Removal Of Dyestuff From Wastewater By Lewatit Monoplus M600

Yıl 2008, Cilt: 21 Sayı: 2, 163 - 181, 31.12.2008

T. Ennil Köse Uğur Selengil

Öz

In this study, removal of dyestuff from wastewater by strong base anion exchange resin was investigaled. The effecls of paramelers such as pH, contacl time, temperalure, resin dosage and initial concentration on dyestuff removal vere studied. Kinelic test was performed tofmdout the mass transfer mechanism oflhe sorption process of dyestuff. The isotherm data could be well described by the Langmuir and Freundlich egualions. The sorption capacity \vas found to be 26. 11 mgg by Langmuir isotherm. in the hatch desorplion process, various desorption solutions vere tesled. in the column study, the hreakthrough curve was obtained and capacity value ofthe resin was calculated.

Anahtar Kelimeler

Dyestvff, Ion-exchange, Lewatit MonoPlus M 600, Batch slucfy, Column study

Removal Of Dyestuff From Wastewater By Lewatit Monoplus M600

Öz

In this study,
removal of dyestuff from wastewater by strong base anion exchange resin was
investigaled. The effecls of paramelers such as pH, contacl time, temperalure,
resin dosage and initial concentration on dyestuff removal vere studied.
Kinelic test was performed tofmdout the mass transfer mechanism oflhe sorption
process of dyestuff. The isotherm data could be well described by the Langmuir
and Freundlich egualions. The sorption capacity \vas found to be 26. 11 mgg by
Langmuir isotherm. in the hatch desorplion process, various desorption
solutions vere tesled. in the column study, the hreakthrough curve was obtained
and capacity value ofthe resin was calculated.

Anahtar Kelimeler

Dyestvff, Ion-exchange, Lewatit MonoPlus M 600, Batch slucfy, Column study

Kaynakça

• [l] Z. Aksu and S. Tezer, "Biosorption ofreactive dyes on the green alga Chlorella Vulgaris", ProcessBiochem., Vo\. 40, pp. 1347-1361, 2005.
• [2] R. S. Juang, F.C. Wu and R. L. Tseng, "The ability ofactivated clay for the adsorption of dyes from aqueous solutions", Environ. Technol., Vol. 18, pp. 525-531, 1997.
• [3] C. H. Liu, J.S. Wu, H.C. Chiu, S.Y. Suen and K.H. Chu, "Removal ofanionic reactive dyes from water using anion exchange membranes as adsorbers", Water Res., Vol. 42, pp. 1491- 1500, 2007.
• |4] S.Karcher, A. Kornmüller and M. Jekel, "Screening of commercial sorbents for the remova\o{resctivedyes, ", Dyes mdPigmefits, Vo}. 51, pp. 111-125, 2001.
• [5] S. Raghu and C.A. Basha, "Chemical or electrochemical techniques, followed by ion exchange, for recycle oftextile dye wastewater", J. Hazard. Mater., Vol. 149, pp. 324-330, 2007.
• [6] G. McKay G, "Equilibrium studies for the adsorption of dyestuff from aqueous solutions by Iow-cost materials", WaterAir andSoil Poll., Vol. 29, pp. 273-283, 1986.
• [7] R. Han, D. Ding, Y. Xu, W. Zou, Y. Wang, Y, Li and L. Zou, "Use of rice husk for the adsorption of congo red from aqueous solution in column mode", Bioresource Technol., doi:10. 10I6/j. biotech. 2007. 06. 027, 2007.
• (8) M. Doğan and M. Alkan, "Removal ofmethyl violet from aqueous solution by perlite", J. Colloid Interf. Sci., Vol. 267, pp. 32-41, 2003.
• [9] N. Oztiirk and T.E. Bektaş, "Bateh adsorption of dyestuff from aqueous solutions onto various adsorbents", Fresen. Environ. Bull., Vol. 15, pp. 489-496, 2006.
• [10] F. Ferrero, "Dye removal by low cost adsorbents: Hazelnut shells in comparison with wood sawdust", J. Hazard. Mater., Vol. 142, pp. 144-152, 2007.
• [11] M.T. Sulak, E. Demirbaş and M. Kobya, "Removal ofAstrazon Yellovv 7GL from aqueous solutions by adsorption onto vvheat bran", Bioresource Technol., Vol. 98, pp. 2590-2598, 2007.
• [12] J.F. Osma, V. Saravia, J.L. Toca-Herrera and S.R. Couto, "Sunflovver seed shells: A novel and effective low-cost adsorbent for the removal ofthe diazo dye Reactive Black 5 from aqueous solutions", J. Hazard. Mater., Vol. 147, pp. 900-905, 2007.
• [13] LA.W. Tan, B.H. Hameed and L. Ahmad, "Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon", Chem. Eng. J., Vol. 127, pp. 111-119, 2007.
• [14] T.E. Köse, "Agricultural residue anion exchaııger far removal of dyestuff from wastewater using full factorial design", Desalinotion, Vol. 222, pp. 323-330, 200S.
• [15] L.C. Morais, O.M. Freitas, E. P. Goncalves, L.T. Vasconcelos and C.G. Gonzales Beca, Reactive dyes removal from wastewaters by adsorption on eucalyptus bark: Variables that define the process", fVaterRes., Vol. 33, pp. 979-988, 1999.
• [16] O. Levenspiel, "Chemical Reaction Engineering", 1 Edn, Wiley, New York, 1972.
• [17] J. L. Cortina, A. Warshawsky, "Developments - in solid-liquid extraction by solventimpregııated resins, lon Exchange and Solvent Extraction", L.A. Marinsky and Y. Marcus (Eds. ), Vol. 13, Marcel Dekker, Inc, New York, 1997. [I8] J. L. Cortina, A. Warshawsky, N. Kahara, V. Kampel, C.H. Sampaio and R. M. Kautzmann, "Kinetics of gold cyanide extraction using ion-exchange resins containing piperazine functionality", React. Funct. Polym., Vol. 54, pp. 25-35, 2003.
• [19] M. Badruk, N. Kabay, M. Demircioglu, H. Mordoğan and U. Ipekoglu, "Removal ofboron from wastewater of geothermal power plant by selective ion-exchange resins. [. Batch sorption-elution studies", Separ. Sci. Technol., Vol. 34, pp. 2553-2569, 1999.
• [20] R. Boncukoğlu, A. E. Yılmaz, M. M. Kocakerim and M. Çopur, "An empirical model far kinetics of baron removal from boron-containing wastewaters by ion exchange in a batch reactor", Desalination, Vol. 160, pp. 159-166, 2004.
• [21] W.J. Weber, "Physicochemical Processes for Water Quality Contro!", John Wiley and Sons, Inc, New York, 1972.
• [22] R.E. Treybal, "Mass Transfer Operaüom", 3'" Edn. McGraw Hill, Inc, Japan, 1980.
• [23] Z. Aksu and F. Gönen, "Biosorption of phenol by immobilized activated sludge in continuous packed bed: prediction ofbreakthrough curves", Process Biochem., Vol. 39, pp. 599-613. 2004.