SYNTHESIS OF SCHIFF BASE COMPLEXES AND INVESTIGATION OF STRUCTURES

Yıl 2019, Cilt: 8 Sayı: 1, 621 - 629, 28.01.2019

Selma Yıldırım Uçan

https://doi.org/10.28948/ngumuh.517210

Öz

   Schiff base compounds are stable, readily synthesizable compounds. Besides,
in many fields of chemistry having a wide use field in, engineering, medicine
and pharmacy has increased the interest in these compounds and made them widely
available in different fields. A new Schiff base ligand,
4-chlorophenylimino-4-methoxysalicylaldehyde was synthesized by the reaction of
4-Methoxysalicylaldehyde and 4-chloroaniline.
The colored complexes were synthesized by adding of acetate salts of Co(II),
Cu(II) ve Zn(II) to the solution of
4-chlorophenylimino-4-methoxysalicylaldehyde dissolved in methanol. The
compounds obtained have been characterized by their elemental analyses, fourier
transform infrared (FT-IR),
nuclear magnetic resonance (¹H NMR), thermogravimetric analysis
(TG/DTG), conductometric measurements and magnetic susceptibility. 

Anahtar Kelimeler

Schiff bases, Metal complexes, Magnetic susceptibility, Thermogravimetric analysis

SCHİFF BAZI KOMPLEKSLERİNİN SENTEZİ VE YAPILARININ İNCELENMESİ

Öz

   Schiff bazı bileşikleri kararlı, kolay
sentezlenebilen bileşiklerdir. Bunun yanısıra, kimyanın pek çok alanında,
mühendislik, tıp ve eczacılıkta alanında geniş kulanım alanlarına sahip
olmaları bu bileşiklere olan ilgiyi artırmış, onları farklı alanlarda yaygın
olarak kullanılabilir hale getirmiştir. 4-Metoksisalisilaldehit ve 4-kloranilin’in reaksiyonundan yeni bir Schiff
bazı ligandı, 4-klorofenilimino-4-metoksisalisilaldehit sentezlendi. Metanollü
ortamda çözülmüş, 4-klorofenilimino-4-metoksisalisilaldehit
ligandına, metanolde çözülmüş olan Co(II), Cu(II) ve Zn(II) asetat
tuzları ilave edilerek renkli kompleksler sentezlendi. Elde edilen bileşiklerin
yapıları, İnfrared spektroskopisi
(FT-IR), nükleer manyetik rezonans (¹H NMR), termogravimetrik
analiz (TG/DTG), manyetik süsseptibilite,
kondüktometrik ölçümleri ve elementel
analiz yöntemleriyle ile karakterize edilmiştir.

Anahtar Kelimeler

Schiff bazı, Metal kompleksleri, Manyetik süsseptibilite, Termogravimetrik analiz

Kaynakça

• [1] LİU, X., CAROLİNA MANZUR, C., NOVOA, N., CELEDÓN, S., CARRİLLO, D., HAMON, J. R., “Multidentate unsymmetrically-substituted Schiff bases and their metal complexes: Synthesis, functional materials properties, and applications to catalysis”, Coordination Chemistry Reviews, 357, 144–172, 2018.
• [2] JİANG, S., GUO, H., ZHU, S., YANG, F., “Novel columnar liquid crystalline oligomers: Triphenylene tetramers with rigid aromatic Schiff-bases and hydrogen-bonding spacers via click chemistry”, Journal of Molecular Liquids,236, 76-80, 2017.
• [3] ZHANG, J., XU, L., WONG, W. Y., “Energy materials based on metal Schiff base complexes”, Coordination Chemistry Reviews, 355, 180-198, 2018.
• [4] LASRİ, J., ELSHERBİNY, A. S., ELTAYEB, N. E., HAUKKA, M., EL-HEFNAWY, M. E., “Synthesis and characterization of ferrocene-based Schiff base and ferrocenecarboxaldehyde oxime and their adsorptive removal of methyl blue from aqueous solution”, Journal of Organometallic Chemistry, 866, 21-26, 2018.
• [5] REİCHERT, D.E., LEWİS, J. S., ANDERSON, C. J., “Metal complexes as diagnostic tool”, Chem. Rev., 184, 3-66, 1999.
• [6] EMREGÜL K. C., DÜZGÜN E., ATAKOL O., “The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media”, Corr. Sci., 48: 3243-3260, 2006.
• [7] SCOVİLL, J.P., “KLAYMAN, D.L., FRANCHİNO, C.F., “2-Acetylpyridine Thiosemicarbazones Complexes with Transition-Metals as Antimalarial and Antileukemic Agents”, J. Med. Chem., 25, 1261-1264, 1982.
• [8] WEST, D.X., PANNELL, L.K., “Transition-Metal Ion Complexes of Thiosemicarbazones Derived from 2-Acetrypyridine N-Oxide, N-4- Dimethyl Derivative”, Transition Met. Chem., 14, 457-462, 1989.
• [9] ZİSHEN, W., ZİGİ, G., ZHENHUAN, Y., “Synthesis, characterization and anticanser activity of L-alanin Schiff base complexes of Cu(II), Zn(II) ve Co(II)”, Synth. React. Inorg. Met.-Org. Chem, 20,335-344, 1990.
• [10] RAMAN, N., and RAVİCHANDRAN, S., “Synthesis and characterization of a new Schiff base and its metal complexes derived from the mannich base, N-(1-piperidinobenzyl)acetamide”, Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 35, 439-444, 2005.
• [11] ARUN, V., ROBİNSON, P.P., MANJU, S., LEEJU, P., VARSHA, G., DİGNA, V. ve YUSUF, K.K.M., “A novel fluorescent bisazomethine derived from 3-hydroxyquinoxaline-2-carboxaldehyde and 2,3-diaminomaleonitrile”, Dyes and Pigments, 82, 268-275, 2009.
• [12] KHANDAR, A. A. ve NEJATİ K., “Synthesis and characterization of a series of copper(II) complexes with azo-linked salicylaldimine Schiff base ligands. Crystal structure of Cu5 PHAZOSALTNPCHCl3”, Polyhedron, 19, 2000.
• [13] ASADİ, M., ASADİ, Z., SYNTHESİS, SADİ B. S., ZAREİ L., BAİGİ, M. F., Amirghofran Z., “Characterization and the interaction of some new water soluble metal Schiff base complexes with human serum albumin”, Molecular and Biomolecular Spectroscopy, 122 ,118-129, 2014.
• [14] EBRAHİMİ, H. P., HADİ J.S., ABDULNABİ Z.A., BOLANDNAZAR Z., “Spectroscopic, thermal analysis and DFT computational studies of salen type Schiff base complexes”, Molecular and Biomolecular Spectroscopy, 117 485-492, 2014.
• [15] UÇAN, Y. S., “Synthesis, Spectral, Thermal, and Magnetic Studies of Cobalt(II), Nickel(II), Copper(II), Zinc(II) and Cadmium(II) Complexes with N2O2 Donor Groups”, Russian Journal of General Chemistry, 84 1819-1824, 2014.
• [16] UÇAN, Y. S., MERCİMEK, B., “Synthesis and characterization of tetradentate N2O2 Schiff base ligands and their transition metal complexes”, Synth. React. Inorg. Met.-Org. and Nano-Met. Chem. 35(3), 197-201, 2005.
• [17] KAKANEJADİFARD, A., ESNA-ASHARİ F., HASHEMİ P., ZABARDASTİ, A., “Synthesis and characterization of an azo dibenzoic acid Schiff base and its Ni(II), Pb(II), Zn(II) and Cd(II) complexes”, Molecular and Biomolecular Spectroscopy,106, 80-85, 2013.
• [18] UÇAN, Y. S., UÇAN, M., MERCİMEK, B., “Synthesis and characterization of some tetradentate Schiff bases and their cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II) and mercury(II) complexes”, Synth. React. Inorg. Met.-Org. and Nano- Metal Chem. 35(5) 417-421, 2005.
• [19] MOKHLES, M., “Spectroscopic Characterization of some Tetradentate Schiff Bases and Their Complexes with Ni(II), Cu(II) and Zn(II)”, Journal of the Chinese Chem. Society, 48, 153-158, 2001.
• [20] RADHA, V.P., JONE KİRUBAVATHY, S., CHİTRA, S., “Synthesis, characterization and biological investigations of novel Schiff base ligands containing imidazoline moiety and their Co(II) and Cu(II) complexes”, Journal of Molecular Structure, 1165, 246-258, 2018.
• [21] ANGELİCA, V., MİHAELA, A., SERGİU, S., MARİA, C., MİRELA, F.Z., “Synthesis, structural characterization and properties of some novel siloxane-based bis-Schiff base copper(II), nickel(II) and manganese(II) complexes”, Polyhedron, 146, 129-135, 2018.
• [22] HAMİDE, B., GHOLAMHOSSEİN, Gr., VACLAV, E., MİCHAL, D., ALİAKBAR, D.K., “Copper(II), nickel(II), zinc(II) and vanadium(IV) Schiff base complexes: Synthesis, characterization, crystal structure determination, and thermal studies”, Polyhedron, 146, 19-25, 2018.