Şeker pancarı melasının sırlı porselen seramik yer karosu gövdelerinde mukavemet artırıcı olarak kullanımı ve karakterizasyonu

Öz

Arka plan—Şeker fabrikaları yan ürün olarak büyük miktarlarda şeker pancarı melası üretmektedir. Melas bazı endüstriyel sektörlerde kullanılsa da, araştırmalarımız seramik pres makineleri için sırlı porselen seramik yer karosu gövde çamuru granüllerinde mukavemet artırıcı olarak kullanılmadığını göstermiştir.

Amaç—Bu makalenin amacı, seramik fabrikalarındaki seramik pres makinelerinde kullanılan seramik yer karosu gövde çamuru granüllerinde şeker pancarı melasının mukavemet artırıcı olarak kullanımını araştırmak ve literatürdeki bu boşluğu doldurmaktır.

Yöntem—Pres makineleri seramik yer karosu üretiminde şekillendirme işleminde kullanılır. Granüllerin gerekenden düşük nem içeriği ve kuru mukavemet değerleri nedeniyle, seramik karo üretiminde sırlama sırasında ve sonrasında ve pişirme aşamasında yaklaşık %10 kayıp meydana gelir. Bu kayıpları en aza indirmek ve bunu mümkün olan en düşük maliyetle başarmak için, şeker fabrikalarının bir yan ürünü olan şeker pancarı melası, mukavemetini artırmak amacıyla standart yer karosu gövde çamuruna ağırlıkça %0,1, %0,2, %0,3, %0,4 ve %0,5 oranlarında eklenmiştir. Daha sonra, eklemeden önce ve sonra meydana gelen değişiklikler X-ışını floresans (XRF) spektroskopisi, SEM analizi, termogravimetrik analiz (DTA-TG) ve fiziksel özellikler (mukavemet, renk ölçümü, yoğunluk, akış süresi, elek kalıntısı, partikül boyutu, kuru mukavemet, pişmiş mukavemet, büzülme, su emme vb.) kullanılarak analiz edilmiş ve sürece dahil edilmiştir. Analiz, %0,3 oranında şeker pancarı melası içeren standart karo gövde çamurunun, melas içermeyen standart karo gövde çamuruna göre daha yüksek mukavemete sahip olduğunu göstermiştir.

Bulgular—Günde yaklaşık 250 ton granül tüketen ve seramik pres makineleri kullanan bir seramik fabrikasında, aylık ortalama 7500 ton sırlı porselen seramik yer karosu hamuru granülü kullanılmaktadır. Seramik pres makinesi üretiminde mukavemet kaybından kaynaklanan %10'luk kaybın geri kazanılabileceği göz önüne alındığında, aylık 750 ton granül israfı önlenecektir. Çalışmalar, seramik pres makinelerinde sırlı porselen seramik yer karosu hamuru granüllerinde mukavemet artırıcı olarak atık şeker pancarı melası kullanımının, şirkete önemli ekonomik faydalar sağlayacağını ve sektörde sürdürülebilirliği destekleyeceğini göstermiştir.

Sonuç—Şeker pancarı melasının kullanımı, seramik ve şeker endüstrilerinin sürdürülebilir gelişimine katkıda bulunacak, çevre kirliliğini önleyecek ve aynı zamanda seramik karoların maliyetini düşürecektir. Atık melası yeniden kullanarak şirket, önemli ekonomik kazanımlar elde edecek ve çevre dostu üretim uygulamalarına öncülük edecektir.

Anahtar Kelimeler

• Seramik bünye çamuru
• seramik karo
• şeker pancarı
• melas.

Use and characterization of sugar beet molasses as a strength enhancer in glazed porcelain ceramic floor tile bodies

Öz

Context—Sugar factories produce large quantities of sugar beet molasses as a byproduct. Although molasses is used in some industrial sectors, our research has shown that it has not been used as a strength enhancer in glazed porcelain ceramic floor tile body sludge granules for ceramic press machines.

Objective—The aim of this article is to investigate the use of sugar beet molasses as a strength enhancer in ceramic floor tile body sludge granules for ceramic press machines in ceramic factories, and to fill this gap in the literature.

Method—Press machines are used in the shaping process of ceramic floor tile production. Due to the lower-than-required moisture content and dry strength values of the granules, approximately 10% losses occur in ceramic tile production during and after glazing, and at the firing stage. To minimize these losses and achieve this at the lowest possible cost, sugar beet molasses, a byproduct of sugar factories, were added to standard floor tile body sludge at weight percentages of 0.1%, 0.2%, 0.3%, 0.4%, and 0.5% to increase its strength. Subsequently, the changes occurring before and after the addition were analyzed using X-ray fluorescence (XRF) spectroscopy, SEM analysis, thermogravimetric analysis (DTA-TG), and physical properties (strength, color measurement, density, flow time, sieve residue, particle size, dry strength, fired strength, shrinkage, water absorption, etc.) and incorporated into the process. The analysis showed that standard floor tile body sludge containing 0.3% sugar beet molasses had higher strength than standard body floor tile sludge without molasses.

Results—In a ceramic factory that consumes approximately 250 tons of granules per day with ceramic press machines, an average of 7500 tons of glazed porcelain ceramic floor tile body granules are used monthly. Considering that the 10% loss due to strength loss in ceramic press machine production can be recovered, the waste of 750 tons of granules per month will be prevented. The studies have shown that using waste sugar beet molasses as a strength enhancer in glazed porcelain ceramic floor tile body slurry granules in ceramic press machines will provide significant economic benefits to the company as well as support sustainability in the sector.

Conclusion—The use of sugar beet molasses will contribute to the sustainable development of the ceramics and sugar industries, prevent environmental pollution, and simultaneously reduce the cost of ceramic tiles. By reusing waste molasses, the company will achieve significant economic gains and will pioneer environmentally friendly production practices.

Anahtar Kelimeler

• Ceramic body sludge
• ceramic tile
• sugar beet
• molasses

Kaynakça

1. Republic of Turkey Ministry of Industry and Technology, “Ceramics Sector Report”. General Directorate of Industry, 2023. Türkiye Cumhuriyeti Sanayi ve Teknoloji Bakanlığı Sanayi Genel Müdürlüğü, “Seramik Sektör Raporu 2022”, Ankara, Türkiye, 2023. https://www.sanayi.gov.tr/assets/pdf/plan-program/SeramikSektorRaporu(2022).pdf?1768780800094.
2. F. Savaş, ”1980’den Günümüze Türk Seramik Karo Endüstrisinde Duvar ve Yer Karosu Tasarımlarının İncelenmesi”, International Journal of Humanities and Art Researches, 7(3), 241-255. https://izlik.org/JA75AG89JN
3. G. S. Stephen, M. J. Shitindi, M. D. Bura, C. A. Kahangwa, E. K. Nassary, “Harnessing the potential of sugarcane-based liquid byproducts-molasses and spentwash (vinasse) for enhanced soil health and environmental quality. A systematic review”, Frontiers in Agronomy, 6, 1358076, 2024. https://doi.org/10.3389/fagro.2024.1358076.
4. M. W. Barsoum, Fundamentals of ceramics, 2nd Ed., Boca Raton, FL, USA, CRC Press, 2019.
5. D. Bloor, R. J. Brook, R. W. Cahn, The encyclopedia of advanced materials, Oxford, UK, Pergamon Press, 1994.
6. R. N. Katz, “Overview of ceramic materials, design, and application”, Mechanical engineers’ handbook: Materials and Mechanical Design, 3rd Ed., M. Kutz, Eds., Hoboken, NJ, USA, John Wiley & Sons, 2006, Chapter 12, 433–449.
7. J. Martin-Marquez, J. Ma Rincon, M. Romero, “Mullite development on firing in porcelain stoneware bodies”, Journal of European Ceramic Society, 30(7), 1599–1607, 2010. https://doi.org/10.1016/j.jeurceramsoc.2010.01.002.
8. Z. B. Ozturk, “Microstructural characterization of mullite and anorthite-based porcelain tile using regional clay”, Journal of Ceramic Processing Research, 17(6), 555–559, 2016.

9. H. F. El-Maghraby, M. M. El-Omla, F. Bondioli, S. M. Naga, “Granite as flux in stoneware tile manufacturing”, Journal of European Ceramic Society, 31(12), 2057–2063, 2011. https://doi.org/10.1016/j.jeurceramsoc.2011.05.023.
10. Z. B. Ozturk, Y. Karaca, S. Kurama, E. Ubay, “Evaluating pumice as a sustainable raw material in porcelain tile production: impact on technical properties”, Journal of the Australian Ceramic Society, 60(5), 1591–1599, 2024. https://doi.org/10.1007/s41779-024-01067-x.
11. J. B. Wachtman, W. R. Cannon, M. J. Matthewson, Mechanical properties of ceramics, Second Edition, Hoboken, NJ, USA, John Wiley & Sons, 2009.
12. F. Altimari, F. Andreola, P. P. Benassi, I. Lancellotti, L. Barbieri, “Pumice and lapillus scraps: New national environmental-friendly chance for the production of ceramic tiles”, Ceramics International, 49 (23), 38743-38753, 2023. https://doi.org/10.1016/j.ceramint.2023.09.211.
13. Z. B. Ozturk, Y. Karaca, B. Kayalı, E. Ubay, “The use and recycling of filter–press cake wastes in eco–friendly porcelain tile formulations”, International Journal of Environmental Science and Technology, 20(6), 6307–6318, 2023. https://doi.org/10.1007/s13762-022-04687-7.
14. K. Dana, J. Dey, S. K. Das, “Synergistic effect of fly ash and blast furnace slag on the mechanical strength of traditional porcelain tiles”, Ceramics International, 31(1), 147–152, 2005. https://doi.org/10.1016/j.ceramint.2004.04.008.
15. A. P. Luz, “Use of glass waste as a raw material in porcelain stone ware tile mixtures”, Ceramics International, 33(5), 761–765, 2007. https://doi.org/10.1016/j.ceramint.2006.01.001.
16. L. -H. Zhao, W. Wei, H. Bai, X. Zhang, D. -Q. Cang, “Synthesis of steel slag ceramics: Chemical composition and crystalline phases of raw materials”, International Journal of Minerals, Metallurgy and Materials, 22(3), 325–333, 2015. https://doi.org/10.1007/s12613-015-1077-z.
17. Z. B. Ozturk, E. E. Gültekin, “Preparation of ceramic wall tiling derived from blast furnace slag”, Ceramics International, 41(9), 12020–12026, 2015. https://doi.org/10.1016/j.ceramint.2015.06.014.
18. B. Tarhan, M. Tarhan, T. Aydin, “Reusing sanitaryware waste products in glazed porcelain tile production”, Ceramics International, 43(3), 3107–3112, 2017. https://doi.org/10.1016/j.ceramint.2016.11.123.
19. T. Aydin, C. Paksoy, “The effect of cement raw mix waste dust on porcelain tile properties”, Journal of the Australian Ceramic Society, 55(1), 37–45, 2019. https://doi.org/10.1007/s41779-018-0208-1.
20. World Sugar Balance, International Sugar Organization (ISO), London, 2025, https://www.isosugar.org/publication/398/quarterly-market-outlook---february-2025.
21. C. Akar, M. Canbaz, “Effect of molasses as an admixture on concrete durability”, Journal of Cleaner Production, 112, 2374-2380, 2016. https://doi.org/10.1016/j.jclepro.2015.09.081.
22. M. Djordjevic, Z. Seres, N. Maravic, M. Sciban, D. Soronja-Simovic, M. Djordjevic “Modified sugar beet pulp and cellulose-based adsorbents as molasses quality enhancers: Assessing the treatment conditions”, LWT-Food Science and Technology, 150, 111988, 2021. https://doi.org/10.1016/j.lwt.2021.111988.
23. G. A. Broderick, W. J. Radloff, “Effect of molasses supplementation on the production of lactating dairy cow fed diets based on alfalfa and corn silage”, Journal of Dairy Science, 87(9), 2997-3009, 2004. https://doi.org/10.3168/jds.S0022-0302(04)73431-1.
24. T. Keskin, P. C. Hallenbeck, “Hydrogen production from sugar industry wastes using single-stage photofermentation”, Bioresource Technology, 112, 131-136, 2012. http://dx.doi.org/10.1016/j.biortech.2012.02.077.
25. V. Valli, A. M. Gómez-Caravaca, M. Di Nunzio, F. Danesi, M. F. Caboni, A. Bordoni, “Sugar cane and sugar beet molasses, antioxidant-rich alternatives to refined sugar”, Journal of Agricultural and Food Chemistry, 60(51), 12508-12515, 2012. http://dx.doi.org/10.1021/jf304416d.
26. A. Barbudo A, J. de Brito, L. Evangelista, M. Bravo, F. Agrela, “Influence of water-reducing admixtures on the mechanical performance of recycled concrete”, Journal of Cleaner Production, 59, 93-98, 2013. https://doi.org/10.1016/j.jclepro.2013.06.022.
27. H. Y. Ersoy, Kompozit Malzeme, İstanbul, Türkiye, Literatür Yayıncılık, 2001.
28. A. Jumadurdiyev, M. H. Ozkul, A. R. Saglam, N. Parlak, “The utilization of beet molasses as a retarding and water-reducing admixture for concrete”, Cement and Concrete Research, 35(5), 874-882, 2005. https://doi.org/10.1016/j.cemconres.2004.04.036.
29. M. Katsioti, P. E. Tsakiridis, P. Giannatos, Z. Tsibouki, J. Marinos, “Characterization of various cement grinding aids and their impact on grindability and cement performance”, Construction and Building Materials, 23(5), 1954-1959, 2009. https://doi.org/10.1016/j.conbuildmat.2008.09.003.
30. H. X. Li, W. Xu, X. J. Yang, J. G. Wu, “Preparation of Portland cement with sugar filter mud as lime-based raw material”, Journal of Cleaner Production, 66, 107-112, 2014. https://doi.org/10.1016/j.jclepro.2013.11.003.
31. H. X. Li, Z. W. Jiang, X. J. Yang, L. Yu, G. F. Zhang, J. G. Wu, X. Y. Liu, “Sustainable resource opportunity for cane molasses: use of cane molasses as a grinding aid in the production of portland cement”, Journal of Cleaner Production, 93, 56-64, 2015. https://doi.org/10.1016/j.jclepro.2015.01.027.
32. M. Nabeel, T. Abbas, F. Ahmed, M. M. Abid, H. Raza, N. Khan, T. Hussain, “Ground-granulated-blast furnace-slag and sugar cane molasses influence on stabilization of claysoil”, Pakistan Journal of Science, 71(4), 273-277, 2019.
33. S. Vinodhkumar, P. Kulanthaivel, A. Kabilan, K. M. Lokeshkanna, “Study of black cotton soil characteristics with molasses”. Asian Journal of Engineering and Applied Technology, 7(S1), 73-77, 2018. https://doi.org/10.51983/ajeat-2018.7.1.857.
34. J. K. M'Ndegwa, “The effect of cane molasses on strength of expansive clay soil”, Journal of Emerging Trends in Engineering and Applied Sciences (JETEAS), 2(6), 1034-1041, 2011.
35. J. E. Jiménez, C. M. Fontes Vieira, H. A. Colorado, “Composite soil made of rubber fibers from waste tires, blended sugar cane molasses, and kaolin clay”, Sustainability, 14(4), 2239, 2022. https://doi.org/10.3390/su14042239.
36. N. Malanda, N. N. Mfoutou, E. E. N. Madila, P. Louzolo-Kimbembe, “Microstructure of Fine Clay Soils Stabilized with Sugarcane Molasses”, Open Journal of Civil Engineering, 12(2), 247-269. 2022. https://doi.org/10.4236/ojce.2022.122015
37. A. M. Erian, M. Sauer, “Utilizing yeasts for the conversion of renewable feedstocks to sugar alcohols- a review”, Bioresource Technology, 346, 126296, 2022. https://doi.org/10.1016/j.biortech.2021.126296.
38. A. Ingaramo, H. Heluane, M. Colombo, M. Cesca, “Water and wastewater eco efficiency indicators for the sugar cane industry”, Journal of Cleaner Production, 17(4), 487-495, 2009. https://doi.org/10.1016/j.jclepro.2008.08.018.
39. A. T. Wynne, J. H. Meyer, “An economic assessment of using molasses and condensed molasses solids as a fertilizer in the South African sugar industry”, Proceedings of the 76th Annual Congress of the South African Sugar Technologists' Association, Mount Edgecombe, South Africa, 30 July-02 August 2002.
40. M. Klaver, A. M. Petersen, J. F. Görgens, “Economic comparison of decentralized versus centralized processing of sugarcane to fructooligosaccharides and ethanol”, Biofuels, Bioproducts & Biorefining-BIOFPR, 17(6), 1566-1578, 2023. https://doi.org/10.1002/bbb.2525.
41. P. Kechagia, D. Koutroumpi, G. Bartzas, A. Peppas, M. Samouhos, S. Deligiannis, P. E. Tsakiridis, “Waste marble dust and recycled glass valorization in the production of ternary blended cements”, Science of the Total Environment, 761, 143224, 2021. https://doi.org/10.1016/j.scitotenv.2020.143224.
42. T. Y. Liu, C. Q. Deng, J. Song, J. Wang, S. H. Jiang, L. Han, J. L. Liu, Z. Y. Zhou, Q. Z. Yang, A. X. Lu, “Preparation of self-foamed glass ceramics based on the cooperative treatment of various solid wastes: Characterization of structure properties and analysis of self-foaming behavior”, Ceramics International, 49(2), 2570-2582, 2023. https://doi.org/10.1016/j.ceramint.2022.09.236.
43. M. M. Parascanu, N. Sanchez, F. Sandoval-Salas, C. M. Carreto, G. Soreanu, L. Sanchez-Silva, “Environmental and economic analysis of bioethanol production from sugarcane molasses and agave juice”, Environmental Science and Pollution Research, 28(45), 64374-64393, 2021. https://doi.org/10.1007/s11356-021-15471-4.
44. Z. B. Ozturk, Y. Karaca, S. Kurama, E. Ubay, U. Cengiz, “Utilizing waste zirconia nozzles for eco-friendly ceramic tile production”, Journal of Ceramic Processing Research, 26(1), 43-50, 2025. https://doi.org/10.36410/jcpr.2025.26.1.43.
45. W. F. Li, S. H. Ma, S. B. Zhang, X. D. Shen, “Physical and chemical studies on cement containing sugarcane molasses”, Journal of Thermal Analysis and Calorimetry, 118(1), 83-91, 2014. https://doi.org/10.1007/s10973-014-3947-4.
46. K. Wisniewska, W. Pichor, E. Kłosek-Wawrzyn, “Influence of firing temperature on phase composition and color properties of ceramic tile bodies”, Materials, 14(21), 6380 2021. https://doi.org/10.3390/ma14216380.
47. Z. B. Ozturk, N. Ay, “An investigation of the effect of alkaline oxides on porcelain tiles using factorial design”, Journal of Ceramic Process Research, 13(5), 635–640, 2012.
48. X. J. Gao, Y. Z. Yang, H. W. Deng, “Utilization of beet molasses as a grinding aid in blended cements”, Construction and Building Materials, 25(9), 3782-3789, 2011. https://doi.org/10.1016/j.conbuildmat.2011.04.041.
49. S. Frybort, R. Mauritz, A. Teischinger, U. Müller, “Cement bonded composites - a mechanical review”, BioResources, 3(2), 602–626, 2008. https://doi.org/10.15376/biores.3.2.602-626.
50. A. Syahfitri, D. Hermawan, S. S. Kusumah, Ismadi, M. A. R. Lubis, B. A. Widyaningrum, M. Ismayati, P. Amanda, R. S. Ningrum, J. Sutiawan, “Conversion of agro-industrial wastes of sorghum bagasse and molasses into lightweight roof tile composite”, Biomass Conversion and Biorefinery, 14(1), 1001-1015, 2024. https://doi.org/10.1007/s13399 022-02435-y.