Craterellus cornucopioides Biyosorbanı ile Sulu Çözeltilerden Kongo Kırmızısı’nın Biyosorpsiyonu: Kinetik, İzotermal ve Termodinamik Çalışmalar

Yıl 2024, Cilt: 28 Sayı: 3, 325 - 334, 23.12.2024

Şirin Nuray Çakar , Aslı Göçenoğlu Sarıkaya , Bilgen Osman

https://doi.org/10.19113/sdufenbed.1454469

Öz

Bu çalışmada yenilebilir bir mantar türü olan Craterellus cornucopioides biyokütlesinin sulu çözeltilerden Kongo kırmızısının biyosorpsiyonunda biyosorbent olarak kullanımı araştırılmıştır. Biyosorbentin karakterizasyonu gerçekleştirildikten sonra biyosorpsiyon koşulları optimize edilmiştir. Elde edilen verilere göre 0,01 g biyosorbent miktarı kullanılarak pH: 6,0’da 25 ⁰C ortam sıcaklığında 2 saatlik biyosorpsiyonun ardından biyosorpsiyon kapasitesi (qe) 150 mg/L başlangıç Kongo kırmızısı derişimi için 46,22±2,14 mg/g olarak bulunmuştur. Biyosorpsiyonun doğasının aydınlatılabilmesi için biyosorpsiyon izotermleri, biyosorpsiyon kinetiği ve termodinamiği araştırılmıştır. Elde edilen deneysel sonuçların kullanılmasıyla hesaplanan fizikokimyasal parametrelere göre, biyosorpsiyon prosesinin Freundlich izoterm modeline ve yalancı-ikinci derece kinetik modele uygun olduğu görülmüştür. Proses ekzotermik karakterde ve kendiliğinden oluşmaktadır. Son olarak biyosorpsiyon-desorpsiyon çalışmaları gerçekleştirilmiş ve kullanılan biyosorbentin etkin bir şekilde tekrar kullanılabileceği gösterilmiştir. Hazırlanan biyosorbentin sulu çözeltilerden boyar madde gideriminde ucuz, verimli ve etkin bir biyosorbent olacağı düşünülmektedir.

Anahtar Kelimeler

Craterellus cornucopioides, Kongo kırmızısı, Biyosorpsiyon

Proje Numarası

FHIZ-2023-1503

Teşekkür

Bu çalışma BUÜ BAP FHIZ-2023-1503 no’lu proje tarafından desteklenmiştir. BUÜ BAP Koordinatörlüğü'ne teşekkür ederiz.

Biosorption of Congo Red from Aqueous Solutions by Craterellus cornucopioides Biosorbent: Kinetic, Isothermal and Thermodynamic Studies

Öz

In this study, the use of Craterellus cornucopioides biomass, an edible mushroom species, as a biosorbent for the biosorption of Congo red from aqueous solutions was investigated. After characterization of the biosorbent, biosorption conditions were optimized. according to the data obtained, using a biosorbent amount of 0,01 g, at pH: 6.0 at 25 ⁰C ambient temperature after 2 hours of biosorption, the biosorption capacity (qe) was found to be 46.22±2.14 mg/g for an initial Congo red concentration of 150 mg/L. In order to investigate the nature of biosorption, biosorption isotherms, biosorption kinetics and thermodynamic parameters were calculated using the obtained experimental results, the biosorption process was fitted to Freundlich isotherm model and the pseudo-second-order kinetic model. The process is exothermic and occurs spontaneous. Finally, biosorption-desorption studies were carried out and it was shown that the biosorbent can be reused effectively. It is thought that the prepared biosorbent will be cheap, efficient and effective biosorbent for the removal of dyestuff from aqueous solutions.

Anahtar Kelimeler

Craterellus cornucopioides, Congo red, Biosorption

Proje Numarası

FHIZ-2023-1503

Kaynakça

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