Nano Malzemelerle Modifiye Edilen Bitüm ve Bitümlü Karışımların Fiziksel ve Reolojik Özelliklerinin İncelenmesi: Literatür Araştırması

Yıl 2022, Cilt: 5 Sayı: 1, 429 - 448, 08.03.2022

Hatice Merve Çetin

https://doi.org/10.47495/okufbed.902416

Cited By: 1

Öz

İnşaa edilen yol kaplamaları; olumsuz iklim şartları, artan ve tekrarlı trafik yüklerden kaynaklı deformasyona uğramaktadır. Servis ömrünü tamamlayamadan bozulmaya uğrayan yollarda yapılan bakım ve onarım çalışmaları ise ülke ekonomisini önemli ölçüde etkilemektedir. Bu sebepten dolayı sürdürülebilir yol üstyapıları için gelişen teknoloji ve katkı malzemelerinin de kullanımıyla kaplamaların dayanımı arttırılarak servis ömrü uzatılabilmektedir. Bitüm ile farklı katkı malzemeleri modifiye edilerek dayanımı yüksek üstyapılar inşaa edilmekte ve kullanıma sunulmaktadır. Bu katkılar; endüstriyel atıklar, geri dönüştürülmüş malzemeler, polimerler ve nano malzemeler olarak sayılabilir. Nanoteknolojinin de gelişmesiyle bitüm modifikasyonunda nano malzemelerin kullanımı yaygınlaşmaya başlamıştır. Yapılan çalışmalarda bitüm; nanokiller, nanosilika, nano-CaCO3, nano-TiO2, nano karbon siyahı ve daha başka malzemelerle modifiye edilerek, bitümün reolojik ve fiziksel özellikleri incelenmiştir. Nano malzemelerin kullanılması ile bitümün, durabilitesi, suya karşı hassasiyeti, depolama stabilitesi ve daha birçok özelliğinde önemli iyileşmeler kaydedilmiştir. Bu çalışmamızda bu önemli konuda yapılan araştırmalar ve bu araştırmalar neticesinde elde edilen bulgular sunulacaktır.

Anahtar Kelimeler

Bitüm, Modifikasyon, Bitümlü karışımlar

Investigation of Physical and Rheological Properties of Bitumen and Bituminous Mixtures Modified with Nanomaterials: Literature Research

Öz

Road pavements are subject to deformation due to adverse climatic conditions, increasing and repetitive traffic loads. Maintenance and repairing works on damaged roads before completing their service life significantly affect the economy. For this reason, the service life of the pavements can be extended by increasing the strength of the coatings by means of developing technology and additives for sustainable road pavements. High-strength superstructures are built and put into service by modifying bitumen and different additive materials. These contributions can be named as industrial wastes, recycled materials, polymers and nanomaterials. With the development of nanotechnology, the use of nano materials in bitumen modification has become widespread. The rheological and physical properties of bitumen were investigated by modifying bitumen with nanoclay, nanosilica, nano calcium carbonate (nano-CaCO3), titanium dioxide nanoparticle (nano-TiO2), nano carbon black obtained from recycled petrochemicals and other materials. With the use of nanomaterials, significant improvements have been achieved in many properties of bitumen, such as durability, water sensitivity and storage stability and resistance to deformation. In this article, the studies in the literature about the nanomaterials mentioned above have been investigated and it is aimed to create a different perspective for researchers by presenting the findings obtained as a result of these researches.

Anahtar Kelimeler

Bitumen, Modification, Bituminous mixtures

Kaynakça

• [1] ASMÜD. Karayolu ağının kaplama tipine göre oranı. http://www.asmud.org.tr/, Erişim tarihi: 25.02.2020.
• [2] Ilıcalı, M., Tayfur, S., Özen, H., Sönmez, İ. ve Eren, K. Asfalt ve Uygulamaları. İstanbul: İstanbul Büyükşehir Belediyesi İstanbul Asfalt Fabrikaları Sanayi ve Ticaret A.Ş. Yayınları, 2001.
• [3] Yu, J. Y. Z., Feng,G., Zhang H. L., 9 - Ageing of polymer modified bitumen (PMB) A2 - McNally, Tony, in Polymer Modified Bitumen, ed: Woodhead Publishing, 264-297, 2011.
• [4] Navarro, F., Partal, P., Martınez-Boza, F., Gallegos,C. Thermo-rheological behaviour and storage stability of ground tire rubber-modified bitumens, Fuel, 83, 2041-2049, 2004. https://doi:10.1016/j.fuel.2004.04.003.
• [5] Mcnally, T. 1 - Introduction to polymer modified bitumen (PmB), in Polymer Modified Bitumen, ed: Woodhead Publishing, 1-21. 2011.
• [6] Lewandowski, L., Polymer modification of paving asphalt binders, Rubber Chemistry and Technology, 673, 447-480, 1994. https://doi.org/10.5254/1.3538685
• [7] ASMÜD, Türkiye'de son 5 yılda yapılan asfalt uygulamaları ve bitüm tüketimi, http://www.asmud.org.tr/asfalt.php?sayfa=26, Erişim tarihi: 21.08.2017.
• [8] Zhu, J., Birgisson, B., Kringos N., Polymer modification of bitumen: Advances and challenges. European Polymer Journal, 54, 18-38, 2014. http://dx.doi.org/10.1016/j.eurpolymj.2014.02.005
• [9] EAPA, Asphalt Institute, The Bitumen Industry - A Global Perspective Production, chemistry, use, specification and occupational exposure. 3 Basım. USA. ARRB Group Limited. 2015.
• [10] Fu, H., Xie, L., Dou, D., Li, L., Yu, M., Yao, S., Storage stability and compatibility of asphalt binder modified by SBS graft copolymer, Construction and Building Materials. 21, 1528–1533, 2007. https://doi.org/10.1016/j.conbuildmat.2006.03.008
• [11] Fang, C., Yu, R., Liu, S., Li, Y., Nanomaterials applied in asphalt modification: a review, J. Mater. Sci. Technol. 29, 589–594, 2013. https://doi.org/10.1016/j.jmst.2013.04.008
• [12] Yanga J., Tighe S., A review of advances of Nanotechnology in asphalt mixtures. Procedia - Social and Behavioral Sciences 96 1269 – 1276, 2013. https://doi.org/10.1016/j.sbspro.2013.08.144
• [13] R. Li, F. Xiao, S. Amirkhanian, Z. You, J. Huang, Developments of nano materials and technologies on asphalt materials – A review. Construction and Building Materials 143 633–648, 2017. https://doi.org/10.1016/j.conbuildmat.2017.03.158
• [14] https://shop.nanografi.com.tr/nanokil-safl-k-99-9-boyut-800-nm/, Erişim tarihi: 28.02.2021.
• [15] Maden Tetkik Ve Arama Genel Müdürlüğü, Bentonit, http://www.mta.gov.tr/v3.0/bilgi-merkezi/bentonit, Erişim tarihi: 14.03.2019.
• [16] Köroğlu, F.N., Nitrofenollerin İyonik ve İyonik Olmayan Organobentonitlerle Adsorpsiyon ve Desorpsiyonu. Yüksek Lisans Tezi. Ankara Üniversitesi, Ankara, 2004.
• [17] Iskender, E., Evaluation of mechanical properties of nano-clay modified asphalt mixtures, Measurement. 93, 359–371, 2016. https://doi.org/10.1016/j.measurement.2016.07.045
• [18] Z. You, J. Mills-Beale, J.M. Foley, S. Roy, G.M. Odegard, Q. Dai, et al., Nanoclaymodified asphalt materials: preparation and characterization. Constr. Build. Mater. 25 (2) 1072–1078, 2011. https://doi.org/10.1016/j.conbuildmat.2010.06.070
• [19] Yao, H., You, Z., Liang, L., Goh, S. W., Lee, C. H., Yap Y. K., Shi, X., Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy, Construction and Building Materials. 38, 327–337, 2013. https://doi.org/10.1016/j.conbuildmat.2012.08.004
• [20] Luísa Gardênia A.T. Farias, Janaina L. Leitinho, Bruno de C. Amoni, Juceline B.S. Bastos, Jorge B. Soares,Sandra de A. Soares, Hosiberto B. de Sant’Ana, Effects of nanoclay and nanocomposites on bitumen rheological properties, Construction and Building Materials 125, 873-883, 2016. https://doi.org/10.1016/j.conbuildmat.2016.08.127
• [21] Hassan, A.F., Abdelghny, A.M., Elhadidy, H., Youssef, A.M., Synthesis and characterization of high surface area nanosilika from rice husk ash by surfactant-free sol–gel method, J. Sol-Gel. Sci. Technol. 69 (3) 465–472, 2013.
• [22] https://www.choko.asia/nano-silica.html, Erişim tarihi: 01.03.2021.
• [23] Ezzat, H., El-Badawy, S., Gabr, A., Zaki, E.-S.I., Breakah, T., Evaluation of asphalt binders modified with nanoclay and nanosilica, Proc. Eng. 143 1260– 1267, 2016. DOI 10.1007/s10971-013-3245-9
• [24] Balaa, N., Napiaha, M., Kamaruddina, I., Effect of nanosilika particles on polypropylene polymer modified asphalt mixture performance. Case Studies in Construction Materials 8 447–454, 2018. https://doi.org/10.1016/j.cscm.2018.03.011
• [25] Yusoff, N. I. Md. , Alhamali, D. I., Ibrahim, A. N. H., Rosyidi, S. A. P., Hassan, N. A., Engineering characteristics of nanosilika/polymer-modified bitumen and predicting their rheological properties using multilayer perceptron neural network model. Construction and Building Materials 204 781–799, 2019. https://doi.org/10.1016/j.conbuildmat.2019.01.203
• [26] http://www.sanayisurasi.gov.tr/pdfs/delikli-nano-caco3-uretimi.pdf ., Erişim tarihi: 25.03.2019.
• [27] Gök, S.B., Nano kalsiyum karbonat eldesi ve α-Amilaz enziminin immobilizasyonununda kullanılması, Yüksek lisans tezi, Marmara Üniversitesi Fen Bilimleri Enstitüsü Kimya Anabilim Dalı Organik Kimya Programı, 2011.
• [28] Liu, D., Zhang, X., Study on Properties of Nano Calcium Carbonate and Polyethylene Complex Modified Asphalt. 1st International Conference on Transportation Infrastructure and Materials (ICTIM 2016) http://dpi-roceedings.com/index.php/dtetr/article/download/5492/5112, Erişim tarihi:08.03.2021.
• [29] Ghanoon, S. A., Tanzadeh, J., Mirsepahi, M., Laboratory evaluation of the composition of nano-clay, nano-lime and SBS modifiers on rutting resistance of asphalt binder. Construction and Building Materials, 238, 117592, 2020. https://doi.org/10.1016/j.conbuildmat.2019.117592
• [30] T.C. Millî Eğitim Bakanlığı, Kimya Teknolojisi Karbon Karaları Ve Testleri, http://megep.meb.gov.tr/mte_program_modul/moduller_pdf/Karbon%20Karalar%C4%B1%20Ve%20Testleri.pdf, Erişim tarihi:08.03.2020.
• [31] Öztürk, İ. Ş., Çelik lifli betonlarda geri dönüştürülmüş nano karbon siyahı ve kandıra taşı tozunun değerlendirilmesi, Yüksek Lisans Tezi, Sakarya Üniversitesi Fen Bilimleri Enstitüsü, 2020.
• [32] Tanzadeh, R., Shafabakhsh, G., Surface free energy and adhesion energy evaluation of modified bitumen with recycled carbon black (micro-nano) from gases and petrochemical waste, Construction and Building Materials, 245, 118361, 2020. https://doi.org/10.1016/j.conbuildmat.2020.118361
• [33] Tanzadeh, R., Shafabakhsh, G., Relationship between the surface free energy and stiffness modulus of bitumen modified with micro-nano-carbon black from end-of-life tires, International Journal of Adhesion & Adhesives, 100, 102606, 2020. https://doi.org/10.1016/j.ijadhadh.2020.102606
• [34] https://www.gelgez.net/nanoteknoloji-parcacigi-titanyum-dioksit-nedir/, Erişim tarihi: 25.02.2021.
• [35] Shafabakhsh, G.H., Jafari Ani, O., Experimental investigation of effect of Nano TiO2/SiO2 modified bitumen on the rutting and fatigue performance of asphalt mixtures containing steel slag aggregates, Construction and Building Materials, 98, 692–702, 2015. https://doi.org/10.1016/j.conbuildmat.2015.08.083
• [36] Zheng, D., Qian, Z., Li, P., Wang,L., Performance evaluation of high-elasticity asphalt mixture containing inorganic nano-titanium dioxide for applications in high altitude regions, Construction and Building Materials, 199, 594–600, 2019. https://doi.org/10.1016/j.conbuildmat.2018.12.053
• [37] Günay, T., Ahmedzade, P., Physical and rheological properties of nano-TiO2 and nanocomposite modified bitumens, Construction and Building Materials, 243, 118208, 2020. https://doi.org/10.1016/j.conbuildmat.2020.118208