Araştırma Makalesi
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NANO SERAMİK TAKVİYELİ ÜRETİLEN POLİMER KOMPOZİTLERİN KURU VE ALKİL BAZLI YAĞLI KOŞULLAR ALTINDAKİ TRİBOLOJİK ÖZELLİKLERİNİN ARAŞTIRILMASI

Yıl 2025, Cilt: 33 Sayı: 3, 1947 - 1954, 19.12.2025
https://doi.org/10.31796/ogummf.1672479

Öz

Bu çalışma, kuru ve polyalphaolefin (PAO) yağlanmış koşullar altında ultra yüksek moleküler ağırlıklı polietilen (UHMWPE) kompozitlerinin tribolojik performansı üzerindeki Al₂O₃ nanopartiküllerin etkisini araştırmaktadır. Deneysel değerlendirmeler, sürtünme katsayısı, aşınma oranı ve sertlik ölçümlerini içerirken, aşınma izlerinin optik mikroskopisi ile desteklenmiştir. Sonuçlar, Al₂O₃ nanopartiküllerin eklenmesinin kuru koşullar altında sürtünme ve aşınma oranlarını önemli ölçüde azalttığını, özellikle daha yüksek dolgu oranlarında (4 wt%) gösterdiğini ortaya koymuştur. PAO ile yağlama sürtünmeyi daha da azaltırken, yüksek dolgu içeriği (4 wt%) ise hafif bir şekilde sürtünmeyi artırmış ve partikül aglomerasyonu nedeniyle periyodik osilasyonlara yol açmıştır. Sertlik, Al₂O₃ içeriği arttıkça düzenli bir şekilde artarak nanopartiküllerin güçlendirici etkisini göstermiştir. Optik mikroskopi, aşınma mekanizmalarını doğrulamış ve yüksek dolgu yüklemelerinde partikül ayrışması sorunlarını vurgulamıştır. UHMWPE-Al₂O₃ kompozitlerinin tribolojik avantajlarını maksimize etmek için dolgu dağılımının optimize edilmesi ve uygun nanoparçacık konsantrasyonlarının korunması gerekmektedir. Potansiyel uygulamalar arasında rulman bileşenleri, biyomedikal implantlar ve endüstriyel sürtünmeli arayüzler yer almakta olup, nanopartikül aglomerasyonunun yönetilmesinde zorluklar devam etmektedir.

Kaynakça

  • Fu, Wenxin, Wei Bai, Sisi Jiang, Bryan T. Seymour, and Bin Zhao. 2018. “UCST-Type Thermoresponsive Polymers in Synthetic Lubricating Oil Polyalphaolefin (PAO).” Macromolecules 51(5):1674–80. doi:10.1021/acs.macromol.7b02755.
  • Golchin, Arash, Alexis Villain, and Nazanin Emami. 2017. “Tribological Behaviour of Nanodiamond Reinforced UHMWPE in Water-Lubricated Contacts.” Tribology International 110:195–200. doi:10.1016/j.triboint.2017.01.016.
  • Hackler, Ryan A., Philip J. Griffin, Amgad Elgowainy, Uddhav Kanbur, Kimaya Vyavhare, Robert M. Kennedy, Ali Erdemir, Guiyan Zang, Pingping Sun, Kenneth R. Poeppelmeier, Massimiliano Delferro, Gokhan Celik, and Aaron D. Sadow. 2021. “Synthetic Lubricants Derived from Plastic Waste and Their Tribological Performance.” ChemSusChem 14. doi:10.1002/cssc.202100912.
  • Hardiman, M., T. J. Vaughan, and C. T. McCarthy. 2016. “The Effects of Pile-up, Viscoelasticity and Hydrostatic Stress on Polymer Matrix Nanoindentation.” Polymer Testing 52:157–66. doi:10.1016/j.polymertesting.2016.04.003.
  • Hussain, Muzamil, Naseem Abbas, Muhammad Waqas Khalid, Rizwan Ali Naqvi, Nida Zahra, Shahzad Masood Khan, Saad Nawaz, and Arif Hussain. 2020. “Ultra-High-Molecular-Weight-Polyethylene (UHMWPE) as a Promising Polymer Material for Biomedical Applications: A Concise Review.” Polymers 12. doi:10.3390/polym12020323.
  • Kumar, Homender, and A. P. Harsha. 2021. “Augmentation in Tribological Performance of Polyalphaolefins by COOH-Functionalized Multiwalled Carbon Nanotubes as an Additive in Boundary Lubrication Conditions.” Journal of Tribology 143(102202). doi:10.1115/1.4051392.
  • Macuvele, Domingos Lusitâneo Pier, Janaína Nones, Jonas V. Matsinhe, Marla M. Lima, Cíntia Soares, Márcio A. Fiori, and Humberto G. Riella. 2017. “Advances in Ultra High Molecular Weight Polyethylene/Hydroxyapatite Composites for Biomedical Applications: A Brief Review.” Materials Science and Engineering: C 76:1248–62. doi:10.1016/j.msec.2017.02.070.
  • Manoj Kumar, R., Sandan Kumar Sharma, B. V. Manoj Kumar, and Debrupa Lahiri. 2015. “Effects of Carbon Nanotube Aspect Ratio on Strengthening and Tribological Behavior of Ultra High Molecular Weight Polyethylene Composite.” Composites Part A: Applied Science and Manufacturing 76:62–72. doi:10.1016/j.compositesa.2015.05.007.
  • Movva, Sahitya, Reeshemah K. Burrell, Hamid Garmestani, and Karl I. Jacob. 2023. “Characterization of Hardness and Elastic Modulus Using Nanoindentation and Correlation with Wear Behavior of UHMWPE during Uniaxial Tension.” Journal of the Mechanical Behavior of Biomedical Materials 147:106142. doi:10.1016/j.jmbbm.2023.106142.
  • Pang, Wenchao, Zifeng Ni, JiaLiang Wu, and Yongwu Zhao. 2018. “Investigation of Tribological Properties of Graphene Oxide Reinforced Ultrahigh Molecular Weight Polyethylene under Artificial Seawater Lubricating Condition.” Applied Surface Science 434:273–82. doi:10.1016/j.apsusc.2017.10.115.
  • Panin, S. V., L. A. Kornienko, T. Nguen Suan, L. R. Ivanova, M. A. Korchagin, S. V. Shil’ko, and Yu. M. Pleskachevskii. 2015. “Wear Resistance of Composites Based on Hybrid UHMWPE–PTFE Matrix: Mechanical and Tribotechnical Properties of the Matrix.” Journal of Friction and Wear 36(3):249–56. doi:10.3103/S1068366615030113.
  • Peña-Parás, Laura, Jaime Taha-Tijerina, Lorena Garza, Demófilo Maldonado-Cortés, Remigiusz Michalczewski, and Carolina Lapray. 2015. “Effect of CuO and Al 2 O 3 Nanoparticle Additives on the Tribological Behavior of Fully Formulated Oils.” Wear 332–333:1256–61. doi:10.1016/j.wear.2015.02.038.
  • Ruggiero, Alessandro, Roberto D׳Amato, Emilio Gómez, and Massimiliano Merola. 2016. “Experimental Comparison on Tribological Pairs UHMWPE/TIAL6V4 Alloy, UHMWPE/AISI316L Austenitic Stainless and UHMWPE/AL2O3 Ceramic, under Dry and Lubricated Conditions.” Tribology International 96:349–60. doi:10.1016/j.triboint.2015.12.041.
  • Samad, M. Abdul, and Sujeet K. Sinha. 2011. “Dry Sliding and Boundary Lubrication Performance of a UHMWPE/CNTs Nanocomposite Coating on Steel Substrates at Elevated Temperatures.” Wear 270(5–6):395–402. doi:10.1016/j.wear.2010.11.011.
  • Sun, Lan-Hui, Zhen-Guo Yang, and Xiao-Hui Li. 2008. “Study on the Friction and Wear Behavior of POM/Al2O3 Nanocomposites.” Wear 264(7):693–700. doi:10.1016/j.wear.2007.06.005.
  • Wang, Yanzhen, Zhongwei Yin, Hulin Li, Gengyuan Gao, and Xiuli Zhang. 2017. “Friction and Wear Characteristics of Ultrahigh Molecular Weight Polyethylene (UHMWPE) Composites Containing Glass Fibers and Carbon Fibers under Dry and Water-Lubricated Conditions.” Wear 380–381:42–51. doi:10.1016/j.wear.2017.03.006.
  • Xu, Jimin, Xing Gao, Hang Dou, Cuiping Zhang, Wei Wang, and Kun Liu. 2023. “Improved Cryogenic Frictional Properties of Thrust Ball Bearings in Liquid Nitrogen through PTFE Cages and Dimple-Type Textures.” Cryogenics 135:103748. doi:10.1016/j.cryogenics.2023.103748.

INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS

Yıl 2025, Cilt: 33 Sayı: 3, 1947 - 1954, 19.12.2025
https://doi.org/10.31796/ogummf.1672479

Öz

This study investigates the influence of Al₂O₃ nanoparticles on the tribological performance of ultra-high molecular weight polyethylene (UHMWPE) composites under dry and polyalphaolefin (PAO)-lubricated conditions. Experimental evaluations included measurements of friction coefficient, wear rate, and hardness, complemented by optical microscopy of wear tracks. Results indicated that incorporating Al₂O₃ cut μ from 0.12 to 0.07 and V̇ from 4.3 × 10⁻⁶ to 1.6 × 10⁻⁶ mm³ N⁻¹ m⁻¹ under dry sliding (4 wt % filler). With PAO, an optimum 2 wt % loading yielded μ ≈ 0.05 and V̇ ≈ 1.1 × 10⁻⁶ mm³ N⁻¹ m⁻¹. Hardness rose by ≈ 22 %,confirming the reinforcing effect of the nanoparticles. Optical microscopy confirmed ploughing wear mechanisms and highlighted issues of particle segregation at elevated filler loadings. Optimizing filler dispersion and maintaining appropriate nanoparticle concentrations are essential for maximizing the tribological advantages of UHMWPE-Al₂O₃ composites. Potential applications include bearing components, biomedical implants, and industrial sliding interfaces, while challenges remain in managing nanoparticle agglomeration.

Kaynakça

  • Fu, Wenxin, Wei Bai, Sisi Jiang, Bryan T. Seymour, and Bin Zhao. 2018. “UCST-Type Thermoresponsive Polymers in Synthetic Lubricating Oil Polyalphaolefin (PAO).” Macromolecules 51(5):1674–80. doi:10.1021/acs.macromol.7b02755.
  • Golchin, Arash, Alexis Villain, and Nazanin Emami. 2017. “Tribological Behaviour of Nanodiamond Reinforced UHMWPE in Water-Lubricated Contacts.” Tribology International 110:195–200. doi:10.1016/j.triboint.2017.01.016.
  • Hackler, Ryan A., Philip J. Griffin, Amgad Elgowainy, Uddhav Kanbur, Kimaya Vyavhare, Robert M. Kennedy, Ali Erdemir, Guiyan Zang, Pingping Sun, Kenneth R. Poeppelmeier, Massimiliano Delferro, Gokhan Celik, and Aaron D. Sadow. 2021. “Synthetic Lubricants Derived from Plastic Waste and Their Tribological Performance.” ChemSusChem 14. doi:10.1002/cssc.202100912.
  • Hardiman, M., T. J. Vaughan, and C. T. McCarthy. 2016. “The Effects of Pile-up, Viscoelasticity and Hydrostatic Stress on Polymer Matrix Nanoindentation.” Polymer Testing 52:157–66. doi:10.1016/j.polymertesting.2016.04.003.
  • Hussain, Muzamil, Naseem Abbas, Muhammad Waqas Khalid, Rizwan Ali Naqvi, Nida Zahra, Shahzad Masood Khan, Saad Nawaz, and Arif Hussain. 2020. “Ultra-High-Molecular-Weight-Polyethylene (UHMWPE) as a Promising Polymer Material for Biomedical Applications: A Concise Review.” Polymers 12. doi:10.3390/polym12020323.
  • Kumar, Homender, and A. P. Harsha. 2021. “Augmentation in Tribological Performance of Polyalphaolefins by COOH-Functionalized Multiwalled Carbon Nanotubes as an Additive in Boundary Lubrication Conditions.” Journal of Tribology 143(102202). doi:10.1115/1.4051392.
  • Macuvele, Domingos Lusitâneo Pier, Janaína Nones, Jonas V. Matsinhe, Marla M. Lima, Cíntia Soares, Márcio A. Fiori, and Humberto G. Riella. 2017. “Advances in Ultra High Molecular Weight Polyethylene/Hydroxyapatite Composites for Biomedical Applications: A Brief Review.” Materials Science and Engineering: C 76:1248–62. doi:10.1016/j.msec.2017.02.070.
  • Manoj Kumar, R., Sandan Kumar Sharma, B. V. Manoj Kumar, and Debrupa Lahiri. 2015. “Effects of Carbon Nanotube Aspect Ratio on Strengthening and Tribological Behavior of Ultra High Molecular Weight Polyethylene Composite.” Composites Part A: Applied Science and Manufacturing 76:62–72. doi:10.1016/j.compositesa.2015.05.007.
  • Movva, Sahitya, Reeshemah K. Burrell, Hamid Garmestani, and Karl I. Jacob. 2023. “Characterization of Hardness and Elastic Modulus Using Nanoindentation and Correlation with Wear Behavior of UHMWPE during Uniaxial Tension.” Journal of the Mechanical Behavior of Biomedical Materials 147:106142. doi:10.1016/j.jmbbm.2023.106142.
  • Pang, Wenchao, Zifeng Ni, JiaLiang Wu, and Yongwu Zhao. 2018. “Investigation of Tribological Properties of Graphene Oxide Reinforced Ultrahigh Molecular Weight Polyethylene under Artificial Seawater Lubricating Condition.” Applied Surface Science 434:273–82. doi:10.1016/j.apsusc.2017.10.115.
  • Panin, S. V., L. A. Kornienko, T. Nguen Suan, L. R. Ivanova, M. A. Korchagin, S. V. Shil’ko, and Yu. M. Pleskachevskii. 2015. “Wear Resistance of Composites Based on Hybrid UHMWPE–PTFE Matrix: Mechanical and Tribotechnical Properties of the Matrix.” Journal of Friction and Wear 36(3):249–56. doi:10.3103/S1068366615030113.
  • Peña-Parás, Laura, Jaime Taha-Tijerina, Lorena Garza, Demófilo Maldonado-Cortés, Remigiusz Michalczewski, and Carolina Lapray. 2015. “Effect of CuO and Al 2 O 3 Nanoparticle Additives on the Tribological Behavior of Fully Formulated Oils.” Wear 332–333:1256–61. doi:10.1016/j.wear.2015.02.038.
  • Ruggiero, Alessandro, Roberto D׳Amato, Emilio Gómez, and Massimiliano Merola. 2016. “Experimental Comparison on Tribological Pairs UHMWPE/TIAL6V4 Alloy, UHMWPE/AISI316L Austenitic Stainless and UHMWPE/AL2O3 Ceramic, under Dry and Lubricated Conditions.” Tribology International 96:349–60. doi:10.1016/j.triboint.2015.12.041.
  • Samad, M. Abdul, and Sujeet K. Sinha. 2011. “Dry Sliding and Boundary Lubrication Performance of a UHMWPE/CNTs Nanocomposite Coating on Steel Substrates at Elevated Temperatures.” Wear 270(5–6):395–402. doi:10.1016/j.wear.2010.11.011.
  • Sun, Lan-Hui, Zhen-Guo Yang, and Xiao-Hui Li. 2008. “Study on the Friction and Wear Behavior of POM/Al2O3 Nanocomposites.” Wear 264(7):693–700. doi:10.1016/j.wear.2007.06.005.
  • Wang, Yanzhen, Zhongwei Yin, Hulin Li, Gengyuan Gao, and Xiuli Zhang. 2017. “Friction and Wear Characteristics of Ultrahigh Molecular Weight Polyethylene (UHMWPE) Composites Containing Glass Fibers and Carbon Fibers under Dry and Water-Lubricated Conditions.” Wear 380–381:42–51. doi:10.1016/j.wear.2017.03.006.
  • Xu, Jimin, Xing Gao, Hang Dou, Cuiping Zhang, Wei Wang, and Kun Liu. 2023. “Improved Cryogenic Frictional Properties of Thrust Ball Bearings in Liquid Nitrogen through PTFE Cages and Dimple-Type Textures.” Cryogenics 135:103748. doi:10.1016/j.cryogenics.2023.103748.
Toplam 17 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Tasarım ve Davranışları
Bölüm Araştırma Makalesi
Yazarlar

Gökçe Mehmet Ay 0000-0001-8354-5070

Esad Kaya 0000-0002-7332-6154

Gönderilme Tarihi 10 Nisan 2025
Kabul Tarihi 24 Haziran 2025
Yayımlanma Tarihi 19 Aralık 2025
Yayımlandığı Sayı Yıl 2025 Cilt: 33 Sayı: 3

Kaynak Göster

APA Ay, G. M., & Kaya, E. (2025). INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, 33(3), 1947-1954. https://doi.org/10.31796/ogummf.1672479
AMA Ay GM, Kaya E. INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS. ESOGÜ Müh Mim Fak Derg. Aralık 2025;33(3):1947-1954. doi:10.31796/ogummf.1672479
Chicago Ay, Gökçe Mehmet, ve Esad Kaya. “INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 33, sy. 3 (Aralık 2025): 1947-54. https://doi.org/10.31796/ogummf.1672479.
EndNote Ay GM, Kaya E (01 Aralık 2025) INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 33 3 1947–1954.
IEEE G. M. Ay ve E. Kaya, “INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS”, ESOGÜ Müh Mim Fak Derg, c. 33, sy. 3, ss. 1947–1954, 2025, doi: 10.31796/ogummf.1672479.
ISNAD Ay, Gökçe Mehmet - Kaya, Esad. “INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 33/3 (Aralık2025), 1947-1954. https://doi.org/10.31796/ogummf.1672479.
JAMA Ay GM, Kaya E. INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS. ESOGÜ Müh Mim Fak Derg. 2025;33:1947–1954.
MLA Ay, Gökçe Mehmet ve Esad Kaya. “INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, c. 33, sy. 3, 2025, ss. 1947-54, doi:10.31796/ogummf.1672479.
Vancouver Ay GM, Kaya E. INVESTIGATION OF TRIBOLOGICAL PROPERTIES OF POLYMER COMPOSITES PRODUCED WITH NANO CERAMIC REINFORCEMENT UNDER DRY AND ALKYL BASED OIL CONDITIONS. ESOGÜ Müh Mim Fak Derg. 2025;33(3):1947-54.

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