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TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ

Yıl 2006, Cilt: 21 Sayı: 1, 1 - 10, 01.03.2006

Öz

Bu çalışmada; laboratuar ölçekli Ardışık Kesikli Reaktör (AKR) kullanılarak tuz (NaCl) ve toksik (Cr6+) şok yüklemelerinin biyolojik atıksu arıtım verimi üzerine etkisi incelenmiştir. Paralel işletilen 2 reaktörden biri kontrol reaktörü olarak çalıştırılırken diğer reaktöre, 20 g/L NaCl, 5 mg/L Cr6+ ve 10 mg/L Cr6+ şok yüklemeleri uygulanmıştır. Reaktörlerde günlük olarak kimyasal oksijen ihtiyacı (KOİ), karışık sıvıdaki askıda katı madde (MLSS), çamur hacim indeksi (ÇHİ), NaCl ve Cr6+ seviyeleri izlenmiştir. NaCl şok yüklemesi KOİ giderim verimini düşürmüş ancak reaktör 3 gün içinde dengeye gelmiştir. 5 mg/L Cr6+ şok yüklemesinde KOİ giderim oranının düşmüş olmasına rağmen sistem 3 gün içinde normal şartlarına dönerken, 10 mg/L Cr6+ şok yüklemesinde KOİ giderim oranı yine düşmüş ancak toksik madde konsantrasyonunun artması nedeniyle dengeye gelme süresi uzamış ve sistem 5. gün sonunda normal işletme şartlarına dönebilmiştir. Tüm şok yüklemelerde MLSS ve ÇHİ değerlerinde çok önemli bir değişiklik olmamıştır.

Kaynakça

  • Akın, B.S., Uğurlu, A. 2003, Biological removal of carbon, nitrogen and phosphorous in a sequencing batch reactor, J. Environ. Sci. Heal. A, 38, 8,1479-1488.
  • APHA (American Public Health Association), 1998, Standard Methods for Examination of Water and Wastewater, 17th ed., Washington, DC, U.S.A.
  • ChuaU, H., 1998, Effects of trace chromium on organic adsorption capacity and organic removal in activated sludge, Sci. Total Environ., 214, 239-245.
  • Banas, J., Plaza, E., Styka, W., Trela, J., 1999, SBR technology used for advanced combined municipal and tannery wastewater treatment with high receiving water standards, Water Sci. Technol., 40, 4-5, 451-458.
  • Fongsatitkul, P., Elefsiniotis, P., Yamasmit, A., Yamasmit, N., 2004, Use of sequencing batch reactors and Fenton’s reagent to treat a wastewater from a textile industry, Biochem. Eng. J., 21, 3, 213-220.
  • Franta, J.R., Wilderer, P.A., 1997, Biological treatment of papermill wastewater by sequencing batch reactor technology to reduce residual organics, Water Sci. Technol., 35, 1,129-136.
  • Gray, N.F., 1989, Biology of Wastewater Treatment, Oxford University Press. U.S.A. New York. Gökçay, C.F., Yetiş, Ü., 1991, Effect of chromium (VI) on activated sludge, Water Res., 25, 65-73.
  • İleri, R., Şengil, İ.A., Kulaç, S., Damar, Y., 2002, Treatment of mixed pharmaceutical industry and domestic wastewater by sequencing batch reactor, 5th Specialised Conference on Small Water and Wastewater Treatment Systems, İstanbul-Türkiye, 447-452.
  • Jirawatjanya, A., 1998, Effects of Chromium (VI) on Kinetic Coefficients in a Completely Mixed Activated Sludge Process, Thesis abstract, Chiang Mai University, Thailand, http://www.chiangmai.ac.th/ abstract/ 1998/ Abstract/ eng/ abstract/ eng 980411.
  • Kargı, F., Uygur, A., 2003, Nutrient loading rate effects on nutrient removal in a five-step sequencing batch reactor, Process Biochem., 34, 313-318.
  • Lee, D.S., Jeon, C.O., Park, J.M., 2001, Biological nitrogen removal with enhanced phosphate uptake in a sequencing batch reactor using single sludge system, Water Res., 35, 16, 3968-3976.
  • Metcalf & Eddy., 2003, Wastewater Engineering: Treatment and Reuse, Fourth Edition, McGraw-Hill International Editions.
  • Obaja, D., Macé,S., Costa, J., Sans, C., Mata-Alvarez, J., 2003, Nitrification, denitrification and biological phosphorus removal in piggery wastewater using a sequencing batch reactor, Bioresource Technol., 87, 1, 103-111.
  • Obaja, D., Macé, S., Mata-Alvarez, J., 2005, Biological nutrient removal by a sequencing batch reactor (SBR) using an internal organic carbon source in digested piggery wastewater, Bioresource Technol., 96, 1, 7-14.
  • Ramirez, C.N., Martinez, S.G., 2000, Phosphorous uptake kinetics in a biofilm sequencing batch reactor, Bioprocess Eng., 23, 143-147.
  • Salvado, H., Mas, M., Menendez, S., Gracia, M.P., 2001, Effect of shock loads of salt on protozoan communities on activated sludge, ACTA Protozool., 40, 177-185.
  • Stasinakis, A.S., Mamais, D., Thomaidis, N.S., Lekkas, D.T., 2002, Effect of chromium (VI) on bacterial kinetics of heterotrofic biomass of activated sludge, Water Res., 36, 3341- 3349.
  • Stasinakis, A.S., Thomaidis, N.S., Mamais, D., Papanikolaou, E.C., Tsakon, A., Lekkas, D.T., 2003, Effect of chromium (VI) addition on the activated sludge process, Water Res., 37, 2140-2148.
  • Taşlı, R., Artan, N., Orhon, D., 1997, The influence of different substrates on enhanced biological phosphorous removal in a sequencing batch reactor, Water Sci. Technol., 35, 1, 75-80.
  • Uygur, A., Kargı, F., 2003, Salt inhibition on biological nutrient removal from saline wastewater in a sequencing batch reactor, Enzyme Microb. Tech., 34, 313-318.
  • http://www.ibec.ie/ ibec/ buspolicies/ buspoliciesdoclib 3.nsf
  • http://www.alken-murray.com/ glossarybug 2.html
  • Yetiş, Ü., Demirer, G., Tekin, H., 1996, Şok krom (VI) yüklemesinin aktif çamur prosesine etkisi, Tr. J. of Eng. Environ. Sci., 22, 445-453.

Effects of Salt (NaCl) and Toxic (Cr6+) Shock Loadings on Oxygen Utilization and Carbon Removal in Sequencing Batch Reactor (SBR)

Yıl 2006, Cilt: 21 Sayı: 1, 1 - 10, 01.03.2006

Öz

In this study, effects of salt (NaCl) and toxic (Cr6+) shock loading on the biological wastewater treatment efficiency were determined by using laboratory scale SBR. For this aim, 2 parallel Sequencing Batch Reactors were used, one was the control and the other was shock loaded reactor. 20 g/L NaCl, 5 mg/L Cr6+ and 10 mg/L Cr6+ shock loadings were applied to one of the reactors. COD, MLSS, SVI, salt (NaCl) ve Cr6+were analyzed daily. In salt shock loading, COD removal efficiency decreased but system returned to steady state conditions within 3 days. Similarly COD removal efficiency decreased and system recovered itself in 3 days in 5 mg/L Cr6+ shock loading, but it took much time to return steady state conditions in 10 mg/L Cr6+ shock loading. In 10 mg/L Cr6+ shock loading, COD removal efficiency decreased and system recovered itself in 5 days. In both shock loadings there were no pronounced differences on MLSS and SVI profiles

Kaynakça

  • Akın, B.S., Uğurlu, A. 2003, Biological removal of carbon, nitrogen and phosphorous in a sequencing batch reactor, J. Environ. Sci. Heal. A, 38, 8,1479-1488.
  • APHA (American Public Health Association), 1998, Standard Methods for Examination of Water and Wastewater, 17th ed., Washington, DC, U.S.A.
  • ChuaU, H., 1998, Effects of trace chromium on organic adsorption capacity and organic removal in activated sludge, Sci. Total Environ., 214, 239-245.
  • Banas, J., Plaza, E., Styka, W., Trela, J., 1999, SBR technology used for advanced combined municipal and tannery wastewater treatment with high receiving water standards, Water Sci. Technol., 40, 4-5, 451-458.
  • Fongsatitkul, P., Elefsiniotis, P., Yamasmit, A., Yamasmit, N., 2004, Use of sequencing batch reactors and Fenton’s reagent to treat a wastewater from a textile industry, Biochem. Eng. J., 21, 3, 213-220.
  • Franta, J.R., Wilderer, P.A., 1997, Biological treatment of papermill wastewater by sequencing batch reactor technology to reduce residual organics, Water Sci. Technol., 35, 1,129-136.
  • Gray, N.F., 1989, Biology of Wastewater Treatment, Oxford University Press. U.S.A. New York. Gökçay, C.F., Yetiş, Ü., 1991, Effect of chromium (VI) on activated sludge, Water Res., 25, 65-73.
  • İleri, R., Şengil, İ.A., Kulaç, S., Damar, Y., 2002, Treatment of mixed pharmaceutical industry and domestic wastewater by sequencing batch reactor, 5th Specialised Conference on Small Water and Wastewater Treatment Systems, İstanbul-Türkiye, 447-452.
  • Jirawatjanya, A., 1998, Effects of Chromium (VI) on Kinetic Coefficients in a Completely Mixed Activated Sludge Process, Thesis abstract, Chiang Mai University, Thailand, http://www.chiangmai.ac.th/ abstract/ 1998/ Abstract/ eng/ abstract/ eng 980411.
  • Kargı, F., Uygur, A., 2003, Nutrient loading rate effects on nutrient removal in a five-step sequencing batch reactor, Process Biochem., 34, 313-318.
  • Lee, D.S., Jeon, C.O., Park, J.M., 2001, Biological nitrogen removal with enhanced phosphate uptake in a sequencing batch reactor using single sludge system, Water Res., 35, 16, 3968-3976.
  • Metcalf & Eddy., 2003, Wastewater Engineering: Treatment and Reuse, Fourth Edition, McGraw-Hill International Editions.
  • Obaja, D., Macé,S., Costa, J., Sans, C., Mata-Alvarez, J., 2003, Nitrification, denitrification and biological phosphorus removal in piggery wastewater using a sequencing batch reactor, Bioresource Technol., 87, 1, 103-111.
  • Obaja, D., Macé, S., Mata-Alvarez, J., 2005, Biological nutrient removal by a sequencing batch reactor (SBR) using an internal organic carbon source in digested piggery wastewater, Bioresource Technol., 96, 1, 7-14.
  • Ramirez, C.N., Martinez, S.G., 2000, Phosphorous uptake kinetics in a biofilm sequencing batch reactor, Bioprocess Eng., 23, 143-147.
  • Salvado, H., Mas, M., Menendez, S., Gracia, M.P., 2001, Effect of shock loads of salt on protozoan communities on activated sludge, ACTA Protozool., 40, 177-185.
  • Stasinakis, A.S., Mamais, D., Thomaidis, N.S., Lekkas, D.T., 2002, Effect of chromium (VI) on bacterial kinetics of heterotrofic biomass of activated sludge, Water Res., 36, 3341- 3349.
  • Stasinakis, A.S., Thomaidis, N.S., Mamais, D., Papanikolaou, E.C., Tsakon, A., Lekkas, D.T., 2003, Effect of chromium (VI) addition on the activated sludge process, Water Res., 37, 2140-2148.
  • Taşlı, R., Artan, N., Orhon, D., 1997, The influence of different substrates on enhanced biological phosphorous removal in a sequencing batch reactor, Water Sci. Technol., 35, 1, 75-80.
  • Uygur, A., Kargı, F., 2003, Salt inhibition on biological nutrient removal from saline wastewater in a sequencing batch reactor, Enzyme Microb. Tech., 34, 313-318.
  • http://www.ibec.ie/ ibec/ buspolicies/ buspoliciesdoclib 3.nsf
  • http://www.alken-murray.com/ glossarybug 2.html
  • Yetiş, Ü., Demirer, G., Tekin, H., 1996, Şok krom (VI) yüklemesinin aktif çamur prosesine etkisi, Tr. J. of Eng. Environ. Sci., 22, 445-453.
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA48AD28JE
Bölüm Makaleler
Yazarlar

Tuba Eğturul Bu kişi benim

Ali Berktay Bu kişi benim

Bilgehan Nas Bu kişi benim

Yayımlanma Tarihi 1 Mart 2006
Yayımlandığı Sayı Yıl 2006 Cilt: 21 Sayı: 1

Kaynak Göster

APA Eğturul, T., Berktay, A., & Nas, B. (2006). TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 21(1), 1-10.
AMA Eğturul T, Berktay A, Nas B. TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ. sujest. Mart 2006;21(1):1-10.
Chicago Eğturul, Tuba, Ali Berktay, ve Bilgehan Nas. “TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 21, sy. 1 (Mart 2006): 1-10.
EndNote Eğturul T, Berktay A, Nas B (01 Mart 2006) TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 21 1 1–10.
IEEE T. Eğturul, A. Berktay, ve B. Nas, “TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ”, sujest, c. 21, sy. 1, ss. 1–10, 2006.
ISNAD Eğturul, Tuba vd. “TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 21/1 (Mart 2006), 1-10.
JAMA Eğturul T, Berktay A, Nas B. TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ. sujest. 2006;21:1–10.
MLA Eğturul, Tuba vd. “TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 21, sy. 1, 2006, ss. 1-10.
Vancouver Eğturul T, Berktay A, Nas B. TUZ (NaCl) VE TOKSİK (Cr6+) ŞOK YÜKLEMELERİN ARDIŞIK KESİKLİ REAKTÖRLERDE (AKR) OKSİJEN KULLANIMI VE KOİ GİDERİMİ ÜZERİNE ETKİSİ. sujest. 2006;21(1):1-10.

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