysilane”, Adsorption Science and Technology, 29(3), 289-300, 2011.
• [22] WAGH, P.B., SHRIVASTAVA, V.S., “Removal of Alizarin Red-S Dye from Aqueous Solution by Sorption on Coconut Shell Activated Carbon”, Journal of Scientific Research and Reports, 3(16), 2197-2215, 2014.
• [23] YANG, M., LI, D., ZHAO, T., MA, J., “Synthesis of Monodispersed Nanospheres of Mn3O4 and Its Adsorption Behavior for Alizarin Red”, Journal of Dispersion Science and Technology, 31(4), 563-566, 2010.
• [24] GHAEDI, M., NAJIBI, A., HOSSAINIAN, H., SHOKROLLAHI, A., SOYLAK, M., “Kinetic and Equilibrium Study of Alizarin Red S Removal by Activated Carbon”, Toxicological and Environmental Chemistry, 94(1), 40-48, 2012.
• [25] WANASSI, B., HARIZ, I.B., GHIMBEU, C.M., VAULOT, C., HASSEN, M.B., JEGUIRIM, M., “Carbonaceous Adsorbents Derived from Textile Cotton Waste for the Removal of Alizarin S Dye from Aqueous Effluent: Kinetic and Equilibrium Studies”, Environmental Science and Pollution Research, 24(11), 10041-10051, 2017.
• [26] ZOLGHARNEIN, J., BAGTASH, M., ASANJARANI, N., “Hybrid Central Composite Design Approach for Simultaneous Optimization of Removal of Alizarin Red S and Indigo Carmine Dyes Using Cetyltrimethylammonium Bromide-Modified TiO2 Nanoparticles”, Journal of Environmental Chemical Engineering, 2, 988-1000, 2014.