In this work, a metal-ferroelectric-semiconductor (MFS) type capacitor
was fabricated and admittance measurements were held in a wide frequency range
of 1 kHz-5 MHz at room temperature for the investigation of frequency and
voltage dependence of complex dielectric constant, complex electric modulus and
electrical conductivity of the MFS
capacitor. Bismuth titanate (Bi4Ti3O12) with high dielectric constant was used as
interfacial ferroelectric material and the structure of MFS capacitor was
obtained as Au/Bi4Ti3O12/n-Si. Experimental
results showed that dielectric, modulus and conductivity parameters are strong
functions of frequency and voltage especially in depletion and accumulation
regions due to the existence of surface states (Nss), series
resistance (Rs), interfacial polarization and interfacial layer. It
was found that Rs of the structure and interfacial ferroelectric
layer are efective in accumulation region whereas surface states (Nss)
and interfacial polarization are efective in
depletion region. Also the changes in dielectric, modulus and conductivity
parameters become considerably high particularly at low frequencies due to high
values of Rs and Nss. The observed anomalous peak in voltage dependent plots of
capacitance and dielectric constant was atributed to the particular density
distribution of Nss, Rs and minority carrier injection.
Moreover, the value of conductivity
at low and intermediate frequencies is almost independent of frequency thus low
frequency data was used to extract d.c. conductivity. This work showed that the use of high-dielectric Bi4Ti3O12
as ferroelectric interfacial layer in a MFS capacitor is preferable due to high
values of its dielectric constant compared with traditional insulator layer
materials such as SiO2 and SnO2. Therefore, a MFS
capacitor with Bi4Ti3O12 interfacial layer can
store more energy thanks to its high dielectric constant.
MFS capacitors frequency and voltage dependence surface states and interfacial polarization dielectric properties and electrical modulus
Bölüm | Araştırma Makalesi |
---|---|
Yazarlar | |
Yayımlanma Tarihi | 20 Aralık 2017 |
Gönderilme Tarihi | 18 Kasım 2016 |
Yayımlandığı Sayı | Yıl 2017 |
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