Boric Acid Removal from Water with Alginate Based Beads and Films as Adsorbents

Yıl 2024, , 21 - 28, 01.10.2024

Kübra Mod , Güler Hasırcı , Nilüfer Hilmioğlu

https://doi.org/10.46810/tdfd.1423670

Öz

High levels of boron cause harmful effects on humans, animals and plants. While boron is an important auxiliary nutrient for plants, excessive amounts cause toxic effects. The removal of boron in wastewater from chemical processes, industrial processes and agriculture is an important field of study. One of the most widely used methods for boron removal is adsorption method due to its low cost and ease of processing. In this study, adsorption method and sodium alginate microcapsules and sodium alginate-carbon nanotube film adsorbents were used as adsorbents for boric acid removal. In adsorption studies, sodium alginate-carbon nanotube film adsorbents with 42.11% boron removal were more efficient than sodium alginate microcapsules As a result of kinetic studies, it was found that the study was consistent with the pseudo-first order kinetic model.

Anahtar Kelimeler

Boric Acid, Microcapsule, Adsorption, Sodium alginate, Film adsorbents, Carbon nanotube

Kaynakça

• Al-Ghouti MA, Khan M. Eggshell membrane as a novel bio sorbent for remediation of boron from desalinated water. Journal of Environmental Management. 2018;207:405–16.
• Gök O, Mesutoğlu ÖÇ. Ağır metallerin giderimi için düşük maliyetli adsorban olarak pirina kullanımı. Journal Of The Faculty Of Engineering And Architecture Of Gazi University. 2017;32(2):507-516.
• Bolaños L, Lukaszewski K, Bonilla I, Blevins D. Why boron?. Plant Physiology and Biochemistry. 2004;42:907-912.
• Meydan E. Boron compounds with magnetic properties and their applicatıon areas in industry. Journal of Scientific Perspectives. 2019;3(1):11-20.
• Bertagnolli C, Grishin A, Vincent T, Guibal E. Boron removal by a composite sorbent: Polyethylenimine/tannic acid derivative immobilized in alginate hydrogel beads. Journal of Environmental Science and Health. 2017;52(4):359-367.
• Çakal GÖY. Dynamic behavior of continuous flow stirred slurry reactors in boric acid production. Ankara: Middle East Technical University; 2004.
• Yılmaz EA. Endüstriyel atıksulardan elektrokoagülasyon yöntemi ile bor giderimi. Erzurum: Atatürk Üniversitesi; 2009.
• Şahin İ. Voltammetrik yöntemlerle bor tayini ve uygulamaları. Balıkesir: Balıkesir Üniversitesi; 2007.
• Aslan K. Borik asitin derişik sulu çözeltilerinden modifiye aktif karbon ve aljinat bazlı adsorbanlar ile giderilmesi. Isparta: Süleyman Demirel Üniversitesi; 2020.
• Küçükyıldırım BO, Eker AA. Karbon nanotüpler, sentezleme yöntemleri ve kullanım alanları. TMMOB MMO Mühendis ve Makina Dergisi. 2012;53(630): 34-44.
• Li Y, Sui K, Liu R, Zhao X, Zhang Y, Liang H, et al. Removal of methyl orange from aqueous solution by calcium alginate/multi-walled carbon nanotubes composite fibers. Energy Procedia. 2012;16:863-868.
• Bhagyaraj S, Al-Ghouti MA, Kasak P, Krupa I. An updated review on boron removal from water through adsorption processes. Emergent Materials. 2021;4: 1167–1186.
• Sarı M. Değişik minerallerin borik asit çözeltilerinde çözünme kinetiği. İstanbul: İstanbul Teknik Üniversitesi; 2008.
• Demey H, Barron-Zambrano J, Mhadhbi T, Miloudi H, Yang Z, Ruiz M, et al. Boron removal from aqueous solutions by using a novel alginate-based sorbent: comparison with al2o3 particles. Polymers. 2019;11(9):1509.
• Zhang J, Cai Y, Liu K. Extremely effective boron removal from water by stable metal organic framework zif-67. Industrial & Engineering Chemistry Research. 2019;58:4199-4207.
• Lyu J, Zhang N, Liu H, Zeng Z, Zhang J, Bai P, et al. Adsorptive removal of boron by zeolitic imidazolate framework: kinetics, isotherms, thermodynamics, mechanism and recycling. Separation and Purification Technology. 2017;187:67–75.
• Dilber Keyis. 3,4 dihidroksi benzaldehit ile modifiye edilmiş kitosan'ın hazırlanması ve sulu ortamlardan bor adsorpsiyon özelliklerinin araştırılması. Aksaray: Aksaray Üniversitesi; 2020.
• Kluczka J, Pudlo W, Krukiewicz K. Boron adsorption removal by commercial andmodified activated carbons. Chemical Engineering Research and Design. 2019;147:30-42.
• Zohdi N, Mahdavi F, Abdullah LC, Choong TSY. Removal of boron from aqueous solution using magnetic carbon nanotube improved with tartaric acid. Journal of Environmental Health Sciences & Engineering. 2014;1–12.
• Oktor, K., Hilmioglu, N. Removal of ammonium from aqueous solutions by adsorption processes using environment friendly natural biopolymer chıtosan. Fresenius environmental bulletin.2021; 30: 1970-1976. Oktor, K., Yuzer, N. Y., Hasirci, G., Hilmioglu, N. . Optimization of Removal of Phosphate from Water by Adsorption Using Biopolymer Chitosan Beads. Water, Air, and Soil Pollution. 2023; 234: 271: 1-14.