Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers

Elif Aybike Berberoğlu; Mümin Mehmet Koç; Nurdan Kurnaz Yetim; Cemile Özcan

EN TR

Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers

Bu makalenin ilk hali 30 Haziran 2023 tarihinde yayımlandı. https://dergipark.org.tr/tr/pub/ojn/article/1192105

Düzeltme Notu

In the full text file of the article titled "Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers" by Elif Aybike BERBEROĞLU, Mümin Mehmet KOÇ, Nurdan KURNAZ YETİM and Cemile ÖZCAN, the article year 2023 and volume-number information should be 8-1, but it was mistakenly written as (2022) 7-2. The corrected article text is attached.

Öz

In this work, cobalt(II/III) oxide (Co3O4) nano/microflowers were practically synthesized in laboratory conditions. Adsorbence properties of the nanoflowers were investigated for the removal of cadmium and chromium heavy metal ions. To assess the chemical and morphological characteristics of Co3O4 nanoflowers, Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), field emission electron microscopy (FESEM), Energy dispersive spectroscopy (EDS), and was used. To determine the adsorbence mechanism in detail, eluent concentration, eluent type, solution pH, adsorbent amount, solution volume, and adsorption duration were studied. In these assessments, flame atomic absorption spectroscopy (FAAS) was used. For Cr6+, adsorption optimum parameters were determined as 3M HNO3, pH 6.5, 150mg, 30mL, 60min. For Cd2+, optimum parameters were determined as 3M HNO3, pH 6.0, 100mg, 10mL, 30min. Co3O4, nanoflowers are eco-friendly adsorbent materials for the adsorption of Cd6+ and Cd2+ heavy metal ions since the production method is affordable and practical.

Anahtar Kelimeler

Co3O4 Nanoflowers, Solid phase extraction, FAAS, Cr6+, Cd2+

Yüksek Toksisiteye Sahip Cd2+ and Cr6+ İyonlarının Karahindiba Şeklindeki Co3O4 Nanoçiçek Yapılar Kullanılarak Sonokimyasal Yöntemle Sudan Ayrıştırılması

Bu makalenin ilk hali 30 Haziran 2023 tarihinde yayımlandı. https://dergipark.org.tr/tr/pub/ojn/article/1192105

Düzeltme Notu

Elif Aybike BERBEROĞLU, Mümin Mehmet KOÇ, Nurdan KURNAZ YETİM ve Cemile ÖZCAN'ın yazarlığını yaptığı "Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers" başlıklı makalenin tam metin dosyasında makale yılı 2023 ve cilt-sayı bilgisi 8-1 olması gerekirken yanlışlıkla (2022) 7–2 şeklinde yazılmıştır. Düzeltilmiş makale metni ektedir.

Öz

Bu çalışmada, hidrotermal yöntem ile kobalt(II/III) oksit (Co3O4) nançiçek yapılar laboratuvar şartlarında pratik bir şekilde sentezlendi. Krom ve kadmiyum gibi ağır metal iyonlarının uzaklaştırılması için bu nanoflowerların adsorban olarak uygulanması araştırıldı. Co3O4 nanoçiçeklerinin, morfolojik analizi ve kimyasal bileşimini karakterize etmek için X ışını kırınım analizi (XRD), alan emisyonlu taramalı elektron mikroskopisi (FESEM), enerji dağılım X-ışınları spektroskopisi (EDS) ve FTIR teknikleri kullanılarak gerçekleştirildi. Adsorpsiyon sisteminin optimum koşullarını belirlemek amacı ile elüent derişimi ve türü, çözeltinin pH’ı, adsorban miktarı, çözelti hacmi ve adsorpsiyon süresi gibi parametrelerin etkisi incelendi. Elde edilen çözeltide metal iyonlarının alevli atomik absorpsiyon spektrometrisi (FAAS) analiz sonuçları doğrultusunda optimumum parametreler belirlendi. Bu paremetre sonuçları sırasıyla Co3O4 nanoflowerı ile Cr6+ için 3 M HNO3, pH 6.5, 150 mg, 30 mL, 60 dk; Cd2+ için 3 M HNO3, pH 6, 100 mg, 10 mL, 30 dk olarak bulundu. Co3O4 nanoçiçekleri; adsorpsiyon kapasitelerinin yüksek olması, kolayca sentezlenebilir ve imalat maliyetlerinin nispeten düşük olmasından dolayı krom, kadmiyum ve diğer ağır metal iyonlarının sulu sistemlerden uzaklaştırılmasında verimli ve çevre dostu adsorbanlar olabileceklerini göstermektedirler.

Anahtar Kelimeler

Co3O4 Nanoçiçekler, Katı faz ekstrasyonu, FAAS, Cr6+, Cd2+

Destekleyen Kurum

no funds

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Çevre Bilimleri

Bölüm

Düzeltme

Yazarlar

Elif Aybike Berberoğlu
0000-0003-0863-5927
Türkiye

Mümin Mehmet Koç
0000-0003-4500-0373
Türkiye

Nurdan Kurnaz Yetim
0000-0001-6227-0346
Türkiye

Cemile Özcan ^*
0000-0002-2954-0612
Türkiye

Yayımlanma Tarihi

29 Haziran 2024

Gönderilme Tarihi

-

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 2024 Cilt: 9 Sayı: 1

IZ

https://izlik.org/JA32KT26XH

APA

Berberoğlu, E. A., Koç, M. M., Kurnaz Yetim, N., & Özcan, C. (2024). Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers. Open Journal of Nano, 9(1), 63-76. https://izlik.org/JA32KT26XH

AMA

1.Berberoğlu EA, Koç MM, Kurnaz Yetim N, Özcan C. Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers. Open J. Nano. 2024;9(1):63-76. https://izlik.org/JA32KT26XH

Chicago

Berberoğlu, Elif Aybike, Mümin Mehmet Koç, Nurdan Kurnaz Yetim, ve Cemile Özcan. 2024. “Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers”. Open Journal of Nano 9 (1): 63-76. https://izlik.org/JA32KT26XH.

EndNote

Berberoğlu EA, Koç MM, Kurnaz Yetim N, Özcan C (01 Haziran 2024) Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers. Open Journal of Nano 9 1 63–76.

IEEE

[1]E. A. Berberoğlu, M. M. Koç, N. Kurnaz Yetim, ve C. Özcan, “Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers”, Open J. Nano, c. 9, sy 1, ss. 63–76, Haz. 2024, [çevrimiçi]. Erişim adresi: https://izlik.org/JA32KT26XH

ISNAD

Berberoğlu, Elif Aybike - Koç, Mümin Mehmet - Kurnaz Yetim, Nurdan - Özcan, Cemile. “Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers”. Open Journal of Nano 9/1 (01 Haziran 2024): 63-76. https://izlik.org/JA32KT26XH.

JAMA

1.Berberoğlu EA, Koç MM, Kurnaz Yetim N, Özcan C. Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers. Open J. Nano. 2024;9:63–76.

MLA

Berberoğlu, Elif Aybike, vd. “Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers”. Open Journal of Nano, c. 9, sy 1, Haziran 2024, ss. 63-76, https://izlik.org/JA32KT26XH.

Vancouver

1.Elif Aybike Berberoğlu, Mümin Mehmet Koç, Nurdan Kurnaz Yetim, Cemile Özcan. Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers. Open J. Nano [Internet]. 01 Haziran 2024;9(1):63-76. Erişim adresi: https://izlik.org/JA32KT26XH

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The Open Journal of Nano dergisinde yayınlanan tüm yayınlar Atıf-GayriTicari 4.0 Uluslararası (CC BY-NC 4.0) lisansı altında lisanlanmıştır.

Sonochemical Removal of Highly Toxic Aqueous Cd2+ and Cr6+ Ions Using Dandelion-like Co3O4 Nanoflowers

Düzeltme Notu

Öz

Anahtar Kelimeler

Yüksek Toksisiteye Sahip Cd2+ and Cr6+ İyonlarının Karahindiba Şeklindeki Co3O4 Nanoçiçek Yapılar Kullanılarak Sonokimyasal Yöntemle Sudan Ayrıştırılması

Düzeltme Notu

Öz

Anahtar Kelimeler

Destekleyen Kurum

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

IZ

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