Ultrasonik Işıma Altında Sentezlenen Grafen Oksitin CO2 Yakalama Performansı

Yıl 2024, Cilt: 27 Sayı: 2, 681 - 687, 27.03.2024

Deniz Sezgin Müge Sarı Yılmaz

https://doi.org/10.2339/politeknik.1179735

Öz

Günümüzde CO2 yakalama, kontrolsüz salınan CO2 emisyonlarını önemli ölçüde azaltmak için önemli bir teknoloji olarak görülmektedir. CO2 yakalamada grafenin bir türevi olan grafen oksitin kullanılması, grafen oksitin benzersiz morfolojisi nedeniyle büyük ilgi görmektedir. Bu çalışmada, modifiye Hummers yöntemine göre ultrason ışıması altında grafen oksit (GrO) sentezlenmiş ve CO2 yakalama performansı incelenmiştir. Numunenin yapısal özelliklerinin belirlenmesi için X-ışını toz kırınımı (XRD) ve Fourier dönüşümü kızılötesi (FTIR) analizleri uygulanmıştır. GrO'nun CO2 tutma performansı farklı sıcaklıklar altında TG analiziyle incelenmiştir. GrO'nun CO2 adsorpsiyon kapasitesi 25°C'de 1,04 mmol g-1'e ulaştı. Kinetik çalışmadan elde edilen deneysel veriler, Avrami modelinin CO2 adsorpsiyonunu daha iyi tanımladığını ortaya koydu.

Anahtar Kelimeler

Grafen oksit, ultrasonik, CO2 yakalama, kinetic, Graphene oxide, ultrasound, CO2 capture, kinetics

CO2 Capture Performance of Graphene Oxide Synthesized Under Ultrasound Irradiation

Öz

Nowadays, CO2 capture is a vital technology to notably reduce the uncontrolled released CO2 emissions. CO2 capture using graphene oxide, a derivative of graphene, has become of tremendous interest due to its unique morphology. In this present work, graphene oxide (GrO) was synthesized under ultrasound irradiation according to the modified Hummers’ method and its CO2 capture performance was examined. The X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) analyses were applied to explore the structure of the sample. CO2 capture performance of GrO was examined by performing TG analysis under different temperatures. The CO2 adsorption capacity of GrO was reached up to 1.04 mmol g-1 at 25°C. The experimental data getting from the kinetic study revealed that the Avrami model better described the CO2 adsorption.

Anahtar Kelimeler

Graphene oxide, ultrasound, CO2 capture, kinetics

Kaynakça

• [1] Ghanbari T., Abnisa F., Wan Daud WMA., A review on production of metal organic frameworks (MOF) for CO2 adsorption, Science of the Total Environment, 707 (2020).
• [2] Jiménez V., Ramírez-Lucas A., Díaz JA., CO2 capture in different carbon materials, Environ Sci Technol, 46:7407–7414 (2012).
• [3] Hu Y., Lu H., Liu W., Incorporation of CaO into inert supports for enhanced CO2 capture: A review, Chemical Engineering Journal, 396 (2020).
• [4] Sun H., Wu C., Shen B., Progress in the development and application of CaO-based adsorbents for CO2 capture—a review, Materials Today Sustainability, 1–2:1–27 (2018).
• [5] Gao N., Chen K., Quan C., Development of CaO-based adsorbents loaded on charcoal for CO2 capture at high temperature, Fuel, 260, (2020).
• [6] Guo H., Xu Z., Jiang T., The effect of incorporation Mg ions into the crystal lattice of CaO on the high temperature CO2capture, Journal of CO2 Utilization, 37:335–345 (2020).
• [7] Bhatta LKG., Subramanyam S., Chengala MD., Progress in hydrotalcite like compounds and metal-based oxides for CO2 capture: A review, J Clean Prod, 103:171–196 (2015).
• [8] Tan C., Guo Y., Sun J., Structurally improved MgO adsorbents derived from magnesium oxalate precursor for enhanced CO2 capture, Fuel, 278 (2020).
• [9] Geng YQ., Guo YX., Fan B., Research progress of calcium-based adsorbents for CO2 capture and anti-sintering modification, Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 49:998–1013 (2021).
• [10] Huang CH., Chang KP., Yu CT., Development of high-temperature CO2 sorbents made of CaO-based mesoporous silica, Chemical Engineering Journal, 161:129–135 (2010).
• [11] Granados-Pichardo A., Granados-Correa F., Sánchez-Mendieta V., Hernández-Mendoza H., New CaO-based adsorbents prepared by solution combustion and high-energy ball-milling processes for CO2 adsorption: Textural and structural influences, Arabian Journal of Chemistry, 13:171–183 (2020).
• [12] Tan YL., Islam MA., Asif M., Hameed BH., Adsorption of carbon dioxide by sodium hydroxide-modified granular coconut shell activated carbon in a fixed bed, Energy, 77:926–931 (2014).
• [13] Zhao Y., Ding H., Zhong Q., Synthesis, and characterization of MOF-aminated graphite oxide composites for CO2 capture, Appl Surf Sci, 284:138–144 (2013).
• [14] Sari Yilmaz M., Karakas SB., Low-Cost Synthesis of Organic–Inorganic Hybrid MSU-3 from Gold Mine Waste for CO2 Adsorption, Water Air Soil Pollut, 229 (2018).
• [15] Chen C., Yang ST., Ahn WS., Ryoo R., Amine-impregnated silica monolith with a hierarchical pore structure: Enhancement of CO2 capture capacity, Chemical Communications, 3627–3629 (2009).
• [16] Li K., Jiang J., Tian S., Polyethyleneimine-nano silica composites: A low-cost and promising adsorbent for CO2 capture, J Mater Chem A Mater, 3:2166–2175 (2015).
• [17] Sari Yilmaz M., Synthesis of novel amine modified hollow mesoporous silica@Mg-Al layered double hydroxide composite and its application in CO2 adsorption, Microporous and Mesoporous Materials, 245:109–117 (2017).
• [18] Sari Yilmaz M., The CO2 adsorption performance of aminosilane-modified mesoporous silicas, J Therm Anal Calorim, 146:2241–2251 (2021).
• [19] Broda M., Kierzkowska AM., Müller CR., Influence of the calcination and carbonation conditions on the CO2 uptake of synthetic Ca-based CO2 sorbents, Environ Sci Technol, 46:10849–10856 (2012).
• [20] Li Y., Zhao CS., Qu C., CO2 capture using CaO modified with ethanol/water solution during cyclic calcination/carbonation, Chem Eng Technol, 31:237–244 (2008).
• [21] Pham TH., Lee BK., Kim J., Lee CH., Enhancement of CO2 capture by using synthesized nano-zeolite, J Taiwan Inst Chem Eng, 64:220–226 (2016).
• [22] Guo B., Chang L., Xie K., Adsorption of Carbon Dioxide on Activated Carbon, Journal of Natural Gas Chemistry, 15:223-229 (2006).
• [23] Zhang C., Song W., Sun G., CO2 capture with activated carbon grafted by nitrogenous functional groups, Energy and Fuels, 4818–4823 (2013).
• [24] Vorokhta M., Morávková J., Dopita M., Effect of micropores on CO2 capture in ordered mesoporous CMK-3 carbon at atmospheric pressure, Adsorption, 27:1221–1236 (2021).
• [25] Cinke M., Li J., Bauschlicher CW., CO2 adsorption in single-walled carbon nanotubes, Chem Phys Lett, 376:761–766 (2003).
• [26] Wang J., Mei X., Huang L., Synthesis of layered double hydroxides/graphene oxide nanocomposite as a novel high-temperature CO2 adsorbent, Journal of Energy Chemistry, 24:127–137 (2015).
• [27] De Marco M., Menzel R., Bawaked SM., Hybrid effects in graphene oxide/carbon nanotube-supported layered double hydroxides: enhancing the CO2 sorption properties, Carbon N Y, 123:616– 627 (2017).
• [28] Liu Y., Sajjadi B., Chen WY., Chatterjee R., Ultrasound-assisted amine functionalized graphene oxide for enhanced CO2 adsorption, Fuel, 247:10–18 (2019).
• [29] Cai J., Chen J., Zeng P., Molecular Mechanisms of CO2 Adsorption in Diamine-Cross-Linked Graphene Oxide, Chemistry of Materials, 31:3729-3735 (2019).
• [30] Chen D., Feng H., Li J., Graphene oxide: Preparation, functionalization, and electrochemical applications, Chem Rev, 112:6027–6053 (2012).
• [31] White RL., White CM., Turgut H., Comparative studies on copper adsorption by graphene oxide and functionalized graphene oxide nanoparticles, J Taiwan Inst Chem Eng, 85:18–28 (2018).
• [32] Sari Yilmaz M., Graphene oxide/hollow mesoporous silica composite for selective adsorption of methylene blue, Microporous and Mesoporous Materials, 330 (2022).
• [33] Bayer T., Bishop SR., Nishihara M., Characterization of a graphene oxide membrane fuel cell, J Power Sources, 272:239–247 (2014).
• [34] Liu S., Sun L., Xu F., Nanosized Cu-MOFs induced by graphene oxide and enhanced gas storage capacity, Energy Environ Sci, 6:818–823 (2013).
• [35] Chen L., Tang Y., Wang K., Direct electrodeposition of reduced graphene oxide on glassy carbon electrode and its electrochemical application, Electrochem commun, 13:133–137 (2011).
• [36] Johra FT., Jung WG., Hydrothermally reduced graphene oxide as a supercapacitor, Appl Surf Sci, 357:1911–1914 (2015).
• [37] Sontakke AD., Purkait MK., A brief review on graphene oxide Nanoscrolls: Structure, Synthesis, characterization and scope of applications, Chemical Engineering Journal, 420 (2021).
• [38] Zhao Y., Ding H., Zhong Q., Preparation, and characterization of aminated graphite oxide for CO2 capture, Appl Surf Sci, 258:4301–4307 (2012).
• [39] Oh J., Lee JH., Koo JC., Graphene oxide porous paper from amine-functionalized poly(glycidyl methacrylate)/graphene oxide core-shell microspheres, J Mater Chem, 20:9200–9204 (2010).
• [40] Song G., Zhu X., Chen R., An investigation of CO2 adsorption kinetics on porous magnesium oxide, Chemical Engineering Journal, 283:175–183 (2016).
• [41] Loganathan S., Tikmani M., Edubilli S., CO2 adsorption kinetics on mesoporous silica under wide range of pressure and temperature, Chemical Engineering Journal, 256:1–8 (2014).
• [42] Hsan, N., Dutta, P. K., Kumar, S., Bera, R., Das, N. Chitosan grafted graphene oxide aerogel: Synthesis, characterization and carbon dioxide capture study. International Journal Of Biological Macromolecules, 125:300-306 (2019).
• [43] Pokhrel, J., Bhoria, N., Anastasiou, S., Tsoufis, T., Gournis, D., Romanos, G., Karanikolos, G. N. CO2 adsorption behavior of amine-functionalized ZIF-8, graphene oxide, and ZIF-8/graphene oxide composites under dry and wet conditions. Microporous and Mesoporous Materials, 267:53-67 (2018).
• [44] Serna-Guerrero R., Sayari A., Modeling adsorption of CO2 on amine-functionalized mesoporous silica: Kinetics and breakthrough curves, Chemical Engineering Journal, 161:182–190 (2010).
• [45] Songolzadeh M., Soleimani M., Takht Ravanchi M., Using modified Avrami kinetic and two component isotherm equation for modeling of CO2/N2 adsorption over a 13X zeolite bed, J Nat Gas Sci Eng, 27:831–841 (2015).