The use of çan stone processing wastes as raw material in ceramic triaxial glaze system

Öz

Natural stones are materials with distinct properties that are becoming increasingly popular because of their accessibility, performance, and decorative qualities. In the construction industry, igneous, sedimentary, and metamorphic rock types are frequently used, particularly in landscaping, sculpture, and ceramic production. These wastes are categorized in various forms, such as dust or fines, aggregates, larger pieces of stone, damaged blocks or slabs, and stone slurry. Waste has a significant impact on soil, water, air, and biological resources if problems that arise during and after operations are not properly addressed. In this study, the operating wastes produced during the production of “Çan Stone”, which is defined in the literature as "rhyolitic tuff", and has mineral deposits in Çan, Turkey, were used as components in recipes created with ceramic triaxial blend systems. The main objective is to eliminate the environmental issues brought on by the accumulation of this waste while also enabling the use of a by-product that has a wide range of applications in various industrial sectors. The chemical compositions of the waste which are added up to 60% into the glaze recipes and raw materials used in recipes were determined by XRF analysis. Among the glaze recipes produced, 6 glaze compositions were selected for characterization tests. XRD, SEM, hot stage microscope and spectrophotometer devices were used to characterize the produced glaze samples. Wastes were obtained from Şahin Mining Company (Çan-Turkey) and included in the formulations of ceramic glazes. Transparent glazes in color tones ranging from light brown to dark brown were obtained in the samples fired at 1200 oC.

Anahtar Kelimeler

• Atık kullanımı
• Geleneksel seramikler
• Silikatlar
• Geri dönüşüm
• Sır

Çan taşı işletme atıklarının seramık üçlü sır sıstemınde hammadde olarak kullanımı

Öz

Doğal taşlar, erişilebilirlikleri, performansları ve dekoratif nitelikleri nedeniyle giderek daha popüler hale gelen, farklı özelliklere sahip malzemelerdir. İnşaat sektöründe magmatik, tortul ve metamorfik kaya türleri, özellikle peyzaj, heykel ve seramik üretiminde sıklıkla kullanılmaktadır. Bu atıklar, toz veya ince taneler, agregalar, daha büyük taş parçaları, hasarlı bloklar veya levhalar ve sulu çamur gibi çeşitli şekillerde sınıflandırılır. Operasyon sırasında ve sonrasında ortaya çıkan sorunlar uygun şekilde ele alınmazsa, atıkların toprak, su, hava ve biyolojik kaynaklar üzerinde önemli bir etkisi vardır. Bu çalışmada, literatürde “riyolitik tüf” olarak tanımlanan ve Çan ilçesinde maden yatakları bulunan “Çan Taşı”nın üretimi sırasında oluşan işletme atıkları, üçlü seramik sır sistemleri ile oluşturulan reçetelerde bileşen olarak kullanılmıştır. Temel amaç, bu atıkların birikmesinden kaynaklanan çevresel sorunları ortadan kaldırmak ve aynı zamanda çeşitli endüstriyel sektörlerde geniş uygulama alanına sahip bir yan ürünün kullanımını sağlamaktır. Sır reçetelerine %60'a kadar eklenen atıkların ve reçetelerde kullanılan hammaddelerin kimyasal bileşimleri XRF analizi ile belirlenmiştir. Üretilen sır reçetelerinden 6 adet sır kompozisyonu karakterizasyon testleri için seçilmiştir. Üretilen sır örneklerinin karakterize edilmesinde XRD, SEM, ısı mikroskobu ve spektrofotometre cihazları kullanılmıştır. Atıklar, Şahin Madencilik Şirketinden (Çan-Türkiye) alınmıştır ve seramik sırlarının formülasyonlarına dahil edilmiştir. 1200 oC'de pişirilen numunelerde açık kahveden koyu kahveye kadar renk tonlarında şeffaf sırlar elde edilmiştir.

Anahtar Kelimeler

• Waste utilization
• Traditional ceramics
• Silicates
• Recycling
• Glaze

Kaynakça

1. [1] Calkins M. The Sustainable Sites Handbook: A Complete Guide to the Principles, Strategies, and Best Practices for Sustainable Landscapes. 1st ed. New York, USA, John Wiley & Sons, 2018.
2. [2] Strzałkowski P. "Characteristics of waste generated in dimension stone processing". Energies, 14(21), 7232, 2021.
3. [3] Yurdakul M. “Natural stone waste generation from the perspective of natural stone processing plants: An industrial-scale case study in the province of Bilecik”. Journal of Cleaner Production, 276, 123339, 2020.
4. [4] Sivrikaya O, Kıyıldı KR, Karaca Z. “Recycling waste from natural stone processing plants to stabilise clayey soil”. Environmental Earth Sciences, 71, 4397-4407, 2014.
5. [5] Nemerow NL, Agardy FJ, Sullivan PJ, Salvato JA. Environmental Engineering: Environmental Health and Safety for Municipal Infrastructure, Land Use and Planning, and Industry. 6th Ed. New York, ABD, John Wiley & Sons, 2009.
6. [6] Yurdakul M, Akdaş H. “Bir doğal taş-mermer ocağında birikmiş atıkların çimento sektöründe değerlendirilmesi: Söğüt örneği”. International Symposium on Mining and Environment (ISME 2017), Muğla, Türkiye, 27-29 Eylül 2017.
7. [7] Al-Zboon KK, That MS. “Recycling of stone cutting waste in floor tiles production”. Trends in Applied Sciences Research, 1(1), 64-70, 2009.
8. [8] Çiner F, Doğan N, Delibalta MS. Endüstriyel Kati Atık Olarak Mermer Atiklarinin Çevresel Etkileri ve Değerlendirilme Alternatifleri. Editors: Güler T, Polat E. Mermer Madenciliğinde Çevresel Yaklaşımlar, 93-128, Muğla, Türkiye, Muğla Büyükşehir Belediyesi Kültür Yayınları, Akademik Yayın Dizisi, 1, 2018.

9. [9] Golla SY, Amer M, Sampeta R, Ghotiya S, Jessica J. “Durability properties of ceramic waste-based concrete”. Materials Today: Proceedings, 66(4), 2282-2287, 2022.
10. [10] Segada˜es, A.M. “Using marble and granite rejects to enhance the processing of clay products”. Applied Clay Science, 30, 42-52, 2005.
11. [11] Aydın G, Karakurt İ. “Doğaltaş üretim ve işleme tesisi atıklarının değerlendirilmesi”. ALKU Journal of Science, 2(2), 62-77, 2020.
12. [12] Suchithra S, Sowmiya M, Pavithran T. “Effect of ceramic tile waste on strength parameters of concrete-a review”. Materials Today: Proceedings, 65(2), 975-982, 2022.
13. [13] Luo Y, Bao S, Zhang Y. “Recycling of granite powder and waste marble produced from stone processing for the preparation of architectural glass-ceramic”. Construction and Building Materials, 346, 128408, 2022.
14. [14] Munevver C, Yesilay S, Busra G. “The use of glass waste in stoneware glazes”. Ceramic Technical, 37, 14-19, 2013.
15. [15] Cleber da Silva R. “Preparation and characterization of glazes from combinations of different industrial wastes”. Ceramics International, 38(4), 2725-2731, 2011.
16. [16] Yeşilay S, Çakı M, Ceylantekin R. “Recycling of AfyonIscehisar marble waste in transparent stoneware glaze recipes”. J Aust Ceram Soc, 53, 475-484, 2017.
17. [17] Kamarudin RA, Zakaria MS. “The utilization of red gypsum waste for glazes”. The Malaysian Journal of Analytical Sciences. 11(1), 57-64, 2007.
18. [18] Yesilay S. “Mermer atığı ilavesi ile mat sır bileşimlerinin üretimi”. Journal of Engineering and Architecture Faculty of Eskişehir Osmangazi University, 26(3), 123-131, 2018.
19. [19] Sultana MS, Ahmed AN, Zaman NM, Rahman MA. “Utilization of hard rock dust in ceramic glaze formulation”. 4th International Conference on Structure, Processing and Properties of Materials (SPPM 2018), IOP Publishing, IOP Conference Series: Materials Science and Engineering, BUET, Dhaka, 1-3 March 2018.
20. [20] Göl F, Çibük S, Kaçar E, Sarıtaş ZG, Yılmaz A, Arslan M, Şen F. “Reuse of glass waste in the manufacture of ceramic tableware glazes”. Ceramics International, 48(11), 15622-15628, 2021.
21. [21] Vasić MV, Mijatović N, Radojević Z. “Aplitic granite waste as raw material for the production of outdoor ceramic floor tiles”. Materials (Basel), 15(9), 3145, 2022.
22. [22] Toluwalope O, Oluwatuase I. “The use of waste borosilicate glasses for formulating a functional transparent glaze”. International Journal of Advancements in Technology, 6(1), 1-3, 2015.
23. [23] Kalilu ROR, Ajadi MO. “Cullet to glaze: Converting waste for ceramic artistic, economic and environmental development”. European Journal of Engineering and Applied Sciences, 4(1), 1-7, 2021.
24. [24] Hopper R. The Ceramic Spectrum: A Simplified Approach to Glaze & Color Development. 2nd ed. USA, Krause Publication, 2001.
25. [25] Daly G. Glazes and Glazing Techniques. 1st ed. Great Britain, A&C Black Limited, 1995.
26. [26] Fraser F. Glazes for the Craft Potter, 2nd ed. London, UK, A&C Black Company, 1998.
27. [27] Pekkan K, Başkırkan H, Çakı M. “Development of goldbronze metallic glazes in a clay-based system for stoneware bodies”. 44, 4789-4794, 2018. Ceramics International,
28. [28] Ebert TA. “Designing glaze colours”. Ceramics Technical, 20, 30-37, 2005.
29. [29] Erenoğlu O. “Mineralogical properties and geochronology of the Çan stone tuff (Biga Peninsula, NW Turkey)”. Geological Bulletin of Turkey, 60, 433-449, 2017.
30. [30] Türkdönmez O, Bozcu M. “The geological, petrographical and engineering properties of rhyolitic tuffs (Çan stone) in Çan-Etili area (Çanakkale), NW Turkey: Their usage as building and covering stones”. Open Journal of Geology, 2, 25-33, 2012.
31. [31] The New Zeland Digital Libsrary The University of Waikato. “Developing Glazes”. http://www.nzdl.org/cgibin/library?e=d-00000-00---off-0hdl--00-0----0-10-0---0---0direct-10---4-------0-0l--11-en-50---20-home---00-0-100-0-0-11-1-0utfZz-800&cl=CL1.7&d=HASHb8171ab02a10e3ab23250b.13> =1 (21.07.2023).
32. [32] Bayca SU. “Effects of the addition of ulexite to the sintering behavior of a ceramic body”. Journal of Ceramic Processing Research, 10(2), 162-166, 2009.
33. [33] Gol F, Saritas Z, Cıbuk S, Ture C, Kacar E, Yilmaz A, Arslan M, Sen F. “Coloring effect of iron oxide content on ceramic glazes and their comparison with the similar waste containing materials”. 48(2), 2241-2249, 2022.
34. [34] Pottery Crafters. “What Ceramics is International, Dip Glazing?”. https://potterycrafters.com/what-is-dip-glazing (16.02. 2023).
35. [35] Kline G. Amazing Glaze: Techniques, Recipes, Finishing, and Firing. 1st ed. USA, Voyageur Press, 2018.