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The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets

Yıl 2025, Cilt: 31 Sayı: 7, 1117 - 1124, 15.12.2025
https://doi.org/10.5505/pajes.2025.63838

Öz

This study examines the effect of forming (bending and folding) procedures on the corrosion behavior of galvanized sheet steel in poultry manure. It also aims to compare the corrosion behavior in poultry manure with salty and atmospheric environments. To achieve this objective, samples were prepared by laser cutting DX51D galvanized sheets. These samples were then subjected to various bending processes, including V, L, U, and Z-bendings, as well as multiple bending, folding, and folding+bending techniques. The samples underwent salt spray testing to determine the percentages of white and red rust on their surfaces. The samples, including laser cut, V-bendings, multiple bending, and folding, were exposed to the atmosphere and poultry manure settings for 28 days. The corrosion rates in these environments were calculated by measuring the mass losses every seven days. In the salt spray test, 60° bent samples exhibited the most corrosion resistance compared to the other forms, showing minimum percentages of white (56%) and red (4%) rust. The frame-cut sample showed a maximum corrosion rate of 0.00152 mm/year in the atmosphere. Bending and folding processes had no detrimental effect on the galvanized coating, such as peeling or flaking the coating. However, corrosion affected the bent and folded regions negatively by decreasing the coating thickness.

Kaynakça

  • [1] Ciubotariu AC, Istrate GG. “Corrosion rate of steels DX51D and S220GD in different corrosion environment”. Scientific Bulletin of Naval Academy, 19(1), 166-172, 2016.
  • [2] Şirin ŞY. “The effect of hot dip galvanizing process on the fatigue properties of hot rolled and quenched-tempered AISI 4340 steel”. Pamukkale University Journal of Engineering Sciences, 24(4), 626-634, 2018.
  • [3] Najafabadi EP, Heidarpour A, Raina S, Arashpour M, Zhao XL. “Effects of galvanization on the mechanical properties of high and ultra-high-strength steel tubes”. ce/papers, 4(2-4), 1606-1611, 2021.
  • [4] Singh JK, Mandal S, Adnin RJ, Lee HS, Yang HM. “Role of coating processes on the corrosion kinetics and mechanism of zinc in artificial seawater”. Materials, 14(23), 7464, 2021.
  • [5] Vagge ST, Raja VS, Narayanan RG. “Effect of deformation on the electrochemical behavior of hot-dip galvanized steel sheets”. Applied Surface Science, 253(20), 8415-8421, 2007.
  • [6] ArcelorMittal Europe. “Corrosion Protection of Rolled Steel Sections Using Hot-Dip Galvanization”. https://sections.arcelormittal.com/repository2/Sections/10_Corrosion%20protection/5_10_02_Corrosion_EN.pdf (10.08.2024).
  • [7] Ploypech S, Boonyongmaneerat Y, Jearanaisilawong P. “Crack initiation and propagation of galvanized coatings hot-dipped at 450 C under bending loads”. Surface and Coatings Technology, 206(18), 3758-3763, 2012.
  • [8] Okafor IC, O’Malley RJ, Prayakarao KR, Aglan HA. "Effect of zinc galvanization on the microstructure and fracture behavior of low and medium carbon structural steels". Engineering, 5(8), 656-666, 2013.
  • [9] Camurri PC, Benavente GR, Roa SI, Carrasco CC. “Deformation and fatigue behavior of hot dip galvanized coatings”. Materials Characterization, 55(3), 203-210, 2005.
  • [10] Oyewole O, Smart P, Ajani D, Olorunfemi JB. “Effect of corrosion on surface degradation of galvanized steel in poultry dung, pig dung and urea solutions using rice straw as an inhibitor”. Journal of the Mechanical Behavior of Materials, 30, 95-102, 2021.
  • [11] Dülger M. Investigating the Effect of Mechanical Processes on Corrosion Behavior in Galvanized DX51 and DX52 Quality Steels. MSc Thesis, Balıkesir University, Balıkesir, Türkiye, 2024.
  • [12] Korkmaz AH, Sürücü A, Horuz A. “The utilization of rw-watered poultry manure as organic fertilizer in the agriculture”. Journal of Faculty of Agriculture, Ondokuz Mayıs University, 11(2), 117–125, 1996.
  • [13] Moreira VB., Krummenauer A, Ferreira JZ, Veit HM, Armelin E, and Meneguzzi A, “Computational image analysis as an alternative tool for the evaluation of corrosion in salt spray test”. Studia UBB Chemia, LXV, 3, 45-61, 2020.
  • [14] Elewa RE, Afolalu SA, Fayomi OSI. “Overview production process and properties of galvanized roofing sheets”. Journal of Physics: Conference Series 1378, 022069, 2019.
  • [15] Haiducu M, Ghiban B, Ghiban N, Miculescu F, “Corrosion resistance of some zinc galvanizing steels”. University Politehnica of Bucharest Scientific Bulletin, Series B, 75(3), 153-164, 2013.
  • [16] Liu Q, Cao Y, Chen S, Xu X, Yao M, Fang J, Lei K, and Liu G, “Hot-dip galvanizing process and the influence of metallic elements on composite coatings”. Journal of Composite Science, 8(5), 160, 2024.
  • [17] Hernandez-Alvarado LA, Hernandez LS, and Rodriguez-Reyna SL. “Evaluation of corrosion behavior of galvanized steel treated with conventional conversion coatings and a chromate-free organic inhibitor”. International Journal of Corrosion, 2012(1), 368130, 2012.
  • [18] Karakaş Ö, Kanca E, Aydın Z. “Examination of the effects of the use of passivation agents and protective oils on corrosion formation”. International Iron & Steel Symposium, Karabük, Türkiye, 2-4 April 2012.
  • [19] Vourlias G, Pistofidis N, Stergioudis G, Pavlidou E, and Tsipas D, “Influence of alloying elements on the structure and corrosion resistance of galvanized coatings”. Physica Status Solidi, 201(7), 1518–1527 2004.
  • [20] Yang WJ, Yang P, Li XM and Feng WL. “Influence of tensile stress on corrosion behaviour of high strength galvanized steel bridge wires in simulated acid rain”. Materials and Corrosion, 63(5), 401-407, 2012.

Şekillendirme işleminin DX51D galvanizli çelik sacın korozyon davranışına etkisi

Yıl 2025, Cilt: 31 Sayı: 7, 1117 - 1124, 15.12.2025
https://doi.org/10.5505/pajes.2025.63838

Öz

Bu çalışma şekillendirmenin (eğme ve katlamanın) galvanizli çelik sacın tavuk gübresindeki korozyon davranışını incelemektedir. Aynı zamanda çalışma, tavuk gübresindeki korozyon davranışını tuz sisi ve atmosfer ortamları ile karşılaştırmayı hedeflemektedir. Bunun için DX51D galvanizli çelik lazer yöntemiyle kesilerek numuneler elde edilmiştir. Daha sonra bu numunelere değişik formlarda eğme işlemleri uygulanmıştır. Bunlar V, L, U, ve Z-eğme ile çoklu eğme, katlama ve katlama artı eğme işlemleridir. Numuneler tuz sisi deneyine tabi tutularak yüzeylerinde oluşan beyaz ve kırmızı pas oranları belirlenmiştir. Lazer kesim, V-eğme, çoklu eğme ve katlama ile şekillendirilen numuneler atmosfer ve tavuk gübresi ortamlarında 28 gün bekletilmişlerdir. Bu ortamlardaki korozyon hızları numunelerin her yedi günde ortamdan alınarak kütle kaybı ölçümlerinden hesaplanmıştır. Tuz sisi deneyinde 60° eğme ile şekillendirilen numuneler %58 beyaz pas ve %4 kırmızı pas oranları ile diğer şekillendirmelere göre en yüksek korozyon direnci göstermişlerdir. Atmosfer ortamında çerçeve kesim numuneleri 0.00152 mm/yıl değeri ile en yüksek korozyon hızı göstermişlerdir. Eğme ve katlama işlemlerinin galvaniz kaplamaya, kaplamanın soyulması veya pul pul dökülmesi gibi zararlı bir etkisi olmamıştır. Ancak korozyon kaplama kalınlığını azaltarak eğilen ve katlanan bölgeleri olumsuz yönde etkilemiştir.

Kaynakça

  • [1] Ciubotariu AC, Istrate GG. “Corrosion rate of steels DX51D and S220GD in different corrosion environment”. Scientific Bulletin of Naval Academy, 19(1), 166-172, 2016.
  • [2] Şirin ŞY. “The effect of hot dip galvanizing process on the fatigue properties of hot rolled and quenched-tempered AISI 4340 steel”. Pamukkale University Journal of Engineering Sciences, 24(4), 626-634, 2018.
  • [3] Najafabadi EP, Heidarpour A, Raina S, Arashpour M, Zhao XL. “Effects of galvanization on the mechanical properties of high and ultra-high-strength steel tubes”. ce/papers, 4(2-4), 1606-1611, 2021.
  • [4] Singh JK, Mandal S, Adnin RJ, Lee HS, Yang HM. “Role of coating processes on the corrosion kinetics and mechanism of zinc in artificial seawater”. Materials, 14(23), 7464, 2021.
  • [5] Vagge ST, Raja VS, Narayanan RG. “Effect of deformation on the electrochemical behavior of hot-dip galvanized steel sheets”. Applied Surface Science, 253(20), 8415-8421, 2007.
  • [6] ArcelorMittal Europe. “Corrosion Protection of Rolled Steel Sections Using Hot-Dip Galvanization”. https://sections.arcelormittal.com/repository2/Sections/10_Corrosion%20protection/5_10_02_Corrosion_EN.pdf (10.08.2024).
  • [7] Ploypech S, Boonyongmaneerat Y, Jearanaisilawong P. “Crack initiation and propagation of galvanized coatings hot-dipped at 450 C under bending loads”. Surface and Coatings Technology, 206(18), 3758-3763, 2012.
  • [8] Okafor IC, O’Malley RJ, Prayakarao KR, Aglan HA. "Effect of zinc galvanization on the microstructure and fracture behavior of low and medium carbon structural steels". Engineering, 5(8), 656-666, 2013.
  • [9] Camurri PC, Benavente GR, Roa SI, Carrasco CC. “Deformation and fatigue behavior of hot dip galvanized coatings”. Materials Characterization, 55(3), 203-210, 2005.
  • [10] Oyewole O, Smart P, Ajani D, Olorunfemi JB. “Effect of corrosion on surface degradation of galvanized steel in poultry dung, pig dung and urea solutions using rice straw as an inhibitor”. Journal of the Mechanical Behavior of Materials, 30, 95-102, 2021.
  • [11] Dülger M. Investigating the Effect of Mechanical Processes on Corrosion Behavior in Galvanized DX51 and DX52 Quality Steels. MSc Thesis, Balıkesir University, Balıkesir, Türkiye, 2024.
  • [12] Korkmaz AH, Sürücü A, Horuz A. “The utilization of rw-watered poultry manure as organic fertilizer in the agriculture”. Journal of Faculty of Agriculture, Ondokuz Mayıs University, 11(2), 117–125, 1996.
  • [13] Moreira VB., Krummenauer A, Ferreira JZ, Veit HM, Armelin E, and Meneguzzi A, “Computational image analysis as an alternative tool for the evaluation of corrosion in salt spray test”. Studia UBB Chemia, LXV, 3, 45-61, 2020.
  • [14] Elewa RE, Afolalu SA, Fayomi OSI. “Overview production process and properties of galvanized roofing sheets”. Journal of Physics: Conference Series 1378, 022069, 2019.
  • [15] Haiducu M, Ghiban B, Ghiban N, Miculescu F, “Corrosion resistance of some zinc galvanizing steels”. University Politehnica of Bucharest Scientific Bulletin, Series B, 75(3), 153-164, 2013.
  • [16] Liu Q, Cao Y, Chen S, Xu X, Yao M, Fang J, Lei K, and Liu G, “Hot-dip galvanizing process and the influence of metallic elements on composite coatings”. Journal of Composite Science, 8(5), 160, 2024.
  • [17] Hernandez-Alvarado LA, Hernandez LS, and Rodriguez-Reyna SL. “Evaluation of corrosion behavior of galvanized steel treated with conventional conversion coatings and a chromate-free organic inhibitor”. International Journal of Corrosion, 2012(1), 368130, 2012.
  • [18] Karakaş Ö, Kanca E, Aydın Z. “Examination of the effects of the use of passivation agents and protective oils on corrosion formation”. International Iron & Steel Symposium, Karabük, Türkiye, 2-4 April 2012.
  • [19] Vourlias G, Pistofidis N, Stergioudis G, Pavlidou E, and Tsipas D, “Influence of alloying elements on the structure and corrosion resistance of galvanized coatings”. Physica Status Solidi, 201(7), 1518–1527 2004.
  • [20] Yang WJ, Yang P, Li XM and Feng WL. “Influence of tensile stress on corrosion behaviour of high strength galvanized steel bridge wires in simulated acid rain”. Materials and Corrosion, 63(5), 401-407, 2012.
Toplam 20 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Tasarım ve Davranışları
Bölüm Araştırma Makalesi
Yazarlar

Alaaddin Toktaş 0000-0002-9902-6969

Mustafa Dülger 0000-0002-8751-5693

Gülcan Toktaş 0000-0002-0455-2107

Gönderilme Tarihi 13 Ağustos 2024
Kabul Tarihi 20 Mart 2025
Erken Görünüm Tarihi 2 Kasım 2025
Yayımlanma Tarihi 15 Aralık 2025
Yayımlandığı Sayı Yıl 2025 Cilt: 31 Sayı: 7

Kaynak Göster

APA Toktaş, A., Dülger, M., & Toktaş, G. (2025). The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 31(7), 1117-1124. https://doi.org/10.5505/pajes.2025.63838
AMA Toktaş A, Dülger M, Toktaş G. The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Aralık 2025;31(7):1117-1124. doi:10.5505/pajes.2025.63838
Chicago Toktaş, Alaaddin, Mustafa Dülger, ve Gülcan Toktaş. “The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31, sy. 7 (Aralık 2025): 1117-24. https://doi.org/10.5505/pajes.2025.63838.
EndNote Toktaş A, Dülger M, Toktaş G (01 Aralık 2025) The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31 7 1117–1124.
IEEE A. Toktaş, M. Dülger, ve G. Toktaş, “The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 31, sy. 7, ss. 1117–1124, 2025, doi: 10.5505/pajes.2025.63838.
ISNAD Toktaş, Alaaddin vd. “The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31/7 (Aralık2025), 1117-1124. https://doi.org/10.5505/pajes.2025.63838.
JAMA Toktaş A, Dülger M, Toktaş G. The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2025;31:1117–1124.
MLA Toktaş, Alaaddin vd. “The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 31, sy. 7, 2025, ss. 1117-24, doi:10.5505/pajes.2025.63838.
Vancouver Toktaş A, Dülger M, Toktaş G. The effect of forming process on the corrosion characteristics of DX51D galvanized steel sheets. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2025;31(7):1117-24.