Synthesis and Characterization of Copper Metal Matrix Composite Reinforced with Ceramic Oxide Extracted By The Green Route
Yıl 2022,
Cilt: 25 Sayı: 3, 1185 - 1189, 01.10.2022
Meena Laad
Öz
The paper presents the synthesis and characterization of Copper metal matrix composite reinforced with silica using powder metallurgy route. The 5%wt of silica is reinforced with copper metal as matrix material. 5% wt Magnesium was added as wetting agent as copper shows poor wettability towards silica. The reinforced silica was extracted from agro waste rice husk ash under controlled conditions of sintering temperature and duration of heating from rice husk ash using alkali extraction method. Reflux method was used to extract nanosilica from silica. Silica and the composite were characterized for microstructural studies, elemental composition and surface morphologies using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray (EDX) and Transmission Electron Microscopy (TEM). The synthesized copper silica composite was studied for structural, compositional and mechanical properties. The results showed that the copper metal matrix composite reinforced with silica showed improved mechanical behavior and can be used in all such applications where light weight and better mechanical strength from copper metal are expected. As the filler material silica is extracted from green route which partially replaces the expensive metal, this work reports a non-toxic, cost effective, light weight and improved mechanical strength substitute for copper metal applications.
Destekleyen Kurum
UGC-DAE Consortium for Scientific Research, Indore, M.P. India
Proje Numarası
CSR/Acctts/2020-21/326
Teşekkür
I thank Prof. Dr. Hakan Ates for inviting me the the ICMATSE2020 conference and giving the opportunity to present my work.
Kaynakça
- [1] Laad M., Jatti V., “Investigation into the effect of Aluminium powder on mechanical , tribological and Electrical properties of Al-ABSComposites”,WseasTransactions on Applied and Theoritical Mechanics , E-ISSN: 2224-3429, 10, 47-53.
- [2] Mallik S., N. Ekere, C. Best, R. Bhatti, “Investigation of thermal management materials for automotive electronic control units”., Appl ThermEng, 31: 355-362, (2011).
- [3] A. Molina, T. Wang, C. Zou, Z. Chen, M. Li, W. Wang, et al. “In situ synthesis of TiB2 particulate reinforced copper matrix composite with a rotating magnetic field”., Mater Des, 65: 280-288, (2015).
- [4] S. Kumari, A. Kumar, P.R. Sengupta, P.K. Dutta, R.B.
Mathur “Improving the mechanical and thermal properties of semi-coke based carbon/copper composites reinforced using carbon nanotubes”., J Adv Mater Lett, 5: 265-271, (2014).
- [5] R. Zitoune, M. El Mansori, K. Vijayan “Tribo-functional design of double cone drill implications in tool wear during drilling of copper mesh/CFRP/woven ply”Wear, 302: 1560-1567, (2013).
- [6] M. Yusoff, R. Othman, Z. Hussain “Mechanical alloying and sintering of nanostructured tungsten carbide-reinforced copper composite and its characterization” Mater Des, 32: 3293-3298, (2011).
- [7] A.A. Thakre, S. Soni “Modeling of burr size in drilling of aluminum silicon carbide composites using response surface methodology”Eng Sci Technol, 19: 1199-1205, (2016).
- [8] Wąsik, Mateusz &Karwan-Baczewska, Joanna. “Copper Metal Matrix Composites Reinforced by Titanium Nitride Particles”. Key Engineering Materials. 682: 270-275, (2016).
- [9] R. Sathiskumar, N. Murugan, I. Dinaharan, S.J. Vijay “Fabrication and characterization of Cu/B4c surface dispersion strengthened composite using friction stir processing” ., 59: 83-89, (2014).
- [10] W.V. Sagar, S.L. Samir, W.R. Amit “Modelling of Cu-Al2O3 metal matrix composite prepared by powder metallurgy route”Int. J. Eng. Adv. Technol., 3: 330-332, (2013).
- [11] M. Yusoff, R. Othman, Z. Hussain “Mechanical alloying and sintering of nanostructured tungsten carbide-reinforced copper composite and its characterization”Mater. Des., 32: 3293-3298, (2011).
- [12]Q. Kang, X. He, S. Ren, L. Zhang, M. Wu, C. Guo, W. Cui, X. Qu “Preparation of copper–diamond composites with chromium carbide coatings on diamond particles for heat sink applications”Appl. Therm. Eng., 60: 423-429, (2013).
- [13] . Zhang, X.H. Qu, X.B. He, B.H. Duan, S.B. Ren,
M.L. Qin “Thermo-physical and mechanical properties of high volume fraction SiCp/Cu composites prepared by pressureless infiltration”Mater. Sci. Eng., A, 489: 285-293, (2008).
- [14] B..M. Girish, B.R. Basawaraj, B.M. Satish, D.R.
“SomashElectrical resistivity and mechanical properties of tungsten carbide reinforced copper alloy composites” Int. J. Comput. Mater., 2 (3): 37-42, (2012).
- [15] V. Aleksandar, R. Viseslava, Z. FatimaFriction and wear properties of copper based composites reinforced with micro and nano-sized Al2O3 particles 8th Int. conf. Tribol., 30th Oct-1st Nov. 2014, Sinaia, Romania, 357-358, (2014).
- [16] A.A. Thakre, S. Soni “Modeling of burr size in drilling of aluminum silicon carbide composites using response surface methodology”Eng. Sci. Technol., 19: 1199-1205, (2016).
- [17] I. Dinaharan, N. Murugan, A. Thangarasu “Development of empirical relationships for prediction of mechanical and wear properties of AA6082 aluminum matrix composites produced using friction stir processing”Eng. Sci. Technol., 19: 1132-1144, (2016).
- [18] M. Laad, “Extraction and Characterization of silica from agro-waste for energy applications”, IEEE International Conference on Energy, Communication, Data Analytics and Soft Computing (ICECDS-2017), 1(V): 233-239.
- [19] R.W.G.Wyckoff, Am.J.Sci.,1925,9,448-459.
- [20] B. T. Ferreira, L.J. Silva, T. H. Panzera, J. C. Santos, R. T. Freire, F. “Scarpa,Sisal-glass hybrid composites reinforced with silica microparticles”, Polymer Testing, 74: 57-62, ISSN 0142-9418, 2019.
- [21] S. Choi, J. Changwoon, B. “Properties of natural rubber composites reinforced with silica or carbon black: influence of cure accelerator content and filler dispersion”. Polymer International, 52: 1382 - 1389, 2003.
- [22] H.H.Xu,J.B.Quinn, A.A.Giuseppetti, F.C.Eichmiller, E.E.Parry, G.E.Schumacher, “Three-body wear of dental resin composites reinforced with silica-fused whisker”, Dent Mater.2004, 20(3): 220-227.
Synthesis and Characterization of Copper Metal Matrix Composite Reinforced with Ceramic Oxide Extracted By The Green Route
Yıl 2022,
Cilt: 25 Sayı: 3, 1185 - 1189, 01.10.2022
Meena Laad
Öz
The paper presents the synthesis and characterization of Copper metal matrix composite reinforced with silica using powder metallurgy route. The 5%wt of silica is reinforced with copper metal as matrix material. 5% wt Magnesium was added as wetting agent as copper shows poor wettability towards silica. The reinforced silica was extracted from agro waste rice husk ash under controlled conditions of sintering temperature and duration of heating from rice husk ash using alkali extraction method. Reflux method was used to extract nanosilica from silica. Silica and the composite were characterized for microstructural studies, elemental composition and surface morphologies using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray (EDX) and Transmission Electron Microscopy (TEM). The synthesized copper silica composite was studied for structural, compositional and mechanical properties. The results showed that the copper metal matrix composite reinforced with silica showed improved mechanical behavior and can be used in all such applications where light weight and better mechanical strength from copper metal are expected. As the filler material silica is extracted from green route which partially replaces the expensive metal, this work reports a non-toxic, cost effective, light weight and improved mechanical strength substitute for copper metal applications.
Proje Numarası
CSR/Acctts/2020-21/326
Kaynakça
- [1] Laad M., Jatti V., “Investigation into the effect of Aluminium powder on mechanical , tribological and Electrical properties of Al-ABSComposites”,WseasTransactions on Applied and Theoritical Mechanics , E-ISSN: 2224-3429, 10, 47-53.
- [2] Mallik S., N. Ekere, C. Best, R. Bhatti, “Investigation of thermal management materials for automotive electronic control units”., Appl ThermEng, 31: 355-362, (2011).
- [3] A. Molina, T. Wang, C. Zou, Z. Chen, M. Li, W. Wang, et al. “In situ synthesis of TiB2 particulate reinforced copper matrix composite with a rotating magnetic field”., Mater Des, 65: 280-288, (2015).
- [4] S. Kumari, A. Kumar, P.R. Sengupta, P.K. Dutta, R.B.
Mathur “Improving the mechanical and thermal properties of semi-coke based carbon/copper composites reinforced using carbon nanotubes”., J Adv Mater Lett, 5: 265-271, (2014).
- [5] R. Zitoune, M. El Mansori, K. Vijayan “Tribo-functional design of double cone drill implications in tool wear during drilling of copper mesh/CFRP/woven ply”Wear, 302: 1560-1567, (2013).
- [6] M. Yusoff, R. Othman, Z. Hussain “Mechanical alloying and sintering of nanostructured tungsten carbide-reinforced copper composite and its characterization” Mater Des, 32: 3293-3298, (2011).
- [7] A.A. Thakre, S. Soni “Modeling of burr size in drilling of aluminum silicon carbide composites using response surface methodology”Eng Sci Technol, 19: 1199-1205, (2016).
- [8] Wąsik, Mateusz &Karwan-Baczewska, Joanna. “Copper Metal Matrix Composites Reinforced by Titanium Nitride Particles”. Key Engineering Materials. 682: 270-275, (2016).
- [9] R. Sathiskumar, N. Murugan, I. Dinaharan, S.J. Vijay “Fabrication and characterization of Cu/B4c surface dispersion strengthened composite using friction stir processing” ., 59: 83-89, (2014).
- [10] W.V. Sagar, S.L. Samir, W.R. Amit “Modelling of Cu-Al2O3 metal matrix composite prepared by powder metallurgy route”Int. J. Eng. Adv. Technol., 3: 330-332, (2013).
- [11] M. Yusoff, R. Othman, Z. Hussain “Mechanical alloying and sintering of nanostructured tungsten carbide-reinforced copper composite and its characterization”Mater. Des., 32: 3293-3298, (2011).
- [12]Q. Kang, X. He, S. Ren, L. Zhang, M. Wu, C. Guo, W. Cui, X. Qu “Preparation of copper–diamond composites with chromium carbide coatings on diamond particles for heat sink applications”Appl. Therm. Eng., 60: 423-429, (2013).
- [13] . Zhang, X.H. Qu, X.B. He, B.H. Duan, S.B. Ren,
M.L. Qin “Thermo-physical and mechanical properties of high volume fraction SiCp/Cu composites prepared by pressureless infiltration”Mater. Sci. Eng., A, 489: 285-293, (2008).
- [14] B..M. Girish, B.R. Basawaraj, B.M. Satish, D.R.
“SomashElectrical resistivity and mechanical properties of tungsten carbide reinforced copper alloy composites” Int. J. Comput. Mater., 2 (3): 37-42, (2012).
- [15] V. Aleksandar, R. Viseslava, Z. FatimaFriction and wear properties of copper based composites reinforced with micro and nano-sized Al2O3 particles 8th Int. conf. Tribol., 30th Oct-1st Nov. 2014, Sinaia, Romania, 357-358, (2014).
- [16] A.A. Thakre, S. Soni “Modeling of burr size in drilling of aluminum silicon carbide composites using response surface methodology”Eng. Sci. Technol., 19: 1199-1205, (2016).
- [17] I. Dinaharan, N. Murugan, A. Thangarasu “Development of empirical relationships for prediction of mechanical and wear properties of AA6082 aluminum matrix composites produced using friction stir processing”Eng. Sci. Technol., 19: 1132-1144, (2016).
- [18] M. Laad, “Extraction and Characterization of silica from agro-waste for energy applications”, IEEE International Conference on Energy, Communication, Data Analytics and Soft Computing (ICECDS-2017), 1(V): 233-239.
- [19] R.W.G.Wyckoff, Am.J.Sci.,1925,9,448-459.
- [20] B. T. Ferreira, L.J. Silva, T. H. Panzera, J. C. Santos, R. T. Freire, F. “Scarpa,Sisal-glass hybrid composites reinforced with silica microparticles”, Polymer Testing, 74: 57-62, ISSN 0142-9418, 2019.
- [21] S. Choi, J. Changwoon, B. “Properties of natural rubber composites reinforced with silica or carbon black: influence of cure accelerator content and filler dispersion”. Polymer International, 52: 1382 - 1389, 2003.
- [22] H.H.Xu,J.B.Quinn, A.A.Giuseppetti, F.C.Eichmiller, E.E.Parry, G.E.Schumacher, “Three-body wear of dental resin composites reinforced with silica-fused whisker”, Dent Mater.2004, 20(3): 220-227.