EFFECT OF AGING TIME ON PHASE TRANSFORMATION, MICROSTRUCTURE AND HARDNESS OF Co-Cr-Mo ALLOYS

Öz

The effect of heat-treatment on phase relationships, microstructures and hardness of Co-Cr-Mo alloys were investigated in detail. The samples were produced by investment casting technique and subsequently solutionized (1240 °C for 4 h) and aged (720 °C for 2, 4, 8 and 16 h). Phase analysis of the samples were performed via X-ray diffraction analysis, microstructural examination were done by light optical and scanning electron microscopy. The microstructures of as-cast and short-time (2 and 4 h) aged samples were composed of FCC γ-Co matrix phase and fine M₂₃C₆ (where M= Co, Cr and Mo) precipitates. Increasing the aging time to 8 and 16 h led to partial transformation of FCC γ-Co matrix phase into HCP ε-Co phase. The volume fraction of ε-Co phase increased with increasing aging time. Moreover, hardness of the Co-Cr-Mo samples were significantly enhanced with formation of ε-Co phase.

Anahtar Kelimeler

• Co-Cr-Mo alloys,Hardness,Microstructure

Yaşlandırma Süresinin Co-Cr-Mo Alaşımlarının Faz Dönüşümleri, Mikroyapıları ve Sertliğine Etkisi

Öz

Bu çalışmada, ısıl işlemin Co-Cr-Mo alaşımlarının faz ilişkileri, mikroyapıları ve sertliklerine etkisi detaylı biçimde incelenmiştir. Alaşım hassas döküm yöntemiyle üretilmiş, takiben çözeltiye alma (1240 °C’de 4 saat) ve yaşlandırma (720 °C’de 2, 4, 8 ve 16 saat) ısıl işlemi uygulanmıştır. Numunelerin faz analizleri X-ışınları kırınım yöntemiyle, mikroyapıları ise optik ve taramalı elektron mikrokobisi yöntemleriyle incelenmiştir. Dökülmüş haldeki ve kısa süre (2 ve 4 saat) yaşlandırılmış numunelerin mikroyapıları YMK kristal yapısına sahip γ-Co matris fazı ve M₂₃C₆ (M= Co, Cr ve Mo) tipi ince karbür çökeltilerinden meydana gelmektedir. Artan yaşlandırma süresi ile birlikte γ-Co matris fazı kısmen ε-Co fazına dönüşmüştür. ε-Co fazının miktarı artan yaşlandırma süresi ile artmıştır. Ayrıca, ε-Co fazının oluşumu alaşımın sertliğini önemli ölçüde arttırmıştır.

Anahtar Kelimeler

• Co-Cr-Mo alaşımları,Mikroyapı,Sertlik

Kaynakça

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