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Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD

Yıl 2020, Cilt: 9 Sayı: 2, 770 - 780, 07.08.2020
https://doi.org/10.28948/ngumuh.700773

Öz

In this study, activated carbon has been obtained by using sea urchin as an adsorbent substance, which is abundant, cheap, and natural in nature, as an alternative to active carbon used in heavy metal removal. Using the Ultrasound-assisted support, 1:1, 2:1, 3:1 (H3PO4/sea urchin) carbonization process was carried out by subjecting H3PO4 as the sea urchin activating agent. The BET surface area of the activated carbon obtained was characterized by total pore volume, ash content, and SEM analysis. Cu (II) removal in aqueous solutions were investigated with activated carbons. Experimental studies have been conducted to determine the effects of pH, contact time (min), adsorbent concentration (g/L), temperature, and initial metal concentration parameters affecting adsorption. The adsorption capacity of the activated carbon obtained from the sea urchin at 25 °C was calculated as 643 mg/g. Optimum conditions from the results were determined as pH 2.0, contact time 80 minutes, initial adsorbent concentration 10 mg/L, and temperature 25 °C. According to the results of the study, it has been concluded that the activated carbon obtained from the sea urchin can be an alternative adsorbent to other activated carbons in heavy metal removal.

Kaynakça

  • M. P. Papini, Y. D. Kahie, B. Troia, and M. Majone, “Adsorption of lead at variable pH onto a natural porous medium: Modeling of batch and column experiments,” Environmental Science and Technology, vol. 33, pp. 3357-4464, 1999.
  • K. Zhang, W. Cheung, and M. Valix, “Roles of physical and chemical properties of activated carbon in the adsorption of lead ions, ” Chemosphere, vol. 60, pp. 1129-1140, 2005.
  • S. Tunali, A. Cabuk, and T. Akar, “Removal of lead and copper ions from aqueous solutions by bacterial strain isolated from soil, ” Chemical Engineering Journal, vol. 115,pp. 203-211, 2006.
  • S. S. Baral, S. N. Das, and P. Rath, “Hexavalent chromium removal from aqueous solution by ad-sorption on treated sawdust, ” Biochemical Engineering Journal, vol. 31, pp. 216–222, 2006.
  • E. S. Abdel-Halima, and S. Salem Al-Deyab, “Removal of heavy metals from their aqueous solutions through adsorption onto natural polymers, ” Carbohydrate Polymers, vol. 84,pp. 454–458, 2011.
  • H. A. Albroomi, M. A. Elsayed, A. Baraka, and M. K. Abdelmaged, “Factors affecting the removal of a basic and azo dye from artificial solutions by adsorption using activated carbon, ” Journal Turkish Chemistry Socience, vol. 2(1), pp. 17-33, 2015.
  • G. Kaykıoğlu, “Kolemanit ve üleksit atığı ile sulu çözeltilerden metilen mavisi giderimi : kinetik ve izoterm değerlendirmesi,” CBÜ Fen Bilimleri Dergisi,vol. 12(3), pp. 499-509, 2016.
  • I. Fatimah, A. Yahya, and R. A. T.Sasti, “Preparation of sodium dodecyl sulphate-functionalized activated carbon from Gnetum gnemon shell for dye adsorption, ” In AIP Conference Proceedings, 2017, pp. 1823(1), 20125.
  • M. Z. Hussein, R. S. H. Tarmizi, Z. Zainal, R. Ibrahim, and M. Badri, “Preparation and characterazation of active carbons from oil palm shells, ” Carbon, vol. 34(11), pp. 1447-1454, 1996.
  • A. C. Lua, and J. Guo, “Preparation and characterazation of chars from oil palm waste, ” Carbon, vol. 36 (11), pp. 1663-1670, 1998.
  • Z. Aksu, “Application of biosorption for the removal of organic pollutants: a review, ” Process Biochemistry, vol. 40 (3-4), pp. 997-1026, 2005.
  • L. J. Yu, S. S. Shukka, K. L. Dorris, A. Shukla, and J. L. Margrave, “Adsorption of chromium from aqueous solutions by fagus orientals, ” Journal of Hazardous Materials, vol. 100, pp. 53-63, 2003.
  • H. E Smith, W. Lu, T. Vengris, and R. Binkiene, “Sorption of Heavy Metals by Lithuian Glauconite, ” Water Research, vol. 30, pp. 2883-2892, 1996.
  • K. Zhang, W. Cheung, and M. Valix, “Roles of physical and chemical properties of activated carbon in the adsorption of lead ions, ” Chempsphere, vol. 60, pp. 1129-1140, 2005.
  • E. Inam, U. J. Etim, E. G. Akpabio, and S. A. Umoren, “Process optimization for the application of carbon from plantain peels in dye abstraction," Journal of Taibah University for Science, vol. 11(1), pp. 173-185, 2017.
  • J. Han, J. H. Kwon, J. W. Lee, J. H. Lee, and K. C. Roh, "An effective approach to preparing partially graphitic activated carbon derived from structurally separated pitch pine biomass, "Carbon, vol. 118, pp. 431-437, 2017.
  • U. S. Zhenisbekovna, M. I. Satayev and S. V. Viktorovich, "Production of active carbons from apricot pit shells by thermal activation in the mixture of carbon dioxide and water vapors," Biosciences Biotechnology Research Asia, vol. 13(3), pp. 1319-1325, 2016.
  • I. Demiral, "Kabak çekirdeği kabuğundan elde edilen aktif karbonun sulu çözeltiden boyarmadde gideriminde değerlendirilmesi," Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Özel Sayı, pp. 212-217, 2016.
  • E. Ustabaş, "İşlenmiş ve Demlenmiş atık çaydan elde edilen aktif karbonun tekstil boyar maddesi metilen mavisini adsorplama özellikleri," Yüksek Lisans Tezi, Trakya Üniversitesi, Fen Bilimleri Enstitüsü, 2016, 83.
  • C. Kumaş, "Fındık kabuğundan aktif karbon elde edilmesinde fosforik asit ve bor kullanılması," Yüksek Lisans Tezi, Afyon Kocatepe Üniversitesi, Fen Bilimleri Enstitüsü, 2015, 34.
  • N. V. Sych, S. I. Trofymenko, O. I. Poddubnaya, M. M. Tsyba, V. I. Sapsay, D. O. Klymchuk, and A. M. Puziy, "Porous structure and surface chemistry of phosphoric acid activated carbon from corncob," Applied Surface Science, vol. 261, pp. 75-82, 2012.
  • H. Bozkan, "Azo boyalarının zeytin atığı(pirina) kullanılarak adsorpsiyon metodu ile giderimi”, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, 2012, 56.
  • S. Naeem, V. Baheti, J. Wiener, and J. Marek, "Removal of methylene blue from aqueous media using activated carbon web," The Journal of The Textile Institute, vol. 108(5), pp. 803-811, 2017.
  • M. Breitbach, and D. Bathen, "Influence of Ultrasound on Adsorption Processes," Ultrasonic Sonochemistry, vol. 8(3), pp. 277-283, 2001.
  • J. Benedito, J. A. Carcel, C. Rossello, and A. Mulet, "Composition assessment of raw meat mixtures using ultrasonics," Meat Science, vol. 57, pp. 365–370, 2001.
  • E. Şayan, and O. N. Ata, "Ultrases Kullanarak Aktif Karbon Üzerine Reactive Blue 19’un Adsorpsiyon Termodinamiğinin Incelenmesi," In Proc.11. Ulusal Kimya Mühendisliği Kongresi, Eskişehir, 2014.
  • E. Kalıpcı, S. Şahinkaya, S. Aras, and M. Öztürk, "Ultrasonik Aktifleştirilmiş Aktif Karbon ile Krom(VI) Adsorpsiyonu," Nevşehir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 2(1), pp20–25, 2013.
  • S. Wang, and Z. H. Zhu, "Sonochemical Treatment of Fly Ash for Dye Removal from Wastewater," Journal of Hazardous Materials, vol. 126(1-3), pp. 91–95, 2005.
  • M. E. Edecan, "Kombine Ultrases/Aktif Karbon Kullanarak Tekstil Boyar Maddesinin Renk Gideriminin Modellenmesi ve Optimizasyonu," Yüksek Lisans Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Erzurum, 2006.
  • R. L. Tseng, F. C. Wu, and R. S. Juang, "Liquid-phase adsorption of dyes and phenols using pinewood-based activated carbons," Carbon, vol. 41, pp. 487–495, 2003.
  • H. Amjad El-Sheikh, P. N. Alan, K. Al-Daffaee Hafid, P. Suki, and C. Neil, "Characterization of activated carbon prepared from a single cultivar of Jordanian Olive stones by chemical and physicochemical techniques," J. Anal. Appl. Pyrolysis, vol. 71, pp. 151-164, 2004.
  • H. Hadoun, Z. Sadaoui, N. Souami, D. Sahel, and I. Toumert, "Characterization of mesoporous carbon prepared from date stems by H3PO4 chemical activation," Applied Surface Science, vol. 280, pp. 1-7, 2013.
  • J. J. Gao, Y. B. Qin, T. Zhou, D. D. Cao, P. Xu, D. Hochstetter, and Y. F. Wang, "Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies," Journal of Zhejiang University Science B, vol. 14(7), pp. 650-658, 2013.
  • S. Babel, and T. A. Kurniawan, "Low-cost adsorbents for heavy metals uptake from contaminated water: a review," Journal of Hazardous Materials, vol. 97, pp. 219-243, 2003.
  • G. G. Stavropoulos, and A. A. Zabaniotou, "Production and characterization of activated carbons from olive-seed waste residue," Micropor Mesopor Mater., vol. 82, pp. 79–85, 2005.
  • I. Ozdemir, M. Şahin, R. Orhan, and M. Erdem, "Preparation and characterization of activated carbon from grape stalk by zinc chloride activation," Fuel Processing Technology, vol. 125, pp. 200-206, 2014.
  • M. Erdem, R. Orhan, M. Şahin, and E. Aydın, "Preparation and Characterization of a Novel Activated Carbon from Vine Shoots by ZnCl2 Activation and Investigation of Its Rifampicine Removal Capability," Water Air Soil Pollut, vol. 227, pp. 226-240, 2016.
  • P. Hadi, M. Xu, C. Ning, C. S. K. Lin, and G. Mc Kay, "A critical review on preparation, characterization and utilization of sludge-derived activated carbons for wastewater treatment," Chemical Engineering Journal, vol. 260, pp. 895-906, 2015.
  • G. Yupeng, S. Y. Jurui Qi, Y. Kaifeng, W. Zichen, and X. Hongding, "Adsorption of Cr(VI) on micro-and mesoporous rice husk-based active carbon," Materials Chemistry and Physics, vol. 78, pp. 132-137, 2002.
  • J. Goel, K. Kadirvelu, C. Rajagopal, and V. K. Garg, "Removal of lead(II) by adsorption using treated granular activated carbon: batch and column studies," J. Hazard. Mater. B, vol. 125, pp. 211-220, 2005.
  • E. Malkoç, "Farklı adsorbent türleri ile sulardan ağır metallerin giderimi" Doktora Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Çevre Mühendisliği Anabilim Dalı, Erzurum, 2005.
  • V. Marinovic, M. Ristic, and M. Dostanic, "Dynamic adsorption of trinitrotoluene on granular activated carbon," Journal of Hazardous Materials, vol. 117, pp. 121-128, 2005.
  • S. Hashemian, K. Salari, and Z. A. Yazdi, "Preparation of activated carbon from agricultural wastes (almond shell and orange peel) for adsorption of 2-pic from aqueous solution," Journal of Industrial and Engineering Chemistry, vol. 20, pp. 1892-1900, 2014.
  • S. A. Torrellas, R. G. Lovera, N. Escalona, C. Sepülveda, J. L. Sotela, and J. Garcia, "Chemical-activated carbons from peach stones for the adsorption of emerging contaminants in aqueous solutions," Chemical Engineering Journal, vol. 279, pp. 788-798, 2015.
  • K. Vijayaraghavan, J. Jegan, K. Palanivelu, and M. Velan, "Removal of nickel(II) ions from aqueous solution using crab shell particles in a packed bed up flow column," J. Hazard. Mater, vol. 113B (1–3), pp. 223–230, 2004.
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ULTRASES YÖNTEMİ İLE HAZIRLANAN DENİZ KESTANESİNDEN ELDE EDİLEN AKTİF KARBON İLE Cu (II) ADSORPSİYONU

Yıl 2020, Cilt: 9 Sayı: 2, 770 - 780, 07.08.2020
https://doi.org/10.28948/ngumuh.700773

Öz

Bu çalışmada, ağır metal gideriminde kullanılan aktif karbonlara farklı seçenek olarak doğada bol, ucuz ve doğal olarak bulunan adsorbent bir madde olarak deniz kestanesi kullanılarak aktif karbon elde edilmiştir. Ultrason desteği kullanılarak deniz kestanesi aktifleştirma maddesi olarak H3PO4 ‘ün kullanıldığı karbonizasyona tabi tutularak 1:1, 2:1, 3:1 (H3PO4 /deniz kestanesi) karbonizasyon işlemi gerçekleştirilmiştir. Elde edilen aktif karbonun BET yüzey alanı, toplam gözenek hacmi, kül içeriği ve SEM analizleriyle karakterize edilmiştir. Aktif karbonlar ile sulu çözeltilerdeki Cu (II) giderimi araştırılmıştır. Adsorpsiyonu etkileyen pH, temas süresi (dk), adsorbent konsantrasyonu (g/L), sıcaklık ve başlangıç metal konsantrasyonu parametrelerinin etkilerini belirlemek için deneysel çalışmalar yapılmıştır. Deniz kestanesinden elde edilen aktif karbonun 25 °C’de Cu (II) adsorplama kapasitesi 643 mg/g olarak hesaplanmıştır. Elde edilen sonuçlardan optimum koşullar pH 2.0, temas süresi 80 dakika, başlangıç adsorbent madde konsantrasyonu 10 mg/L ve sıcaklık 25 °C olarak belirlenmiştir. Çalışmanın sonuçlarına göre, deniz kestanesinden elde edilen aktif karbonun ağır metal gideriminde diğer aktif karbonlara alternatif bir adsorbent olabileceği sonucu elde edilmiştir.

Kaynakça

  • M. P. Papini, Y. D. Kahie, B. Troia, and M. Majone, “Adsorption of lead at variable pH onto a natural porous medium: Modeling of batch and column experiments,” Environmental Science and Technology, vol. 33, pp. 3357-4464, 1999.
  • K. Zhang, W. Cheung, and M. Valix, “Roles of physical and chemical properties of activated carbon in the adsorption of lead ions, ” Chemosphere, vol. 60, pp. 1129-1140, 2005.
  • S. Tunali, A. Cabuk, and T. Akar, “Removal of lead and copper ions from aqueous solutions by bacterial strain isolated from soil, ” Chemical Engineering Journal, vol. 115,pp. 203-211, 2006.
  • S. S. Baral, S. N. Das, and P. Rath, “Hexavalent chromium removal from aqueous solution by ad-sorption on treated sawdust, ” Biochemical Engineering Journal, vol. 31, pp. 216–222, 2006.
  • E. S. Abdel-Halima, and S. Salem Al-Deyab, “Removal of heavy metals from their aqueous solutions through adsorption onto natural polymers, ” Carbohydrate Polymers, vol. 84,pp. 454–458, 2011.
  • H. A. Albroomi, M. A. Elsayed, A. Baraka, and M. K. Abdelmaged, “Factors affecting the removal of a basic and azo dye from artificial solutions by adsorption using activated carbon, ” Journal Turkish Chemistry Socience, vol. 2(1), pp. 17-33, 2015.
  • G. Kaykıoğlu, “Kolemanit ve üleksit atığı ile sulu çözeltilerden metilen mavisi giderimi : kinetik ve izoterm değerlendirmesi,” CBÜ Fen Bilimleri Dergisi,vol. 12(3), pp. 499-509, 2016.
  • I. Fatimah, A. Yahya, and R. A. T.Sasti, “Preparation of sodium dodecyl sulphate-functionalized activated carbon from Gnetum gnemon shell for dye adsorption, ” In AIP Conference Proceedings, 2017, pp. 1823(1), 20125.
  • M. Z. Hussein, R. S. H. Tarmizi, Z. Zainal, R. Ibrahim, and M. Badri, “Preparation and characterazation of active carbons from oil palm shells, ” Carbon, vol. 34(11), pp. 1447-1454, 1996.
  • A. C. Lua, and J. Guo, “Preparation and characterazation of chars from oil palm waste, ” Carbon, vol. 36 (11), pp. 1663-1670, 1998.
  • Z. Aksu, “Application of biosorption for the removal of organic pollutants: a review, ” Process Biochemistry, vol. 40 (3-4), pp. 997-1026, 2005.
  • L. J. Yu, S. S. Shukka, K. L. Dorris, A. Shukla, and J. L. Margrave, “Adsorption of chromium from aqueous solutions by fagus orientals, ” Journal of Hazardous Materials, vol. 100, pp. 53-63, 2003.
  • H. E Smith, W. Lu, T. Vengris, and R. Binkiene, “Sorption of Heavy Metals by Lithuian Glauconite, ” Water Research, vol. 30, pp. 2883-2892, 1996.
  • K. Zhang, W. Cheung, and M. Valix, “Roles of physical and chemical properties of activated carbon in the adsorption of lead ions, ” Chempsphere, vol. 60, pp. 1129-1140, 2005.
  • E. Inam, U. J. Etim, E. G. Akpabio, and S. A. Umoren, “Process optimization for the application of carbon from plantain peels in dye abstraction," Journal of Taibah University for Science, vol. 11(1), pp. 173-185, 2017.
  • J. Han, J. H. Kwon, J. W. Lee, J. H. Lee, and K. C. Roh, "An effective approach to preparing partially graphitic activated carbon derived from structurally separated pitch pine biomass, "Carbon, vol. 118, pp. 431-437, 2017.
  • U. S. Zhenisbekovna, M. I. Satayev and S. V. Viktorovich, "Production of active carbons from apricot pit shells by thermal activation in the mixture of carbon dioxide and water vapors," Biosciences Biotechnology Research Asia, vol. 13(3), pp. 1319-1325, 2016.
  • I. Demiral, "Kabak çekirdeği kabuğundan elde edilen aktif karbonun sulu çözeltiden boyarmadde gideriminde değerlendirilmesi," Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Özel Sayı, pp. 212-217, 2016.
  • E. Ustabaş, "İşlenmiş ve Demlenmiş atık çaydan elde edilen aktif karbonun tekstil boyar maddesi metilen mavisini adsorplama özellikleri," Yüksek Lisans Tezi, Trakya Üniversitesi, Fen Bilimleri Enstitüsü, 2016, 83.
  • C. Kumaş, "Fındık kabuğundan aktif karbon elde edilmesinde fosforik asit ve bor kullanılması," Yüksek Lisans Tezi, Afyon Kocatepe Üniversitesi, Fen Bilimleri Enstitüsü, 2015, 34.
  • N. V. Sych, S. I. Trofymenko, O. I. Poddubnaya, M. M. Tsyba, V. I. Sapsay, D. O. Klymchuk, and A. M. Puziy, "Porous structure and surface chemistry of phosphoric acid activated carbon from corncob," Applied Surface Science, vol. 261, pp. 75-82, 2012.
  • H. Bozkan, "Azo boyalarının zeytin atığı(pirina) kullanılarak adsorpsiyon metodu ile giderimi”, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, 2012, 56.
  • S. Naeem, V. Baheti, J. Wiener, and J. Marek, "Removal of methylene blue from aqueous media using activated carbon web," The Journal of The Textile Institute, vol. 108(5), pp. 803-811, 2017.
  • M. Breitbach, and D. Bathen, "Influence of Ultrasound on Adsorption Processes," Ultrasonic Sonochemistry, vol. 8(3), pp. 277-283, 2001.
  • J. Benedito, J. A. Carcel, C. Rossello, and A. Mulet, "Composition assessment of raw meat mixtures using ultrasonics," Meat Science, vol. 57, pp. 365–370, 2001.
  • E. Şayan, and O. N. Ata, "Ultrases Kullanarak Aktif Karbon Üzerine Reactive Blue 19’un Adsorpsiyon Termodinamiğinin Incelenmesi," In Proc.11. Ulusal Kimya Mühendisliği Kongresi, Eskişehir, 2014.
  • E. Kalıpcı, S. Şahinkaya, S. Aras, and M. Öztürk, "Ultrasonik Aktifleştirilmiş Aktif Karbon ile Krom(VI) Adsorpsiyonu," Nevşehir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 2(1), pp20–25, 2013.
  • S. Wang, and Z. H. Zhu, "Sonochemical Treatment of Fly Ash for Dye Removal from Wastewater," Journal of Hazardous Materials, vol. 126(1-3), pp. 91–95, 2005.
  • M. E. Edecan, "Kombine Ultrases/Aktif Karbon Kullanarak Tekstil Boyar Maddesinin Renk Gideriminin Modellenmesi ve Optimizasyonu," Yüksek Lisans Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Erzurum, 2006.
  • R. L. Tseng, F. C. Wu, and R. S. Juang, "Liquid-phase adsorption of dyes and phenols using pinewood-based activated carbons," Carbon, vol. 41, pp. 487–495, 2003.
  • H. Amjad El-Sheikh, P. N. Alan, K. Al-Daffaee Hafid, P. Suki, and C. Neil, "Characterization of activated carbon prepared from a single cultivar of Jordanian Olive stones by chemical and physicochemical techniques," J. Anal. Appl. Pyrolysis, vol. 71, pp. 151-164, 2004.
  • H. Hadoun, Z. Sadaoui, N. Souami, D. Sahel, and I. Toumert, "Characterization of mesoporous carbon prepared from date stems by H3PO4 chemical activation," Applied Surface Science, vol. 280, pp. 1-7, 2013.
  • J. J. Gao, Y. B. Qin, T. Zhou, D. D. Cao, P. Xu, D. Hochstetter, and Y. F. Wang, "Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies," Journal of Zhejiang University Science B, vol. 14(7), pp. 650-658, 2013.
  • S. Babel, and T. A. Kurniawan, "Low-cost adsorbents for heavy metals uptake from contaminated water: a review," Journal of Hazardous Materials, vol. 97, pp. 219-243, 2003.
  • G. G. Stavropoulos, and A. A. Zabaniotou, "Production and characterization of activated carbons from olive-seed waste residue," Micropor Mesopor Mater., vol. 82, pp. 79–85, 2005.
  • I. Ozdemir, M. Şahin, R. Orhan, and M. Erdem, "Preparation and characterization of activated carbon from grape stalk by zinc chloride activation," Fuel Processing Technology, vol. 125, pp. 200-206, 2014.
  • M. Erdem, R. Orhan, M. Şahin, and E. Aydın, "Preparation and Characterization of a Novel Activated Carbon from Vine Shoots by ZnCl2 Activation and Investigation of Its Rifampicine Removal Capability," Water Air Soil Pollut, vol. 227, pp. 226-240, 2016.
  • P. Hadi, M. Xu, C. Ning, C. S. K. Lin, and G. Mc Kay, "A critical review on preparation, characterization and utilization of sludge-derived activated carbons for wastewater treatment," Chemical Engineering Journal, vol. 260, pp. 895-906, 2015.
  • G. Yupeng, S. Y. Jurui Qi, Y. Kaifeng, W. Zichen, and X. Hongding, "Adsorption of Cr(VI) on micro-and mesoporous rice husk-based active carbon," Materials Chemistry and Physics, vol. 78, pp. 132-137, 2002.
  • J. Goel, K. Kadirvelu, C. Rajagopal, and V. K. Garg, "Removal of lead(II) by adsorption using treated granular activated carbon: batch and column studies," J. Hazard. Mater. B, vol. 125, pp. 211-220, 2005.
  • E. Malkoç, "Farklı adsorbent türleri ile sulardan ağır metallerin giderimi" Doktora Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Çevre Mühendisliği Anabilim Dalı, Erzurum, 2005.
  • V. Marinovic, M. Ristic, and M. Dostanic, "Dynamic adsorption of trinitrotoluene on granular activated carbon," Journal of Hazardous Materials, vol. 117, pp. 121-128, 2005.
  • S. Hashemian, K. Salari, and Z. A. Yazdi, "Preparation of activated carbon from agricultural wastes (almond shell and orange peel) for adsorption of 2-pic from aqueous solution," Journal of Industrial and Engineering Chemistry, vol. 20, pp. 1892-1900, 2014.
  • S. A. Torrellas, R. G. Lovera, N. Escalona, C. Sepülveda, J. L. Sotela, and J. Garcia, "Chemical-activated carbons from peach stones for the adsorption of emerging contaminants in aqueous solutions," Chemical Engineering Journal, vol. 279, pp. 788-798, 2015.
  • K. Vijayaraghavan, J. Jegan, K. Palanivelu, and M. Velan, "Removal of nickel(II) ions from aqueous solution using crab shell particles in a packed bed up flow column," J. Hazard. Mater, vol. 113B (1–3), pp. 223–230, 2004.
  • M. Foroughi-dahr, M. Esmaieli, H. Abolghasemi, A. Shojamoradi, and E. S. Pouya, "Continuous adsorption study of Congo red using tea waste in a fixed-bed column," Desalin. Water Treat, vol. 57, pp. 8437–8446, 2016.
  • I. Mobasherpour, e. Salahi, and A. Asjodi, "Research on the batch and fixed-bed column performance of red mud adsorbents for lead removal," Canadian Chemical Transactions, vol. 2(1), pp. 83-96, 2014.
  • P. Venkateswarlu, M. Venkata Ratnam, D. Subba Rao, and M. Venkateswara Rao, "Removal of chromium from an aqueous solution using Azadirachta indica (neem) leaf powder as an ad-sorbent," International Journal of Physical Sciences, vol. 2(8), pp. 188-195, 2007.
  • C. C. V. Cruz, A. C. A. Da Costa, C. A. Henriques, and A. S. Luna, "Kinetic modeling and equilib-rium studies during cadmium biosorption by dead Sargassum Sp.Biomass," Bioresource Technology, vol. 91(3), pp. 249-257, 2003.
  • R. L. Ramos, A. Juarez Martinez, and R. M. Guerro Coronado, "Adsorption of chromium (VI) from aqueous solutions on activated carbon, Water Science and Technology, vol. 30 (9), pp. 191-197, 1994.
  • V. Marinovic, M. Ristic, and M. Dostanic, "Dynamic adsorption of trinitrotoluene on granular activated carbon, " Journal of Hazardous Materials, vol. 117, pp. 121-128, 2005.
  • S. Sadaf, and H. N. Bhatti, "Evaluation of peanut husk as a novel, low cost biosorbent for the removal of Indosol Orange RSN dye from aqueous solutions: batch and fixed bed studies," Clean Technol Environ Policy, vol. 16, pp. 527-544, 2014.
  • Z. Z. Chowdhury, S. M. Zain, A. K. Rashid, and K. Khalid, "Linear regression analysis for kinetics and isotherm studies of sorption of manganese (II) ions onto activated palm ash from waste water," Orient. J. Chem, vol. 27(2), pp. 405-415, 2011.
  • M. El Haddad, R. Slimani, R. Mamouni, S. ElAntri, and S. Lazar, "Removal of two textile dyes from aqueous solutions onto calcined bones," Journal of the Association of Arab Universities for Basic and Applied Sciences, vol. 14(1), pp. 51-59, 2013.
Toplam 54 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Çevre Mühendisliği
Yazarlar

Bahdisen Gezer 0000-0002-2096-7185

Yayımlanma Tarihi 7 Ağustos 2020
Gönderilme Tarihi 9 Mart 2020
Kabul Tarihi 6 Haziran 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 9 Sayı: 2

Kaynak Göster

APA Gezer, B. (2020). Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 9(2), 770-780. https://doi.org/10.28948/ngumuh.700773
AMA Gezer B. Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD. NÖHÜ Müh. Bilim. Derg. Ağustos 2020;9(2):770-780. doi:10.28948/ngumuh.700773
Chicago Gezer, Bahdisen. “Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9, sy. 2 (Ağustos 2020): 770-80. https://doi.org/10.28948/ngumuh.700773.
EndNote Gezer B (01 Ağustos 2020) Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9 2 770–780.
IEEE B. Gezer, “Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD”, NÖHÜ Müh. Bilim. Derg., c. 9, sy. 2, ss. 770–780, 2020, doi: 10.28948/ngumuh.700773.
ISNAD Gezer, Bahdisen. “Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 9/2 (Ağustos 2020), 770-780. https://doi.org/10.28948/ngumuh.700773.
JAMA Gezer B. Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD. NÖHÜ Müh. Bilim. Derg. 2020;9:770–780.
MLA Gezer, Bahdisen. “Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 9, sy. 2, 2020, ss. 770-8, doi:10.28948/ngumuh.700773.
Vancouver Gezer B. Cu (II) ADSORPTION WITH ACTIVATED CARBON OBTAINED FROM SEA URCHIN PREPARED BY ULTRASOUND-ASSISTED METHOD. NÖHÜ Müh. Bilim. Derg. 2020;9(2):770-8.

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