Araştırma Makalesi
BibTex RIS Kaynak Göster

New Water-Soluble Polymers Based On Polyisobutylene

Yıl 1996, Cilt: 9 Sayı: 2, 33 - 40, 31.12.1996

Öz

New \vater-sohıble poîymers on the basis ofpofyi sobuîylene have been
synfhesized. The active groups (dichlorophosphoride) are added lo îhe pofymer chain
aa a resuU of ifs treafment by phosphorııs trichloride. in fhe presence of oxyg tl. Af fer
fhe jnteraction of fhe reaction prodvcf \vith sodivm hydroxi(3e and diefhylamine,
polymers which confain differenf funcîiom! gro. ı/ps have been obtained. H-NMR ai-ıcf
/R-specfm of fhese poîymers have been reçorded and fhermostabüıty of the modifled
polymers have invesfigafed by the ihermogravhneînc atiatys ıs mefhod. Sodmmconiaining
polymer has modifıed by alk^'i halıdes and their sıırface fension is
cSetermined by stalagmomeîric method.

Kaynakça

  • [l] J.P. Sduoeder. W.P. Sopchak, "ClıloiTlıosplıoıylation ofpolyetlıylene by phosphoms triı;Uorideanduxygen",. /Po/pn<îr, Scı.. Vul. 149, p. 417, 1960.
  • [2] Z.Manasec. D. Bellus, B. Bohmer, "Chlorophosphoıylated atactıc polypropylene", Chem. Zvesti. Vol. 17, p. 318, 1963.
  • [3] S. R. Rafikov, G. N. CheInokova, Ya. V.Aılemova, "Oxigative chlorophosphination of polyvmylacetate ", Vysokomb. soyed., Vol. 7, p. 1609, 1965(in Russian).
  • [4] S.R. Rafikov, G. N. Chelnokova, M. E, Ergebekov, T.V, Ershova, "Synthesis and stuty of polyalkyleneplıosplıinic acids", Vysokomb Soyed., Vol.7, p. 65, 1965 (in Russiau).
  • [5] E. C. Leonaıd. W. E. Loeb, J. H.Mason, W.L. Wheelwright, "New synthetic elastomer based on chlorophosphonated polyolcfin", J. Appl. Polymer Sci, Vol, 5, N. 14, p. 157, 1961.
  • [6] V.V. Koıshok, E. S.Krongays, A.M. Berlir. "Phosplıororganic polymerswith P-Nbonds". hvestia Akademi Nauk SSSR. old. chim. n.. N. 8, p. p. 1412-1416, 1962S (1n Russian),
  • [7] 1.0. Cleyloa aud W.U. Jensen, "Reaction ofPaıaffin Hydıocaıbons ıvitlı phosphouıs trichloride and Oxygen to produce alkanephosphonly chlorides", J. Americaıl Chem. Soc., Vol. 70, p. 3880, 1948.

New Water-Soluble Polymers Based On Polyisobutylene

Yıl 1996, Cilt: 9 Sayı: 2, 33 - 40, 31.12.1996

Öz

New \vater-sohıble poîymers on the basis ofpofyi sobuîylene have been

synfhesized. The active groups (dichlorophosphoride) are added lo îhe pofymer chain

aa a resuU of ifs treafment by phosphorııs trichloride. in fhe presence of oxyg tl. Af fer

fhe jnteraction of fhe reaction prodvcf \vith sodivm hydroxi(3e and diefhylamine,

polymers which confain differenf funcîiom! gro. ı/ps have been obtained. H-NMR ai-ıcf

/R-specfm of fhese poîymers have been reçorded and fhermostabüıty of the modifled

polymers have invesfigafed by the ihermogravhneînc atiatys ıs mefhod. Sodmmconiaining

polymer has modifıed by alk^'i halıdes and their sıırface fension is

cSetermined by stalagmomeîric method.

Kaynakça

  • [l] J.P. Sduoeder. W.P. Sopchak, "ClıloiTlıosplıoıylation ofpolyetlıylene by phosphoms triı;Uorideanduxygen",. /Po/pn<îr, Scı.. Vul. 149, p. 417, 1960.
  • [2] Z.Manasec. D. Bellus, B. Bohmer, "Chlorophosphoıylated atactıc polypropylene", Chem. Zvesti. Vol. 17, p. 318, 1963.
  • [3] S. R. Rafikov, G. N. CheInokova, Ya. V.Aılemova, "Oxigative chlorophosphination of polyvmylacetate ", Vysokomb. soyed., Vol. 7, p. 1609, 1965(in Russian).
  • [4] S.R. Rafikov, G. N. Chelnokova, M. E, Ergebekov, T.V, Ershova, "Synthesis and stuty of polyalkyleneplıosplıinic acids", Vysokomb Soyed., Vol.7, p. 65, 1965 (in Russiau).
  • [5] E. C. Leonaıd. W. E. Loeb, J. H.Mason, W.L. Wheelwright, "New synthetic elastomer based on chlorophosphonated polyolcfin", J. Appl. Polymer Sci, Vol, 5, N. 14, p. 157, 1961.
  • [6] V.V. Koıshok, E. S.Krongays, A.M. Berlir. "Phosplıororganic polymerswith P-Nbonds". hvestia Akademi Nauk SSSR. old. chim. n.. N. 8, p. p. 1412-1416, 1962S (1n Russian),
  • [7] 1.0. Cleyloa aud W.U. Jensen, "Reaction ofPaıaffin Hydıocaıbons ıvitlı phosphouıs trichloride and Oxygen to produce alkanephosphonly chlorides", J. Americaıl Chem. Soc., Vol. 70, p. 3880, 1948.
Toplam 7 adet kaynakça vardır.

Ayrıntılar

Konular Kimya Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Rasim Miralioğly Alosmanov Bu kişi benim

Majied Nourbakhsh Bu kişi benim

Alesker Abdulsaid Abdulğamidoğly Azızov Bu kişi benim

Vakif Malikoğly Akhmedov Bu kişi benim

Ziyafettin Hamidoğly Asadov Bu kişi benim

Yayımlanma Tarihi 31 Aralık 1996
Yayımlandığı Sayı Yıl 1996 Cilt: 9 Sayı: 2

Kaynak Göster

APA Alosmanov, R. M., Nourbakhsh, M., Azızov, A. A. A., Akhmedov, V. M., vd. (1996). New Water-Soluble Polymers Based On Polyisobutylene. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 9(2), 33-40.
AMA Alosmanov RM, Nourbakhsh M, Azızov AAA, Akhmedov VM, Asadov ZH. New Water-Soluble Polymers Based On Polyisobutylene. ESOGÜ Müh Mim Fak Derg. Aralık 1996;9(2):33-40.
Chicago Alosmanov, Rasim Miralioğly, Majied Nourbakhsh, Alesker Abdulsaid Abdulğamidoğly Azızov, Vakif Malikoğly Akhmedov, ve Ziyafettin Hamidoğly Asadov. “New Water-Soluble Polymers Based On Polyisobutylene”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 9, sy. 2 (Aralık 1996): 33-40.
EndNote Alosmanov RM, Nourbakhsh M, Azızov AAA, Akhmedov VM, Asadov ZH (01 Aralık 1996) New Water-Soluble Polymers Based On Polyisobutylene. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 9 2 33–40.
IEEE R. M. Alosmanov, M. Nourbakhsh, A. A. A. Azızov, V. M. Akhmedov, ve Z. H. Asadov, “New Water-Soluble Polymers Based On Polyisobutylene”, ESOGÜ Müh Mim Fak Derg, c. 9, sy. 2, ss. 33–40, 1996.
ISNAD Alosmanov, Rasim Miralioğly vd. “New Water-Soluble Polymers Based On Polyisobutylene”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 9/2 (Aralık 1996), 33-40.
JAMA Alosmanov RM, Nourbakhsh M, Azızov AAA, Akhmedov VM, Asadov ZH. New Water-Soluble Polymers Based On Polyisobutylene. ESOGÜ Müh Mim Fak Derg. 1996;9:33–40.
MLA Alosmanov, Rasim Miralioğly vd. “New Water-Soluble Polymers Based On Polyisobutylene”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, c. 9, sy. 2, 1996, ss. 33-40.
Vancouver Alosmanov RM, Nourbakhsh M, Azızov AAA, Akhmedov VM, Asadov ZH. New Water-Soluble Polymers Based On Polyisobutylene. ESOGÜ Müh Mim Fak Derg. 1996;9(2):33-40.

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