Araştırma Makalesi
BibTex RIS Kaynak Göster

Sıvı kristaller ve nanopartikül arasındaki etkileşimlerin belirlenmesi üzerine çalışma: Nanopartikül katkılı sıvı kristallerin floresan spektrumları

Yıl 2023, Cilt: 8 Sayı: 1, 50 - 64, 30.06.2023
https://doi.org/10.56171/ojn.1225833

Öz

Maddenin katı hali ile sıvı hali arasında bulunan sıvı kristaller ilginç moleküler yapılara sahip malzemelerdir. Hem katı kristallerin özelliklerini hem de sıvıların özelliklerini gösteren moleküler malzemelerdir. Fiziksel özellikleri parçacık boyutuna bağlı olarak değişen, boyutları nanometre düzeyinde olan malzemeler nanoparçacıklardır. Nanopartiküller boyutlarına ve yapısal şekillerine bağlı olarak birçok farklı tipte üretilebilir. Sıvı kristaller ve nanoparçacıkları üç farklı özellikteki çözücülerde birleştirerek floresans grafikleri elde ettik. Bu çalışmada kullandığımız sıvı kristaller 4-Pentilfenil 4-Metoksibenzoat (4PP4MetoxB), 4-Pentilfenil 4-Pentilbenzot (4PP4PentB) ve 4-Pentilfenil 4-(Oktiloksi)Benzoattır (4PP4OktoksB). Kullandığımız diğer malzemeler ZnS, CdSe ve CdS nanoparçacıklarıdır. Bu sıvı kristalleri ve nanopartikülleri solventlerde birleştirerek yeni malzemeler yarattık. Yeni oluşan malzemelerdeki sıvı kristaller ve nanoparçacıkların çözücüler içinde etkileşime girip girmediğini ve sıvı kristallerin floresans grafiklerine göre floresans grafiklerinin nasıl değiştiğini inceledik.

Kaynakça

  • J. Beeckman, “Liquid-crystal photonic applications,” Optical Engineering, vol. 50, no. 8, p. 081202, 2011, doi: 10.1117/1.3565046.
  • T. Ikeda, “Photomodulation of liquid crystal orientations for photonic applications,” Journal of Materials Chemistry, vol. 13, no. 9, pp. 2037–2057, 2003, doi: 10.1039/b306216n.
  • H. Kawamoto, “The History of Liquid-Crystal Displays,” vol. 90, no. 4, 2006.
  • S. J. Woltman, G. D. Jay, and G. P. Crawford, “Liquid-crystal materials find a new order in biomedical applications,” Nature Materials, vol. 6, no. 12, pp. 929–938, 2007, doi: 10.1038/nmat2010.
  • J. P. F. Lagerwall and G. Scalia, “A new era for liquid crystal research: Applications of liquid crystals in soft matter nano-, bio- and microtechnology,” Current Applied Physics, vol. 12, no. 6, pp. 1387–1412, 2012, doi: 10.1016/j.cap.2012.03.019.
  • C. Noël and P. Navard, “Liquid crystal polymers,” Progress in Polymer Science, vol. 16, no. 1, pp. 55–110, Jan. 1991, doi: 10.1016/0079-6700(91)90007-8.
  • I. I. Smalyukh, “Liquid Crystal Colloids,” Annual Review of Condensed Matter Physics, vol. 9, no. November 2017, pp. 207–226, 2018, doi: 10.1146/annurev-conmatphys-033117-054102.
  • M. Bangal et al., “Semiconductor nanoparticles,” Hyperfine Interactions, vol. 160, no. 1–4, pp. 81–94, 2005, doi: 10.1007/s10751-005-9151-y.
  • K. J. Si, Y. Chen, Q. Shi, and W. Cheng, “Nanoparticle Superlattices: The Roles of Soft Ligands,” Advanced Science, vol. 5, no. 1, 2018, doi: 10.1002/advs.201700179.
  • J. R. Lakowicz, I. Gryczynski, Z. Gryczynski, and C. J. Murphy, “Luminescence spectral properties of CdS nanoparticles,” Journal of Physical Chemistry B, vol. 103, no. 36, pp. 7613–7620, 1999, doi: 10.1021/jp991469n.
  • T. Hegmann, H. Qi, and V. M. Marx, “Nanoparticles in liquid crystals: Synthesis, self-assembly, defect formation and potential applications,” Journal of Inorganic and Organometallic Polymers and Materials, vol. 17, no. 3, pp. 483–508, 2007, doi: 10.1007/s10904-007-9140-5.
  • R. K. Shukla, Y. G. Galyametdinov, R. R. Shamilov, and W. Haase, “Effect of CdSe quantum dots doping on the switching time, localised electric field and dielectric parameters of ferroelectric liquid crystal,” Liquid Crystals, vol. 41, no. 12, pp. 1889–1896, 2014, doi: 10.1080/02678292.2014.959571.
  • V. Kumar, A. Kumar, A. M. Biradar, G. B. Reddy, D. Sachdev, and R. Pasricha, “Enhancement of electro-optical response of ferroelectric liquid crystal: the role of graphene quantum dots,” Liquid Crystals, vol. 41, no. 12, pp. 1719–1725, 2014, doi: 10.1080/02678292.2014.949888.
  • A. Anczykowska, S. Bartkiewicz, M. Nyk, and J. Myśliwiec, “Enhanced photorefractive effect in liquid crystal structures co-doped with semiconductor quantum dots and metallic nanoparticles,” Applied Physics Letters, vol. 99, no. 19, pp. 1–4, 2011, doi: 10.1063/1.3659485.
  • L. J. Martínez-Miranda, K. M. Traister, I. Meĺndez-Rodríguez, and L. Salamanca-Riba, “Liquid crystal-ZnO nanoparticle photovoltaics: Role of nanoparticles in ordering the liquid crystal,” Applied Physics Letters, vol. 97, no. 22, 2010, doi: 10.1063/1.3511736.
  • T. Zhang, C. Zhong, and J. Xu, “CdS-Nanoparticle-doped liquid crystal displays showing low threshold voltage,” Japanese Journal of Applied Physics, vol. 48, no. 5, pp. 0550021–0550026, 2009, doi: 10.1143/JJAP.48.055002.
  • J. Tauc and A. Menth, “States in the gap,” Journal of Non-Crystalline Solids, vol. 8–10, no. C, pp. 569–585, 1972, doi: 10.1016/0022-3093(72)90194-9.
  • J. C. Tauc, “Semiconductor Amorphous and Liquid,” p. 195, 1974.
  • O. Baytar, O. Sahin, H. Kilicvuran, and S. Horoz, “Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 6, pp. 4564–4568, 2018, doi: 10.1007/s10854-017-8406-0.
  • S. Horoz et al., “CdSe quantum dots synthesized by laser ablation in water and their photovoltaic applications,” Applied Physics Letters, vol. 101, no. 22, pp. 1–5, 2012, doi: 10.1063/1.4768706.
  • O. Sahin and S. Horoz, “Synthesis of Ni:ZnS quantum dots and investigation of their properties,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 19, pp. 16775–16781, 2018, doi: 10.1007/s10854-018-9771-z.
  • OriginPro19b (Version 9.5), OriginLab Corporation, Northampton, MA (USA), 2022.
  • SpectraGryph 1.2, Spectroscopy Software, https://www.effemm2.de/spectragryph/down.html.
  • Y. Li, L. Ma, X. Zhang, A. G. Joly, Z. Liu, and W. Chen, “Synthesis and optical properties of sulfide nanoparticles prepared in dimethylsulfoxide,” Journal of Nanoscience and Nanotechnology, vol. 8, no. 11, pp. 5646–5651, Nov. 2008, doi: 10.1166/JNN.2008.474.
  • F. Rodríguez‐mas, J. C. Ferrer, J. L. Alonso, S. F. de Ávila, and D. Valiente, “Reduced Graphene Oxide Inserted into PEDOT:PSS Layer to Enhance the Electrical Behaviour of Light-Emitting Diodes,” Nanomaterials 2021, Vol. 11, Page 645, vol. 11, no. 3, p. 645, Mar. 2021, doi: 10.3390/NANO11030645.

The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals

Yıl 2023, Cilt: 8 Sayı: 1, 50 - 64, 30.06.2023
https://doi.org/10.56171/ojn.1225833

Öz

Liquid crystals, which are between the solid state of matter and the liquid state, are materials with interesting molecular structures. They are molecular materials that show both the properties of solid crystals and the properties of liquids. Materials whose physical properties change depending on the particle size, whose dimensions are at the nanometer level, are nanoparticles. Nanoparticles can be produced in many different types, depending on their size and structural shape. We obtained fluorescence graphs by combining liquid crystals and nanoparticles in solvents with three different characteristics. The liquid crystals we used in this study are 4-Pentylphenyl 4-Methoxybenzoate (4PP4MetoxB), 4-Pentylphenyl 4-Pentylbenzote (4PP4PentB), and 4-Pentylphenyl 4-(Octyloxy)Benzoate (4PP4OctoxB). Other materials we use are ZnS, CdSe, and CdS nanoparticles. We created new materials by combining these liquid crystals and nanoparticles in solvents. We examined whether the liquid crystals and nanoparticles in the newly formed materials interact in solvents and how the fluorescence graphs change according to the fluorescence graphs of liquid crystals.

Kaynakça

  • J. Beeckman, “Liquid-crystal photonic applications,” Optical Engineering, vol. 50, no. 8, p. 081202, 2011, doi: 10.1117/1.3565046.
  • T. Ikeda, “Photomodulation of liquid crystal orientations for photonic applications,” Journal of Materials Chemistry, vol. 13, no. 9, pp. 2037–2057, 2003, doi: 10.1039/b306216n.
  • H. Kawamoto, “The History of Liquid-Crystal Displays,” vol. 90, no. 4, 2006.
  • S. J. Woltman, G. D. Jay, and G. P. Crawford, “Liquid-crystal materials find a new order in biomedical applications,” Nature Materials, vol. 6, no. 12, pp. 929–938, 2007, doi: 10.1038/nmat2010.
  • J. P. F. Lagerwall and G. Scalia, “A new era for liquid crystal research: Applications of liquid crystals in soft matter nano-, bio- and microtechnology,” Current Applied Physics, vol. 12, no. 6, pp. 1387–1412, 2012, doi: 10.1016/j.cap.2012.03.019.
  • C. Noël and P. Navard, “Liquid crystal polymers,” Progress in Polymer Science, vol. 16, no. 1, pp. 55–110, Jan. 1991, doi: 10.1016/0079-6700(91)90007-8.
  • I. I. Smalyukh, “Liquid Crystal Colloids,” Annual Review of Condensed Matter Physics, vol. 9, no. November 2017, pp. 207–226, 2018, doi: 10.1146/annurev-conmatphys-033117-054102.
  • M. Bangal et al., “Semiconductor nanoparticles,” Hyperfine Interactions, vol. 160, no. 1–4, pp. 81–94, 2005, doi: 10.1007/s10751-005-9151-y.
  • K. J. Si, Y. Chen, Q. Shi, and W. Cheng, “Nanoparticle Superlattices: The Roles of Soft Ligands,” Advanced Science, vol. 5, no. 1, 2018, doi: 10.1002/advs.201700179.
  • J. R. Lakowicz, I. Gryczynski, Z. Gryczynski, and C. J. Murphy, “Luminescence spectral properties of CdS nanoparticles,” Journal of Physical Chemistry B, vol. 103, no. 36, pp. 7613–7620, 1999, doi: 10.1021/jp991469n.
  • T. Hegmann, H. Qi, and V. M. Marx, “Nanoparticles in liquid crystals: Synthesis, self-assembly, defect formation and potential applications,” Journal of Inorganic and Organometallic Polymers and Materials, vol. 17, no. 3, pp. 483–508, 2007, doi: 10.1007/s10904-007-9140-5.
  • R. K. Shukla, Y. G. Galyametdinov, R. R. Shamilov, and W. Haase, “Effect of CdSe quantum dots doping on the switching time, localised electric field and dielectric parameters of ferroelectric liquid crystal,” Liquid Crystals, vol. 41, no. 12, pp. 1889–1896, 2014, doi: 10.1080/02678292.2014.959571.
  • V. Kumar, A. Kumar, A. M. Biradar, G. B. Reddy, D. Sachdev, and R. Pasricha, “Enhancement of electro-optical response of ferroelectric liquid crystal: the role of graphene quantum dots,” Liquid Crystals, vol. 41, no. 12, pp. 1719–1725, 2014, doi: 10.1080/02678292.2014.949888.
  • A. Anczykowska, S. Bartkiewicz, M. Nyk, and J. Myśliwiec, “Enhanced photorefractive effect in liquid crystal structures co-doped with semiconductor quantum dots and metallic nanoparticles,” Applied Physics Letters, vol. 99, no. 19, pp. 1–4, 2011, doi: 10.1063/1.3659485.
  • L. J. Martínez-Miranda, K. M. Traister, I. Meĺndez-Rodríguez, and L. Salamanca-Riba, “Liquid crystal-ZnO nanoparticle photovoltaics: Role of nanoparticles in ordering the liquid crystal,” Applied Physics Letters, vol. 97, no. 22, 2010, doi: 10.1063/1.3511736.
  • T. Zhang, C. Zhong, and J. Xu, “CdS-Nanoparticle-doped liquid crystal displays showing low threshold voltage,” Japanese Journal of Applied Physics, vol. 48, no. 5, pp. 0550021–0550026, 2009, doi: 10.1143/JJAP.48.055002.
  • J. Tauc and A. Menth, “States in the gap,” Journal of Non-Crystalline Solids, vol. 8–10, no. C, pp. 569–585, 1972, doi: 10.1016/0022-3093(72)90194-9.
  • J. C. Tauc, “Semiconductor Amorphous and Liquid,” p. 195, 1974.
  • O. Baytar, O. Sahin, H. Kilicvuran, and S. Horoz, “Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 6, pp. 4564–4568, 2018, doi: 10.1007/s10854-017-8406-0.
  • S. Horoz et al., “CdSe quantum dots synthesized by laser ablation in water and their photovoltaic applications,” Applied Physics Letters, vol. 101, no. 22, pp. 1–5, 2012, doi: 10.1063/1.4768706.
  • O. Sahin and S. Horoz, “Synthesis of Ni:ZnS quantum dots and investigation of their properties,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 19, pp. 16775–16781, 2018, doi: 10.1007/s10854-018-9771-z.
  • OriginPro19b (Version 9.5), OriginLab Corporation, Northampton, MA (USA), 2022.
  • SpectraGryph 1.2, Spectroscopy Software, https://www.effemm2.de/spectragryph/down.html.
  • Y. Li, L. Ma, X. Zhang, A. G. Joly, Z. Liu, and W. Chen, “Synthesis and optical properties of sulfide nanoparticles prepared in dimethylsulfoxide,” Journal of Nanoscience and Nanotechnology, vol. 8, no. 11, pp. 5646–5651, Nov. 2008, doi: 10.1166/JNN.2008.474.
  • F. Rodríguez‐mas, J. C. Ferrer, J. L. Alonso, S. F. de Ávila, and D. Valiente, “Reduced Graphene Oxide Inserted into PEDOT:PSS Layer to Enhance the Electrical Behaviour of Light-Emitting Diodes,” Nanomaterials 2021, Vol. 11, Page 645, vol. 11, no. 3, p. 645, Mar. 2021, doi: 10.3390/NANO11030645.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Araştırma Makalesi
Yazarlar

Yunus Emre Kara 0000-0002-8412-6633

Yadigar Gülseven Sıdır 0000-0002-5329-2815

Sabit Horoz 0000-0002-3238-8789

Erken Görünüm Tarihi 8 Ağustos 2022
Yayımlanma Tarihi 30 Haziran 2023
Gönderilme Tarihi 29 Aralık 2022
Yayımlandığı Sayı Yıl 2023 Cilt: 8 Sayı: 1

Kaynak Göster

APA Kara, Y. E., Gülseven Sıdır, Y., & Horoz, S. (2023). The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. Open Journal of Nano, 8(1), 50-64. https://doi.org/10.56171/ojn.1225833
AMA Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. Haziran 2023;8(1):50-64. doi:10.56171/ojn.1225833
Chicago Kara, Yunus Emre, Yadigar Gülseven Sıdır, ve Sabit Horoz. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano 8, sy. 1 (Haziran 2023): 50-64. https://doi.org/10.56171/ojn.1225833.
EndNote Kara YE, Gülseven Sıdır Y, Horoz S (01 Haziran 2023) The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. Open Journal of Nano 8 1 50–64.
IEEE Y. E. Kara, Y. Gülseven Sıdır, ve S. Horoz, “The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals”, OJN, c. 8, sy. 1, ss. 50–64, 2023, doi: 10.56171/ojn.1225833.
ISNAD Kara, Yunus Emre vd. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano 8/1 (Haziran 2023), 50-64. https://doi.org/10.56171/ojn.1225833.
JAMA Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. 2023;8:50–64.
MLA Kara, Yunus Emre vd. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano, c. 8, sy. 1, 2023, ss. 50-64, doi:10.56171/ojn.1225833.
Vancouver Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. 2023;8(1):50-64.

Open Journal of Nano(OJN), dergisi molekülerden mikro boyuttaki yapılara kadar değişen fiziksel, kimyasal ve biyolojik olaylar ve süreçlerle ilgili (ancak bunlarla sınırlı olmayan) bilgilerle ilgilenir.
Cc_by-nc_icon.svgThe Open Journal of Nano dergisinde yayınlanan tüm yayınlar Atıf-GayriTicari 4.0 Uluslararası (CC BY-NC 4.0) lisansı altında lisanlanmıştır.