Araştırma Makalesi

Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION

Cilt: 5 Sayı: 3 1 Eylül 2017
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Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION

Abstract

Synthesis of carbon supported palladium particles based on a polyol process was investigated. The activity of Pd catalysts, synthesized by microwave assisted polyol method on carbon support, has been examined for formic acid electro-oxidation reaction. The catalysts were characterized with XRD to identify their nanostructure properties. The effect of catalyst preparation parameters on electrocatalytic performance of catalysts was examined. The electrocatalytic properties of Pd/C catalysts for the oxidation of formic acid were investigated by cyclic voltammetry (CV). The electrocatalytic activity of Pd/C synthesized at 30 s and 130 oC are higher than the other Pd/C catalysts synthesized at different temperature and reaction time. It is proposed that the longer reaction time and higher temperature increased the particle size.

Keywords

Kaynakça

  1. Antolini E., 2009, “Palladium in Fuel Cell Catalysis”, Energy & Environmental Science, Vol. 2 (9), pp. 915-931.
  2. Guo, P., Wei, Z., Ye, W., Qin, W., Wang, Q., Guo, X., Lu, C., Zhao, X.S., 2012, “Preparation and Characterization of Nanostructured Pd with High Electrocatalytic Activity”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 395, pp. 75−81.
  3. Harish S., Baranton S., Coutanceau C., Joseph J., 2012, “Microwave Assisted Polyol Method for The Preparation of Pt/C, Ru/C and PtRu/C Nanoparticles and Its Application in Electrooxidation of Methanol” Journal of Power Sources, Vol. 214, pp. 33-39.
  4. Husin M.H.M., Nordin M.R., Mohamad I.S., Yong L.K., 2014, “Pt –Cu Bimetallic Nanoparticles Synthesized by Polyol Method Under Different Reduction Conditions”, Journal of Mechanical Engineering and Technology, Vol. 6 (1), pp. 77-86.
  5. Mazumder V., Lee Y.M., Sun S.H., 2010, “Recent Development of Active Nanoparticle Catalysts for Fuel Cell Reactions”, Advanced Functional Materials, Vol. 20, pp.1224-1231.
  6. Nethravathi C., Anumol E.A., Rajamathi M., Ravishankar N., 2011, “Highly Dispersed Ultrafine Pt and PtRu Nanoparticles on Graphene: Formation Mechanism and Electrocatalytic Activity”, Nanoscale, Vol. 3, pp. 569–571.
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Ayrıntılar

Birincil Dil

İngilizce

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yayımlanma Tarihi

1 Eylül 2017

Gönderilme Tarihi

30 Ocak 2017

Kabul Tarihi

3 Mart 2017

Yayımlandığı Sayı

Yıl 2017 Cilt: 5 Sayı: 3

Kaynak Göster

APA
Gökdoğan Şahin, Ö. (2017). Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 5(3), 322-328. https://doi.org/10.15317/Scitech.2017.92
AMA
1.Gökdoğan Şahin Ö. Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION. sujest. 2017;5(3):322-328. doi:10.15317/Scitech.2017.92
Chicago
Gökdoğan Şahin, Özlem. 2017. “Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5 (3): 322-28. https://doi.org/10.15317/Scitech.2017.92.
EndNote
Gökdoğan Şahin Ö (01 Eylül 2017) Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5 3 322–328.
IEEE
[1]Ö. Gökdoğan Şahin, “Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION”, sujest, c. 5, sy 3, ss. 322–328, Eyl. 2017, doi: 10.15317/Scitech.2017.92.
ISNAD
Gökdoğan Şahin, Özlem. “Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 5/3 (01 Eylül 2017): 322-328. https://doi.org/10.15317/Scitech.2017.92.
JAMA
1.Gökdoğan Şahin Ö. Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION. sujest. 2017;5:322–328.
MLA
Gökdoğan Şahin, Özlem. “Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 5, sy 3, Eylül 2017, ss. 322-8, doi:10.15317/Scitech.2017.92.
Vancouver
1.Özlem Gökdoğan Şahin. Pd/C CATALYSTS SYNTHESIZED BY MICROWAVE ASSISTED POLYOL METHOD FOR FORMIC ACID ELECTRO-OXIDATION. sujest. 01 Eylül 2017;5(3):322-8. doi:10.15317/Scitech.2017.92

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