INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS

Sezer Çetin; Mehmet Uğur Toprak; Seher Güz

doi:10.31796/ogummf.902041

TR EN

INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS

Öz

Kaolin based one-part geopolymers (produced by adding water to preground aluminosilicate+alkali mixture) were produced in this study. Effect of and silica fume addition and prewaiting time on microstructure, mechanical and mineralogical properties of geopolymers evaluated with X–ray Fluorescence (XRF), X–ray diffractometer (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectrometer (FT–IR). Kaolin based one-part geopolymers gained 7-day compressive strength of 66.73 MPa while silica fume addition enhanced the strength up to 88.57 MPa.

Anahtar Kelimeler

Kaolin, Geopolymer, Aluminosilicate, Silica fume, Sodium hydroxide

Kaynakça

Al Bakri Abdullah, M. M., Liew, Y. M., Heah, C. Y., & Mohd Tahir, M. F. (2018). Clay-Based Materials in Geopolymer Technology. Cement Based Materials. doi:10.5772/intechopen.74438
Aldred, J. M., Bury, M. A., Detwiler, R. J., Fouad, F. H., Halczak, W., Holland, T. C., . . . Zhang, M.-H. (2000). Guide for the Use of Silica Fume in Concrete. Report by ACI Committee
Allahverdi, A., Mehrpour, K., & Kani, E. N. (2008). Investigating The Possibility of Utilizing Pucime-Type Natural Pozzonal in Production of Geopolymer Cement. Ceramics silikaty, 52(1), 16-23.
Alonso, S., & Palomo, A. (2001). Calorimetric Study of Alkaline Activation of Calcium Hydroxide-Metakaolin Solid Mixtures. Cement and Concrete Research, 31(1), 25-30. doi:10.1016/S0008-8846(00)00435-X
Davidovits, J. (1976). Solid-Phase Synthesis of a Mineral Blockpolymer by Low Temperature Polycondensation of Alumino-Silicate Polymers: Na-poly(sialate) or Na-PS and Characteristics. IUPAC Symposium on Long-Term Properties of Polymers and Polymeric. Stockholm, Sweden.
Davidovits, J. (1982). The Need to Create a New Technical Language for the Transfer of Basic Scientific Information. Transfer and Exploitation of Scientific and Technical Information, 316 – 320. Luxemburg.
Davidovits, J. (1988). Geopolymer Chemistry and Properties. 1st International Conference on Geopolymer, 1, 25-48. Compiegne.
Davidovits, J. (1991). GEOPOLYMERS: Inorganic polymeric new materials. Journal of Thermal Analysis and Calorimetry, 37, 1633–1656. doi:10.1007/bf01912193
Davidovits, J. (1994). Geopolymers: Man-made rock geosynthesis and the resulting development of very early high strength cement. Journal Materials Education, 16, 91-139.
Dimas, D. D., Giannopoulou, I. P., & Panias , D. (2009). Utilization of Alumina Red Mud for Synthesis of Inorganic Polymeric Materials. Mineral Processing and Extractive Metallurgy Review, 30, 211-239. doi:10.1080/08827500802498199

Duxson, P. (2009). Geopolymer precursor design. In J. S. John L. Provis, Geopolymers, 37-49. Abington Hall, Granta Park, Great Abington, Cambridge: Woodhead Publishing Limited. doi:10.1533/9781845696382.1.37
Duxson, P., Fernández-Jiménez, A., Provis, J. L., Lukey, G. C., Palomo, A., & van Deventer, J. S. (2007). Geopolymer technology: the current state of the art. Journal of Materials Science, 42, 2917–2933. doi:10.1007/s10853-006-0637-z
Hajimohammadi, A., Provis, J. L., & van Deventer, J. S. (2008). One-Part Geopolymer Mixes from Geothermal Silica and Sodium Aluminate. Industrial & Engineering Chemistry Research, 47, 9396-9405. doi:10.1021/ie8006825
Koloušek, D., Urbanova, M., Andertova, J., Hulinsky, V., & Vorel, J. (2007). Preparation, structure and hydrothermal stability of alternative (sodium silicate-free) geopolymers. Journal of Materials Science, 42, 9267–9275. doi:10.1007/s10853-007-1910-5
Komnitsas, K., & Zaharaki, D. (2007). Geopolymerisation: A Review and Prospects for the Minerals Industry. Minerals Engineering, 20(14), 1261-1277. doi:10.1016/j.mineng.2007.07.011
Konan, K. L., Peyratout, C., Smith, A., Bonnet, J.-P., Rossignol, S., & Oyetola, S. (2009). Comparison of surface properties between kaolin and metakaolin in concentrated lime solutions. Journal of Colloid and Interface Science, 339(1), 103-109. doi:10.1016/j.jcis.2009.07.019
Milkey, R. G. (1960). Infrared spectra of some tectosilicates. American Mineralogist: Journal of Earth and Planetary Materials, 45(9-10), 990-1007
Pacheco-Torgal, F., Castro-Gomes, J., & Jalali, S. (2008). Alkali-activated binders: A review: Part 1. Historical background, terminology, reaction mechanisms and hydration products. Construction and Building Materials, 22(7), 1305–1314. doi:10.1016/j.conbuildmat.2007.10.015
Palomo, A., Grutzeck, M. W., & Blanco-Varela, M. T. (1999). Alkali-Activated Fly Ashes - A Cement for the Future. Cement and Concrete Research, 29(8), 1323-1329. doi:10.1016/S0008-8846(98)00243-9
Peng, M. X., Wang, Z. H., Shen, S. H., & Xiao, Q. G. (2015). Synthesis, characterization and mechanisms of one-part geopolymeric cement by calcining low-quality kaolin with alkali. Materials and Structures, 48, 699–708. doi:10.1617/s11527-014-0350-3
Poon, C.-S., Lam, L., Kou, S., Wong, Y.-L., & Wong, R. (2001). Rate of pozzolanic reaction of metakaolin in high-performance cement pastes. Cement and Concrete Research, 31, 1301-1306. doi:10.1016/S0008-8846(01)00581-6
Provis, J. L. (2009). Activating solution chemistry for geopolymers. In J. L. Provis, & J. S. van Deventer, Geopolymers : structure, processing, properties and industrial applications, 50–71. Cambridge: Woodhead Publishing. doi:10.1533/9781845696382.1.50
Provis, J. L. (2014). Geopolymers and other alkali activated materials: why, how, and what? Materials and Structures, 47, 11–25. doi:10.1617/s11527-013-0211-5
Provis, J. L., & van Deventer, J. S. (2009). Introduction to geopolymers. In J. L. Provis, & J. J. van Deventer, Geopolymers : structure, processing, properties and industrial applications, 1-11. Cambridge: Woodhead Publishing. doi:10.1533/9781845696382.1
Provis, J. L., Duxson, P., Kavalerova, E., Krivenko, P. V., Pan, Z., Puertas, F., & van Deventer, J. S. (2014). Historical Aspects and Overview. In J. L. Provis, & J. S. van Deventer (Eds.), Alkali Activated Materials, 13, 11-57. Dordrecht: Springer. doi:10.1007/978-94-007-7672-2_2
Provis, J. L., Lukey, G. C., & van Deventer, J. S. (2005). Do Geopolymers Actually Contain Nanocrystalline Zeolites? A Reexamination of Existing Results. Chemistry of Materials, 17(12), 3075-3085. doi:10.1021/cm050230i
Shi, C., Fernández-Jiménez, A., & Palomo, A. (2011). New Cements for the 21st Century: The Pursuit of an Alternative to Portland Cement. Cement and Concrete Research, 41(7), 750-763. doi:10.1016/j.cemconres.2011.03.016
Shvarzman, A., Kovler, K., Grader, G., & Shter, G. (2003). The effect of dehydroxylation/amorphization degree on pozzolanic activity of kaolinite. Cement and Concrete Research, 33(3), 405-416. doi:10.1016/S0008-8846(02)00975-4
Sturm, P., Greiser, S., Gluth, G. J., Jäger, C., & Brouwers, H. (2015). Degree of reaction and phase content of silica-based one-part geopolymers investigated using chemical and NMR spectroscopic methods. Journal of Materials Science, 50, 6768–6778. doi:10.1007/s10853-015-9232-5
Tonak, T., Sipahi, F., & Atay, Y. (1997). Elektrometalurji Sanayii Atık Ürünü Silis Dumanı’nın Çimento Üretiminde Kullanılması. Endüstriyel Atıkların İnşaat Sektöründe Kullanılması Sempozyumu, 169-183. Ankara: TMMOB İnşaat Müh. Odası
van Jaarsveld, J. G., van Deventer, J. S., & Lukey, G. C. (2002). The Effect of Composition and Temperature on the Properties of Fly Ash- and Kaolinite-Based Geopolymers. Chemical Engineering Journal, 89(1-3), 63-73. doi:10.1016/S1385-8947(02)00025-6
Yeğinobalı, A. (2009). Silis Dumanı ve Çimento ile Betonda Kullanımı. Türkiye Çimento Müstahsilleri Birliği, 27-36

Ayrıntılar

Birincil Dil

İngilizce

Konular

İnşaat Mühendisliği

Bölüm

Araştırma Makalesi

Yazarlar

Sezer Çetin ^*
0000-0002-8976-3594
Türkiye

Mehmet Uğur Toprak
0000-0001-5483-2871
Türkiye

Seher Güz
0000-0003-4926-8035
Türkiye

Yayımlanma Tarihi

31 Ağustos 2021

Gönderilme Tarihi

25 Mart 2021

Kabul Tarihi

27 Mayıs 2021

Yayımlandığı Sayı

Yıl 2021 Cilt: 29 Sayı: 2

DOI

https://doi.org/10.31796/ogummf.902041

IZ

https://izlik.org/JA49UX65ZH

APA

Çetin, S., Toprak, M. U., & Güz, S. (2021). INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, 29(2), 172-181. https://doi.org/10.31796/ogummf.902041

AMA

1.Çetin S, Toprak MU, Güz S. INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS. ESOGÜ Müh Mim Fak Derg. 2021;29(2):172-181. doi:10.31796/ogummf.902041

Chicago

Çetin, Sezer, Mehmet Uğur Toprak, ve Seher Güz. 2021. “INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 29 (2): 172-81. https://doi.org/10.31796/ogummf.902041.

EndNote

Çetin S, Toprak MU, Güz S (01 Ağustos 2021) INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 29 2 172–181.

IEEE

[1]S. Çetin, M. U. Toprak, ve S. Güz, “INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS”, ESOGÜ Müh Mim Fak Derg, c. 29, sy 2, ss. 172–181, Ağu. 2021, doi: 10.31796/ogummf.902041.

ISNAD

Çetin, Sezer - Toprak, Mehmet Uğur - Güz, Seher. “INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 29/2 (01 Ağustos 2021): 172-181. https://doi.org/10.31796/ogummf.902041.

JAMA

1.Çetin S, Toprak MU, Güz S. INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS. ESOGÜ Müh Mim Fak Derg. 2021;29:172–181.

MLA

Çetin, Sezer, vd. “INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi, c. 29, sy 2, Ağustos 2021, ss. 172-81, doi:10.31796/ogummf.902041.

Vancouver

1.Sezer Çetin, Mehmet Uğur Toprak, Seher Güz. INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS. ESOGÜ Müh Mim Fak Derg. 01 Ağustos 2021;29(2):172-81. doi:10.31796/ogummf.902041

INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS

KAOLİN ESASLI TEK BİLEŞENLİ JEOPOLİMERLERİN İNCELENMESİ

Öz

Anahtar Kelimeler

INVESTIGATION OF KAOLIN BASED ONE PART GEOPOLYMERS

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster