Preparation and Characterisation of Biochar from Hazelnut Shell and Its Adsorption Properties for Methylene Blue Dye

Yıl 2018, Cilt: 21 Sayı: 4, 765 - 776, 01.12.2018

Nihan Kaya Zeynep Yıldız Selim Ceylan

https://doi.org/10.2339/politeknik.386963

Cited By: 8

Öz

One of the major
pollutants in water resources are organic dyes that are widely used by
different industries. Methylene blue (MB) is one of them which is quite harmful
for aquatic life. This pollutant must be removed with proper methods.
Adsorption is one of the most popular methods because of its high purification
yield and known as a cost effective process if the sorbent is inexpensive. In
this study, biochar which is used as an adsorbent has been produced from
hazelnut shells used as the raw material. Chemical, thermal and surface
characteristics of raw hazelnut shell were investigated by FT-IR, TG/DTG, SEM
and elemental analysis. Biochar characteristics were determined by FT-IR, BET
and SEM analysis. The effect of different adsorption parameters such as pH,
initial dye concentration, contact time, adsorbent dosage and temperature on
the adsorption of MB onto hazelnut shell char were examined in batch
experiments. The equilibrium of adsorption was modeled using Langmuir and
Freundlich isotherm models. The maximum adsorption yield of MB was found to be
83% at pH 4.0, adsorbent dosage of 4 g/L, contact time of 300 min., initial dye
concentration of 15 mg/L and temperature of 45 ^oC. In addition, the
Freundlich isotherm was found to be the best fitting isotherm model for the
adsorption process. The pseudo-first-order and pseudo-second-order kinetic
models were applied to the experimental data and thermodynamic parameters such
as Gibbs free energy, enthalpy and entropy were determined. 

Anahtar Kelimeler

Adsorption, methylene blue, hazelnut shell, carbonization, biochar

Kaynakça

• [1] Çalışkan M., Değirmenci M. and Çiner F. "Kot boyama tekstil atıksuyunda kalıcı KOİ’nin belirlenmesi", DEÜ Fen ve Mühendislik Dergisi, 4(1):1-9, (2002).
• [2] Poon C.S., Huang Q. and Fung P.C. "Degradation kinetics of cuprophenyl yellow RL by UV/H2O2/Ultrasonication (US) process in aqueous solution", Chemosphere, 38:1005-1014, (1999).
• [3] Chakraborty S., Chowdhury S. and Saha P., “Adsorption of crystal violet from aqueous solution onto NaOH-modified rice husk”, Carbohydrate Polymers, 86:1533–1541, (2011).
• [4] Rafatullah M., Sulaiman O., Hashim R and Ahmad A., “Adsorption of methylene blue on low-cost adsorbents: A review”, Journal of Hazardous Materials, 177:70-80, (2010).
• [5] Mohammadi A. and Karimi A.A., “Methylene blue removal using surface-modified TiO2 nanoparticles: A comparative study on adsorption and photocatalytic degradation”, J. Water Environ. Nanotechnol., 2(2):118-128, (2017).
• [6] Gaouar-Yadi M., Tizaoui K., Gaouar-Benyelles N. and Benguella B., “Efficient and eco-friendly adsorption using low-cost natural sorbents in waste water treatment”, Indian Journal of Chemical Technology, 23:204-209, (2016).
• [7] Demiral İ. and Aydın Şamdan C., “Preparation and characterisation of activated carbon from pumpkin seed shell using H3PO4”, Anadolu University Journal of Science and Technology A-Applied Sciences and Engineering, 17(1):125-138, (2016).
• [8] Sharma S.K., “Green Chemistry for Dyes Removal from Waste Water: Research Trends and Applications”, Wiley, India, (2015).
• [9] Aygün A., Yenisoy-Karakaş S. and Duman I., “Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties”, Microporous and Mesoporous Materials, 66:189-195, (2003).
• [10] Alade A.O., Amuda O.S., Afolabi A.O. and Adelowo F.E., “Adsorption of acenaphthene unto activated carbon produced from agricultural wastes”, Journal of Environmental Science and Technology, 5(4):192-209, (2012).
• [11] Savova D., Apak E., Ekinci E., Yardim F., Petrov N., Budinova T., Razvigorova M. and Minkova V., “Biomass conversion to carbon adsorbents and gas”, Biomass and Bioenergy, 21:133-142, (2001).
• [12] Kim J.W., Sohn M.H., Kim D.S., Sohn S.M. and Kwon Y.S., “Production of granular activated carbon from waste walnut shell and its adsorption characteristics for Cu2+ ion”, Journal of Hazardous Materials, 85:301-315, (2001).
• [13] Saha P., Chowdhury S., Gupta S. and Kumar I., “Insight into adsorption equilibrium, kinetics and thermodynamics of malachite green onto clayey soil of Indian origin”, Chemical Engineering Journal, 165:874-882, (2010).
• [14] Ferrero F., “Dye removal by low cost adsorbents: Hazelnut shells in comparison with wood sawdust”, Journal of Hazardous Materials, 142:144-152, (2007).
• [15] Ceylan S., Topçu Y., “Pyrolysis kinetics of hazelnut husk using thermogravimetric analysis”, Bioresource Technology, 156:182–188, (2014).
• [16] Sait H. H., Hussain A., Salema A. A., Ani F. N., “Pyrolysis and combustion kinetics of date palm biomass using thermogravimetric analysis”, Bioresource Technology, 118:382–389, (2012).
• [17] Saidur R., Abdelaziza E. A., Demirbas A., Hossaina M. S., Mekhile S., “A review on biomass as a fuel for boilers”, Renewable and Sustainable Energy Reviews, 15:2262–2289, (2011).
• [18] Li S., Chen X., Liu A., Wang L., Yu G., “Co-pyrolysis characteristic of biomass and bituminous coal”, Bioresource Technology, 179:414–420, (2015).
• [19] Odeh A. O., “Oualitative and quantitative ATR-FTIR analysis and its application to coal char of different ranks”, Journal of Fuel Chemistry and Technology, 43:129-137, (2015).
• [20] Plis A., Lasek J., Skawinska A., Zuwala J., “Thermochemical and kinetic analysis of the pyrolysis process in cladophora glomerata algae”, Journal of Analytical and Applied Pyrolysis, 115:166–174, (2015).
• [21] Ghaffar S.H. and Fan M., “Structural analysis for lignin characteristics in biomass straw”, Biomass and Bioenergy, 57:264-279, (2013).
• [22] Chen Z., Hu M., Zhu X., Guo D., Liu S., Hu Z., Xiao B., Wang J., Laghari M., “Characteristics and kinetic study on pyrolysis of five lignocellulosic biomass via thermogravimetric analysis”, Bioresour. Technol., 192:441–450, (2015).
• [23] Hu M., Chen Z., Wang S., Guo D., Ma C., Zhou Y., Chen J., Laghari M., Fazal S., Xiao B., Zhang B., Ma S., “Thermogravimetric kinetics of lignocellulosic biomass slow pyrolysis using distributed activation energy model, Fraser–Suzuki deconvolution, and iso-conversional method”, Energy Convers. Manag., 118:1–11, (2016).
• [24] Biswas B., Pandey N., Bisht Y., Singh R., Kumar J., Bhaskar T., “Pyrolysis of agricultural biomass residues: Comparative study of corn cob, wheat straw, rice straw and rice husk”, Bioresour. Technol., 237:57-63, (2017).
• [25] Aljeboree A.M., Alshirifi A.N., Alkaim A.F., “Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon”, Arabian Journal of Chemistry, 10:S3381-S3393, (2017).
• [26] Ahmad R., “Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP)”, Journal of Hazardous Materials, 171:767-773, (2009).
• [27] Luk C.J., Yip J., Yuen C.M., Kan C. and Lam K., “A comprehensive study on adsorption behaviour of direct, reactive and acid dyes on crosslinked and non-crosslinked chitosan beads”, Journal of Fiber Bioengineering and Informatics, 7(1):35–52, (2014).
• [28] Chowdhury S., Chakraborty S. and Saha P., “Biosorption of basic green 4 from aqueous solution by ananas comosus (pineapple) leaf powder”, Colloids and Surfaces B: Biointerfaces, 84:520-527, (2011).
• [29] Dawood S. and Sen T.K., “Review on dye removal from its aqueous solution into alternative cost effective and non-conventional adsorbents”, Journal of Chemical and Process Engineering, 1(104):1-11, (2014).
• [30] Doğan M., Abak H. and Alkan M., “Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters”, Journal of Hazardous Materials, 164:172-181, (2009).
• [31] Karaca S., Gürses A., Açıkyıldız M. and Ejder Korucu M., “Adsorption of cationic dye from aqueous solutions by activated carbon”, Microporous and Mesoporous Materials, 115:376-382, (2008).
• [32] Belhachemi M. and Addoun F., “Comparative adsorption isotherms and modeling of methylene blue onto activated carbons”, Appl. Water Sci., 1:111-117, (2011).
• [33] Kumar P.S., Anne Fernando P.S., Ahmed R.T., Srinath R., Priyadharshini M., Vignesh A.M. and Thanjiappan A., “Effect of temperature on the adsorption of methylene blue dye onto sulfuric acid–treated orange peel”, Chemical Engineering Communications, 201(11):1526-1547, (2014).
• [34] Aksu Z. and Kabasakal E., “Adsorption characteristics of 2,4-dichlorophenoxyacetic acid (2,4-D) from aqueous solution on powdered activated carbon”, Journal of Environmental Science and Health, Part B, 40(4):545-570, (2005).
• [35] Al-Rubayee W.T., Abdul-Rasheed O.F., Mustafa Ali N., “Preparation of a modified nanoalumina sorbent for the removal of alizarin yellow R and methylene blue dyes from aqueous solutions”, Journal of Chemistry, 1-12, (2016).