Hurda Pazarından %5.25 Verimli Boya Duyarlı Güneş Hücrelerinin Üretimine Uzanan Bir Çalışma

Yıl 2018, Cilt: 6 Sayı: 1, 129 - 139, 01.03.2018

Sunay Turkdogan

https://doi.org/10.15317/Scitech.2018.120

Öz

Bu çalışma birçok üniversite ve kurumda sınırlı donanıma sahip olmanın herhangi bir deneysel araştırma yapılmaması için sadece bir bahane olduğunu ortaya koymaktadır. Bu, gelişmiş ülkeler için garip gelebilir; ancak, az gelişmiş ve bazı gelişmekte olan ülkeler için bile en temel sorunlarından biridir. Bu yazıda, çoğunlukla atık/hurda ev cihazları kullanarak bir laboratuvar oluşturma çalışması ve bu laboratuvardaki cihazları kullanarak boya duyarlı güneş hücrelerinin üretimi anlatılmaktadır. Bu çalışmanın özellikle düşük gelirli ülkeler, çok sınırlı bir bütçeye sahip üniversiteler ve araştırma yapmak isteyen öğrenciler ve araştırmacılar için tetikleyici ve cesaret verici bir referans olacağı düşünülmektedir. Hurda malzemeler kullanılarak tasarlanan bazı cihazların kısaca açıklanmasından sonra, AM1.5 benzetimi altında %5.25 güç dönüşüm verimliliğine (PCE) sahip boya duyarlı güneş hücrelerinin üretimi ev yapımı ekipmanlar kullanılarak gösterilecektir. Üretilen cihazların yapısal, elektriksel ve fotovoltaik özellikleri taramalı elektron mikroskopu (SEM), X-ışınları difraksiyonu (XRD), akım-gerilim (IV) karakterizasyon araçları kullanılarak bu çalışmada araştırılmıştır.

Anahtar Kelimeler

Boya Duyarlı Güneş Hücreleri, Ev Yapımı, Optik Takometre, Etüv, Fotovoltaik, Spin Kaplayıcı / Santrifüj

A STUDY FROM JUNK MARKET TO THE PRODUCTION OF 5.25% EFFICIENT DYE-SENSITIZED SOLAR CELLS

Öz

This paper reveals that having limited facilities is just an excuse not to do any experimental research in most of the universities and institutions all over the world. This may sound impractical for developed countries; however, it is one of the most fundamental problems for underdeveloped and even for some of the developing countries. In this paper, a study of building a laboratory mostly using homemade devices from junks is explained. This paper might be a good and encouraging reference especially for low-income countries, some universities/institutions with very limited budget around the world as well as some students/researchers who want to have their own tools to conduct a research. After a brief explanation to build some of the tools using junks, the production of dye-sensitized solar cells using homemade equipments with up to 5.25% power conversion efficiency (PCE) will be demonstrated under AM1.5 simulated light emission. Structural, electrical and photovoltaic properties of the fabricated devices will also be investigated using scanning electron microscopy (SEM), X-ray diffraction spectroscopy (XRD), and current-voltage (IV) characterization tools in this paper.

Anahtar Kelimeler

Dye-sensitized solar cells, Homemade, Optical tachometer, Oven, Photovoltaics (PV), , Spin coater / centrifuge

Kaynakça

• Bianchi, R. F., Panssiera, M. F., Lima, J. P. H., Yagura, L., Andrade, A. M., Faria, R. M., 2006, "Spin Coater based on Brushless DC Motor of Hard Disk Drivers", Progress in Organic Coatings, Vol. 57, No. 1, pp. 33-36.
• Downs, R. T., Hall-Wallace, M., 2003, "The American Mineralogist Crystal Structure Database", American Mineralogist, Vol. 88, pp. 247-250.
• El-Agez, T. M., Taya, S. A., 2014 "Design of a Spectroscopic Ellipsometer by Synchronous Rotation of the Polarizer and Analyzer in Oppositedirections", Microwave and Optical Technology Letters, Vol. 56, No. 12, pp. 2822–2826.
• Ellabban, O., Abu-Rub, H., Blaabjerg, F., 2014, "Renewable Energy Resources: Current Status, Future Prospects and Their Enabling Technology", Renewable and Sustainable Energy Reviews, Vol. 39, pp. 748–764.
• Fan, F., Liu, Z., Yin, L., Nichols, P. L., Ning, H., Turkdogan, S., Ning, C. Z., 2013, "Simultaneous Two-Color Lasing in a Single CdSSe Heterostructure Nanosheet", Semiconductor Science and Technology, Vol. 28, No. 6, pp. 065005.
• Fan, F., Turkdogan, S., Liu, Z., Shelhammer, D., Ning, C. Z., 2015, "A Monolithic White Laser", Nature Nanotechnology, Vol. 10, No. 9, pp. 796-803.
• Feldman, D., 2014, Photovoltaic (PV) Pricing Trends: Historical, Recent, And Near-Term Projections, https://escholarship.org/uc/item/06b4h95q
• Gratzel, M., 2003, "Dye-sensitized Solar Cell", Journal of Photochemistry and Photobiology C, Vol. 4, pp. 145–153.
• Gevorkian, P., 2007, Sustainable Energy Systems Engineering: The Complete Green Building Design Resource, McGraw Hill Professional.
• Green, M. A., Emery, K., Hishikawa, Y., Warta, W., Dunlop, E. D., 2017, "Solar Cell Efficiency Tables (Version 49)", Progress in Photovoltaics: Research and Applications, Vol. 25, pp. 3-13.
• IEA, 2014, Technology Roadmap: Solar Photovoltaic Energy.
• Jose, R., Thavasi, V., Ramakrishna, S., 2009, "Metal Oxides for Dye‐Sensitized Solar Cells", Journal of the American Ceramic Society, Vol. 92, no. 2, pp. 289-301.
• Ji, I., Park, M. J., Jung, J. Y., Choi, M. J., Lee, Y. W., Lee, J. H., Bang, J. H., 2012, "One-dimensional Core/Shell Structured TiO 2/ZnO Heterojunction for Improved Photoelectrochemical Performance", Bulletin of the Korean Chemical Society, Vol. 33, No. 7, pp. 2200-2206.
• Shankleman, J., Martin, C., 2017, "Solar Could Beat Coal to Become the Cheapest Power on Earth". Bloomberg View, Bloomberg LP, Retrieved 3 January 2017.
• Kilic, B., Omay, D., Kosa, E., Trabzon, L., Kizil, H., 2012, "Growth of ZnO Nanostructures on Biopolymer Films", Journal of Materials Science and Engineering A, Vol. 2, No. 12A, pp. 761.
• Kılıç, B., Çelik, V, 2015, "Self-assembled Growth of Tandem Nanostructures based on TiO2 Mesoporous/ZnO Nanowire Arrays and Their Optoelectronic and Photoluminescence Properties", Applied Physics A, Vol. 119, No. 2, pp. 783-790.
• Kilic, B., Turkdogan, S., Astam, A., Ozer, O. C., Asgin, M., Cebeci, H., Urk, D., Mucur, S. P., 2016, "Preparation of Carbon Nanotube/TiO2 Mesoporous Hybrid Photoanode with Iron Pyrite (FeS2) Thin Films Counter Electrodes for Dye-Sensitized Solar Cell", Scientific Reports, Vol. 6, pp. 27052.
• Levelized Cost and Levelized Avoided Cost of New Generation Resources, US Energy Information Administration, Annual Energy Audit 2016, 5 Aug. 2016.
• Parida, B., Iniyan, S., Goic, R., 2011, “A Review of Solar Photovoltaic Technologies”, Renewable and Sustainable Energy Reviews, Vol. 15, no. 3, pp. 1625-1636.
• Scriven, L. E., 1988, "Physics and Applications of Dip Coating and Spin Coating", In MRS Proceedings, Vol. 121, pp. 717.
• Sun, S., Gao, L., Liu, Y., 2010, "Enhanced Dye-Sensitized Solar Cell using Graphene-TiO2 Photoanode Prepared by Heterogeneous Coagulation", Applied Physics Letters, Vol. 96, No. 8, pp. 083113.
• Turkdogan, S., 2012, Nanowire Synthesis and Characterization: Erbium Chloride Silicate and Two Segment Cadmium Sulfide-Cadmium Selenide Nanowires and Belts, Master Thesis, Arizona State University, Electrical Engineering, Tempe.
• Turkdogan, S., 2015, Growth and Characterization of Multisegment Chalcogenide Alloy Nanostructures for Photonic Applications in a Wide Spectral Range, PhD Dissertation, Arizona State University, Electrical Engineering, Tempe.
• Turkdogan, S., Fan, F., Ning, C. Z., 2016, "Color‐Temperature Tuning and Control of Trichromatic White Light Emission from a Multisegment ZnCdSSe Heterostructure Nanosheet", Advanced Functional Materials, Vol. 26, No. 46, pp. 8521-8526.
• Yang, N., Zhai, J., Wang, D., Chen, Y., Jiang, L., 2010, "Two-dimensional Graphene Bridges Enhanced Photoinduced Charge Transport in Dye-Sensitized Solar Cells", ACS Nano, Vol. 4, No. 2, pp. 887-894.
• Yang, Z., Liu, M., Zhang, C., Tjiu, W. W., Liu, T., Peng, H., 2013, "Carbon Nanotubes Bridged with Graphene Nanoribbons and Their Use in High‐Efficiency Dye‐Sensitized Solar Cells", Angewandte Chemie International Edition, Vol. 52, No. 14, pp. 3996-3999.