ANOT CÜRUFLARINDAN BAKIRIN GERİ KAZANIMINDA DÜŞÜK ERİME NOKTALI ÇÖZÜCÜ KULLANIMININ ARAŞTIRILMASI
Yıl 2020,
Cilt: 28 Sayı: 3, 308 - 320, 31.12.2020
Mehmet Ali Topçu
,
Aydın Rüşen
Öz
Bu çalışmada, ikincil kaynaklardan bakır tel üretimi yapan bir firmadan temin edilen bakır anot cürufundan bakır geri kazanımı için çevre ve insan sağlığına duyarlı düşük erime noktalı çözücü kullanımı araştırılmıştır. Bakır anot cürufunun fiziksel, kimyasal ve mineralojik karakterizasyonu öncesinde yapılan öğütme işleminde cüruf içindeki metalik bakırın bir kısmı fiziksel olarak ayrılmıştır. Liç deneylerinde son yıllarda hidrometalurjik süreçlerde kullanılan kolin klorür (ChCl) ve üre (1:2) ile hazırlanan düşük erime noktalı solvent çevre duyarlı çözücü olarak kullanılmıştır. Liç deneylerinin sonuçlarına göre fiziksel olarak anot cürufundan ayrılmayan bakır 72 saatlik reaksiyon süresi, 95 oC’lik liç sıcaklığı ve 1/20 katı/sıvı oranı şartlarındaki liç işlemi ile %90 üzerinde ekstrakte edilmiştir. Liç deneylerinden sonrasında çözeltideki demir çözünürlüğünün oldukça düşük seviyede kaldığı görülmüştür. Çalışmada elde edilen sonuçlara göre fiziksel olarak ayırma ve sonrasında ChCl-üre karışımıyla hazırlanan düşük erime noktalı çözücü kullanılarak yapılan liç işlemleri ile bakır anot cürufundan bakır geri kazanımı için çevreci bir çözücü adayı olabileceği ortaya konmuştur.
Destekleyen Kurum
Karamanoğlu Mehmetbey Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü
Proje Numarası
17 - M - 18
Teşekkür
Bu çalışmanın yapılmasını 17-M-18 proje numarası ile destekleyen Karamanoğlu Mehmetbey Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü’ne teşekkür ederiz.
Kaynakça
- Referans 1
Abbott, A. P., Capper, G., Davies, D.L., Rasheed, R. K., &Tambyrajah, V. (2003).Novel solvent properties o choline chloride/urea mixtures.Chemical Communications, (1), 70–71. doi: https://doi.org/10.1039/B210714G
- Referans 2
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004). Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. Journal of the American Chemical Society, 126(29), 9142-9147.doi: https://doi.org/10.1021/ja048266j
- Referans 3
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., &Shikotra, P. (2005). Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorganic Chemistry, 44(19), 6497-6499.doi: https://doi.org/10.1021/ic0505450
- Referans 4
Abbott, A. P., Capper, G., Davies, D. L., &Shikotra, P. (2006).Processing metal oxides using ionic liquids. Mineral Processing and Extractive Metallurgy, 115(1), 15-18.doi: https://doi.org/10.1039/C0GC00716A
- Referans 5
Abbott, A. P., Capper, G., Davies, D. L., McKenzie, K. J., & Obi, S. U. (2006).Solubility of metal oxides in deep eutectic solvents based on choline chloride. Journal of Chemical & Engineering Data, 51(4), 1280-1282.doi: https://doi.org/10.1021/je060038c
- Referans 6
Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007).Eutectic‐based ionic liquids with metal‐containing anions and cations. Chemistry-A European Journal, 13(22), 6495-6501.doi: https://doi.org/10.1002/chem.200601738
- Referans 7
Abbott, A. P., Collins, J., Dalrymple, I., Harris R. C., Mistry, R., Qiu, F., Scheirer, J., & Wise, R. W. (2009).Processing of electric arc furnace dust using deep eutectic solvents.Australian Journal of Chemistry, 62(4), 341 – 347.doi: https://doi.org/10.1071/CH08476
- Referans 8
Agrawal, A., Kumari, S., &Sahu, K. K. (2009). Iron and copper recovery/removal from industrial wastes: A review. Industrial & Engineering Chemistry Research, 48(13), 6145-6161.doi: https://doi.org/10.1021/ie900135u
- Referans 9
Arslan, C., &Arslan, F. (2002). Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy, 67(1-3), 1-7.doi:https://doi.org/10.1016/S0304-386X(02)00139-1
- Referans 10
Bakkar, A. (2014). Recycling of electric arc furnace dust through dissolution in deep eutectic ionic liquids and electrowinning. Journal of Hazardous Materials, 280, 191-199. doi: https://doi.org/10.1016/j.jhazmat.2014.07.066
- Referans 11
Banza, A. N., Gock, E., & Kongolo, K. (2002). Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction. Hydrometallurgy, 67(1-3), 63-69. doi: https://doi.org/10.1016/S0304-386X(02)00138-X
- Referans 12
Boyrazli, M., Altundogan, H. S., &Tümen, F. (2006).Recovery of metals from copper converter slag by leaching with K2Cr2O7-H2SO4. Canadian Metallurgical Quarterly, 45(2), 145-152.doi: https://doi.org/10.1179/cmq.2006.45.2.145
- Referans 13
Dai, Y., Van Spronsen, J., Witkamp, G. J., Verpoorte, R., & Choi, Y. H. (2013).Natural deep eutectic solvents as new potential media for green technology. AnalyticaChimicaActa, 766, 61-68.doi: https://doi.org/10.1016/j.aca.2012.12.019
- Referans 14
Delgado-Mellada, N., Laribba, M., Navarro, P., Rigual, V.,Ayuso, M., Garcia, J., & Rodriguez, F., (2018). Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis.Journal of Molecular Liquids, 260, 37 – 43.doi: https://doi.org/10.1016/j.molliq.2018.03.076
- Referans 15
Dong, T., Hua, Y., Zhang, Q., & Zhou, D. (2009).Leaching of chalcopyrite with Brønsted acidic ionic liquid. Hydrometallurgy, 99(1-2), 33-38.doi: https://doi.org/10.1016/j.hydromet.2009.06.001
- Referans 16
Huang, J., Chen, M., Chen, H., Chen, S., & Sun, Q. (2014).Leaching behavior of copper from waste printed circuit boards with Brønsted acidic ionic liquid. Waste Management, 34(2), 483-488.doi: https://doi.org/10.1016/j.wasman.2013.10.027
- Referans 17
Jalkanen, H., Vehviläinen, J., &Poijärvi, J. (2003).Copper in solidified copper smelter slags. Scandinavian Journal of Metallurgy, 32(2), 65-70.doi: https://doi.org/10.1034/j.16000692.2003.00536.x
- Referans 18
Lee, J., Kim, S., & Shin, D. (2015). Electrolytic recovery of Fe from Cu smelter slag in nitric acid solution. Journal of Applied Electrochemistry, 45(3), 281-288. doi: https://10.1007/s10800-015-0797-0
- Referans 19
Li, Y., Papangelakis, V. G., & Perederiy, I. (2009). High pressure oxidative acid leaching of nickel smelter slag: Characterization of feed and residue. Hydrometallurgy, 97(3-4), 185-193. doi: https://doi.org/10.1016/j.hydromet.2009.03.007
- Referans 20
Liu, W., Rao, S., Wang, W., Yang, T., Yang, L., Chen, L., & Zhang, D. (2015). Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst. International Journal of Mineral Processing, 141, 8-14.doi: https://doi.org/10.1016/j.minpro.2015.06.002
- Referans 20
Mihailova, I., &Mehandjiev, D. (2010).Characterization of fayalite from copper slags. Journal of the University of Chemical Technology and Metallurgy, 45(3), 317-326.Erişim adresi: https://dl.uctm.edu/journal/node/j20103/12_Irena_Mihailova_317-326.pdf
- Referans 21
Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014).Natural deep eutectic solvents–solvents for the 21st century. ACS Sustainable Chemistry & Engineering, 2(5), 1063-1071.doi:https://doi.org/10.1021/sc500096j
- Referans 22
Rüşen, A., &Topcu, M. A. (2017).Optimization of gold recovery from copper anode slime by acidic ionic liquid. Korean Journal of Chemical Engineering, 34(11), 2958-2965.doi: https://doi.org/10.1007/s11814-017-0200-4
- Referans 23
Rüşen, A., & Ali Topcu, M.A. (2017). Investigation of Various Metal Recoveries from Zinc Plant Leach Residue by Choline-Chloride Agent. Current Physical Chemistry, 7(4), 273-280. doi: https://doi.org/10.2174/1877946807666170808120341
- Referans 24
Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., &Ragauskas, A. J. (2018). Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. Biotechnology Advances , 36 (8), 2032-2050. doi: https://doi.org/10.1016/j.biotechadv.2018.08.009
- Referans 25
Topçu, M. A., Rüşen, A., &Derin, B. (2019). Minimizing of copper losses to converter slag by a boron compound addition. Journal of Materials Research and Technology, 8(6), 6244-6252.doi: https://doi.org/10.1016/j.jmrt.2019.10.018
- Referans 26
Whitehead, J. A., Zhang, J., Pereira, N., McCluskey, A., &Lawrance, G. A. (2007).Application of 1-alkyl-3-methyl-imidazolium ionic liquids in the oxidative leaching of sulphidic copper, gold and silver ores. Hydrometallurgy, 88(1-4), 109-120.doi: https://doi.org/10.1016/j.hydromet.2007.03.009
- Referans 27
Zhang, Q., Vigier, K. D., Royer, S., & Jerome, F. (2012). Deep eutectic solvents: syntheses, properties and applications. Chemical Society Reviews , 41, 7108-7146. doi: https://doi.org/10.1039/C2CS35178A
- Referans 28
Xiang, J., Huang, Q., Lv, X., & Bai, C. (2017). Multistage utilization process for the gradient-recovery of V, Fe, and Ti from vanadium-bearing converter slag. Journal of Hazardous Materials, 336, 1-7. doi: https://doi.org/10.1016/j.jhazmat.2017.04.060
- Referans 29
Xie, X., Zou, X., Lu, X., Zheng, K., Cheng, H., Xu, Q., & Zhou, Z. (2016).Voltammetric study and electrodeposition of Cu from CuO in deep eutectic solvents. Journal of The Electrochemical Society, 163(9),537 - 543. doi: https://doi.org/10.1149/2.1241609jes
INVESTIGATION OF USE OF DEEP EUTETIC SOLVENT ON COPPER RECOVERY FROM COPPER ANODE SLAG
Yıl 2020,
Cilt: 28 Sayı: 3, 308 - 320, 31.12.2020
Mehmet Ali Topçu
,
Aydın Rüşen
Proje Numarası
17 - M - 18
Kaynakça
- Referans 1
Abbott, A. P., Capper, G., Davies, D.L., Rasheed, R. K., &Tambyrajah, V. (2003).Novel solvent properties o choline chloride/urea mixtures.Chemical Communications, (1), 70–71. doi: https://doi.org/10.1039/B210714G
- Referans 2
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004). Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. Journal of the American Chemical Society, 126(29), 9142-9147.doi: https://doi.org/10.1021/ja048266j
- Referans 3
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., &Shikotra, P. (2005). Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorganic Chemistry, 44(19), 6497-6499.doi: https://doi.org/10.1021/ic0505450
- Referans 4
Abbott, A. P., Capper, G., Davies, D. L., &Shikotra, P. (2006).Processing metal oxides using ionic liquids. Mineral Processing and Extractive Metallurgy, 115(1), 15-18.doi: https://doi.org/10.1039/C0GC00716A
- Referans 5
Abbott, A. P., Capper, G., Davies, D. L., McKenzie, K. J., & Obi, S. U. (2006).Solubility of metal oxides in deep eutectic solvents based on choline chloride. Journal of Chemical & Engineering Data, 51(4), 1280-1282.doi: https://doi.org/10.1021/je060038c
- Referans 6
Abbott, A. P., Barron, J. C., Ryder, K. S., & Wilson, D. (2007).Eutectic‐based ionic liquids with metal‐containing anions and cations. Chemistry-A European Journal, 13(22), 6495-6501.doi: https://doi.org/10.1002/chem.200601738
- Referans 7
Abbott, A. P., Collins, J., Dalrymple, I., Harris R. C., Mistry, R., Qiu, F., Scheirer, J., & Wise, R. W. (2009).Processing of electric arc furnace dust using deep eutectic solvents.Australian Journal of Chemistry, 62(4), 341 – 347.doi: https://doi.org/10.1071/CH08476
- Referans 8
Agrawal, A., Kumari, S., &Sahu, K. K. (2009). Iron and copper recovery/removal from industrial wastes: A review. Industrial & Engineering Chemistry Research, 48(13), 6145-6161.doi: https://doi.org/10.1021/ie900135u
- Referans 9
Arslan, C., &Arslan, F. (2002). Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy, 67(1-3), 1-7.doi:https://doi.org/10.1016/S0304-386X(02)00139-1
- Referans 10
Bakkar, A. (2014). Recycling of electric arc furnace dust through dissolution in deep eutectic ionic liquids and electrowinning. Journal of Hazardous Materials, 280, 191-199. doi: https://doi.org/10.1016/j.jhazmat.2014.07.066
- Referans 11
Banza, A. N., Gock, E., & Kongolo, K. (2002). Base metals recovery from copper smelter slag by oxidising leaching and solvent extraction. Hydrometallurgy, 67(1-3), 63-69. doi: https://doi.org/10.1016/S0304-386X(02)00138-X
- Referans 12
Boyrazli, M., Altundogan, H. S., &Tümen, F. (2006).Recovery of metals from copper converter slag by leaching with K2Cr2O7-H2SO4. Canadian Metallurgical Quarterly, 45(2), 145-152.doi: https://doi.org/10.1179/cmq.2006.45.2.145
- Referans 13
Dai, Y., Van Spronsen, J., Witkamp, G. J., Verpoorte, R., & Choi, Y. H. (2013).Natural deep eutectic solvents as new potential media for green technology. AnalyticaChimicaActa, 766, 61-68.doi: https://doi.org/10.1016/j.aca.2012.12.019
- Referans 14
Delgado-Mellada, N., Laribba, M., Navarro, P., Rigual, V.,Ayuso, M., Garcia, J., & Rodriguez, F., (2018). Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis.Journal of Molecular Liquids, 260, 37 – 43.doi: https://doi.org/10.1016/j.molliq.2018.03.076
- Referans 15
Dong, T., Hua, Y., Zhang, Q., & Zhou, D. (2009).Leaching of chalcopyrite with Brønsted acidic ionic liquid. Hydrometallurgy, 99(1-2), 33-38.doi: https://doi.org/10.1016/j.hydromet.2009.06.001
- Referans 16
Huang, J., Chen, M., Chen, H., Chen, S., & Sun, Q. (2014).Leaching behavior of copper from waste printed circuit boards with Brønsted acidic ionic liquid. Waste Management, 34(2), 483-488.doi: https://doi.org/10.1016/j.wasman.2013.10.027
- Referans 17
Jalkanen, H., Vehviläinen, J., &Poijärvi, J. (2003).Copper in solidified copper smelter slags. Scandinavian Journal of Metallurgy, 32(2), 65-70.doi: https://doi.org/10.1034/j.16000692.2003.00536.x
- Referans 18
Lee, J., Kim, S., & Shin, D. (2015). Electrolytic recovery of Fe from Cu smelter slag in nitric acid solution. Journal of Applied Electrochemistry, 45(3), 281-288. doi: https://10.1007/s10800-015-0797-0
- Referans 19
Li, Y., Papangelakis, V. G., & Perederiy, I. (2009). High pressure oxidative acid leaching of nickel smelter slag: Characterization of feed and residue. Hydrometallurgy, 97(3-4), 185-193. doi: https://doi.org/10.1016/j.hydromet.2009.03.007
- Referans 20
Liu, W., Rao, S., Wang, W., Yang, T., Yang, L., Chen, L., & Zhang, D. (2015). Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst. International Journal of Mineral Processing, 141, 8-14.doi: https://doi.org/10.1016/j.minpro.2015.06.002
- Referans 20
Mihailova, I., &Mehandjiev, D. (2010).Characterization of fayalite from copper slags. Journal of the University of Chemical Technology and Metallurgy, 45(3), 317-326.Erişim adresi: https://dl.uctm.edu/journal/node/j20103/12_Irena_Mihailova_317-326.pdf
- Referans 21
Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014).Natural deep eutectic solvents–solvents for the 21st century. ACS Sustainable Chemistry & Engineering, 2(5), 1063-1071.doi:https://doi.org/10.1021/sc500096j
- Referans 22
Rüşen, A., &Topcu, M. A. (2017).Optimization of gold recovery from copper anode slime by acidic ionic liquid. Korean Journal of Chemical Engineering, 34(11), 2958-2965.doi: https://doi.org/10.1007/s11814-017-0200-4
- Referans 23
Rüşen, A., & Ali Topcu, M.A. (2017). Investigation of Various Metal Recoveries from Zinc Plant Leach Residue by Choline-Chloride Agent. Current Physical Chemistry, 7(4), 273-280. doi: https://doi.org/10.2174/1877946807666170808120341
- Referans 24
Satlewal, A., Agrawal, R., Bhagia, S., Sangoro, J., &Ragauskas, A. J. (2018). Natural deep eutectic solvents for lignocellulosic biomass pretreatment: Recent developments, challenges and novel opportunities. Biotechnology Advances , 36 (8), 2032-2050. doi: https://doi.org/10.1016/j.biotechadv.2018.08.009
- Referans 25
Topçu, M. A., Rüşen, A., &Derin, B. (2019). Minimizing of copper losses to converter slag by a boron compound addition. Journal of Materials Research and Technology, 8(6), 6244-6252.doi: https://doi.org/10.1016/j.jmrt.2019.10.018
- Referans 26
Whitehead, J. A., Zhang, J., Pereira, N., McCluskey, A., &Lawrance, G. A. (2007).Application of 1-alkyl-3-methyl-imidazolium ionic liquids in the oxidative leaching of sulphidic copper, gold and silver ores. Hydrometallurgy, 88(1-4), 109-120.doi: https://doi.org/10.1016/j.hydromet.2007.03.009
- Referans 27
Zhang, Q., Vigier, K. D., Royer, S., & Jerome, F. (2012). Deep eutectic solvents: syntheses, properties and applications. Chemical Society Reviews , 41, 7108-7146. doi: https://doi.org/10.1039/C2CS35178A
- Referans 28
Xiang, J., Huang, Q., Lv, X., & Bai, C. (2017). Multistage utilization process for the gradient-recovery of V, Fe, and Ti from vanadium-bearing converter slag. Journal of Hazardous Materials, 336, 1-7. doi: https://doi.org/10.1016/j.jhazmat.2017.04.060
- Referans 29
Xie, X., Zou, X., Lu, X., Zheng, K., Cheng, H., Xu, Q., & Zhou, Z. (2016).Voltammetric study and electrodeposition of Cu from CuO in deep eutectic solvents. Journal of The Electrochemical Society, 163(9),537 - 543. doi: https://doi.org/10.1149/2.1241609jes