The use of çan stone processing wastes as raw material in ceramic triaxial glaze system

Yıl 2025, Cilt: 31 Sayı: 2, 309 - 318, 29.04.2025

Selvin Yeşilay , Hande Özge Özkul Münevver Çakı

https://izlik.org/JA32KE77AY

Öz

Natural stones are materials with distinct properties that are becoming increasingly popular because of their accessibility, performance, and decorative qualities. In the construction industry, igneous, sedimentary, and metamorphic rock types are frequently used, particularly in landscaping, sculpture, and ceramic production. These wastes are categorized in various forms, such as dust or fines, aggregates, larger pieces of stone, damaged blocks or slabs, and stone slurry. Waste has a significant impact on soil, water, air, and biological resources if problems that arise during and after operations are not properly addressed. In this study, the operating wastes produced during the production of “Çan Stone”, which is defined in the literature as "rhyolitic tuff", and has mineral deposits in Çan, Turkey, were used as components in recipes created with ceramic triaxial blend systems. The main objective is to eliminate the environmental issues brought on by the accumulation of this waste while also enabling the use of a by-product that has a wide range of applications in various industrial sectors. The chemical compositions of the waste which are added up to 60% into the glaze recipes and raw materials used in recipes were determined by XRF analysis. Among the glaze recipes produced, 6 glaze compositions were selected for characterization tests. XRD, SEM, hot stage microscope and spectrophotometer devices were used to characterize the produced glaze samples. Wastes were obtained from Şahin Mining Company (Çan-Turkey) and included in the formulations of ceramic glazes. Transparent glazes in color tones ranging from light brown to dark brown were obtained in the samples fired at 1200 oC.

Anahtar Kelimeler

Atık kullanımı , Geleneksel seramikler , Silikatlar , Geri dönüşüm , Sır

Çan taşı işletme atıklarının seramık üçlü sır sıstemınde hammadde olarak kullanımı

https://izlik.org/JA32KE77AY

Öz

Doğal taşlar, erişilebilirlikleri, performansları ve dekoratif nitelikleri nedeniyle giderek daha popüler hale gelen, farklı özelliklere sahip malzemelerdir. İnşaat sektöründe magmatik, tortul ve metamorfik kaya türleri, özellikle peyzaj, heykel ve seramik üretiminde sıklıkla kullanılmaktadır. Bu atıklar, toz veya ince taneler, agregalar, daha büyük taş parçaları, hasarlı bloklar veya levhalar ve sulu çamur gibi çeşitli şekillerde sınıflandırılır. Operasyon sırasında ve sonrasında ortaya çıkan sorunlar uygun şekilde ele alınmazsa, atıkların toprak, su, hava ve biyolojik kaynaklar üzerinde önemli bir etkisi vardır. Bu çalışmada, literatürde “riyolitik tüf” olarak tanımlanan ve Çan ilçesinde maden yatakları bulunan “Çan Taşı”nın üretimi sırasında oluşan işletme atıkları, üçlü seramik sır sistemleri ile oluşturulan reçetelerde bileşen olarak kullanılmıştır. Temel amaç, bu atıkların birikmesinden kaynaklanan çevresel sorunları ortadan kaldırmak ve aynı zamanda çeşitli endüstriyel sektörlerde geniş uygulama alanına sahip bir yan ürünün kullanımını sağlamaktır. Sır reçetelerine %60'a kadar eklenen atıkların ve reçetelerde kullanılan hammaddelerin kimyasal bileşimleri XRF analizi ile belirlenmiştir. Üretilen sır reçetelerinden 6 adet sır kompozisyonu karakterizasyon testleri için seçilmiştir. Üretilen sır örneklerinin karakterize edilmesinde XRD, SEM, ısı mikroskobu ve spektrofotometre cihazları kullanılmıştır. Atıklar, Şahin Madencilik Şirketinden (Çan-Türkiye) alınmıştır ve seramik sırlarının formülasyonlarına dahil edilmiştir. 1200 oC'de pişirilen numunelerde açık kahveden koyu kahveye kadar renk tonlarında şeffaf sırlar elde edilmiştir.

Anahtar Kelimeler

Waste utilization , Traditional ceramics , Silicates , Recycling , Glaze

Kaynakça

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