Cu 4 O 4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi

Elif Güngör

doi:10.19113/sdufbed.19670

Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi

Öz

Polimerik bakır (II) komplekslerinin tasarımı ve sentezi, moleküler biyoloji, manyetizma ve fotolüminesans alanlarındaki potansiyel uygulamalarından dolayı büyük ilgi uyandırmaktadır. Bu çalışmada, fotolüminesans özellikler gösteren {Cu₄O₄} kübik formda, C₃₈H₄₀Cl₄Cu₄N₄O₁₀(1) kompleksi rapor edilmektedir. Kompleks 1, solvotermal reaksiyon ile sentezlendi ve element analizi, FT-IR, katı UV-Vis spektroskopisi ve tek kristal X ışını kırınımı ile karakterize edildi. Kristal yapı çalışmaları, kompleks 1 in kristal yapısındaki dört çekirdekli birimdeki bakır(II) iyonlarının bozulmuş kare piramit geometriye sahip olduğunu gösterdi. Kompleks 1 ve ligandı H₂L’nin katı durumdaki fotolüminesans özellikleri ise görünür bölgede oda sıcaklığında incelendi. Kompleks 1 ve ligandı H₂L UV ışık ile 349 nm de uyarıldığı zaman, kompleks 1 görünür bölgede 452 nm’de şiddetli mor emisyon gösterirken, ligandı H₂L 504 nm’de yeşil emisyon göstermektedir. Bu umut verici fotolüminesans davranış, bu tip bileşikler için duyarlı moleküler cihazlar veya organik ışık yayan diyotlar (OLEDs) için olası uygulamalara kapı açmaktadır.

Anahtar Kelimeler

Schiff baz,Bakır kompleksi; Kristal yapı; Fotolüminesans

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

-

Bölüm

-

Yazarlar

Elif Güngör

Yayımlanma Tarihi

13 Mart 2017

Gönderilme Tarihi

9 Kasım 2016

Kabul Tarihi

-

Yayımlandığı Sayı

Yıl 2017 Cilt: 21 Sayı: 2

DOI

https://doi.org/10.19113/sdufbed.19670

IZ

https://izlik.org/JA73HT92MM

Kaynak Göster

RIS / Bibtex

APA

Güngör, E. (2017). Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(2), 652-658. https://doi.org/10.19113/sdufbed.19670

AMA

1.Güngör E. Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. 2017;21(2):652-658. doi:10.19113/sdufbed.19670

Chicago

Güngör, Elif. 2017. “Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 (2): 652-58. https://doi.org/10.19113/sdufbed.19670.

EndNote

Güngör E (01 Ağustos 2017) Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 2 652–658.

IEEE

[1]E. Güngör, “Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi”, Süleyman Demirel Üniv. Fen Bilim. Enst. Derg., c. 21, sy 2, ss. 652–658, Ağu. 2017, doi: 10.19113/sdufbed.19670.

ISNAD

Güngör, Elif. “Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21/2 (01 Ağustos 2017): 652-658. https://doi.org/10.19113/sdufbed.19670.

JAMA

1.Güngör E. Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. 2017;21:652–658.

MLA

Güngör, Elif. “Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, c. 21, sy 2, Ağustos 2017, ss. 652-8, doi:10.19113/sdufbed.19670.

Vancouver

1.Elif Güngör. Cu4O4 Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. 01 Ağustos 2017;21(2):652-8. doi:10.19113/sdufbed.19670

Cited By

Yeni Eu(III) kompleksinin sentezlenmesi ve fotofiziksel özellikleri

Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi

https://doi.org/10.25092/baunfbed.363733

Cu<sub>4</sub>O<sub>4</sub> Kübik Formdaki Bakır (II) Kompleksinin Yapısal ve Fotolüminesans Özelliklerinin İncelenmesi