BASKI PROSESİNDE ÇAY ATIKLARIYLA RENKLENDİRİLEN SÜRDÜRÜLEBİLİR TEKSTİLLER

Yıl 2025, Cilt: 32 Sayı: 137, 44 - 55, 30.03.2025

Doğa Sude Ordu , Zeynep Ömeroğulları

https://doi.org/10.7216/teksmuh.1593823

Öz

Çalışmanın temel amacı, insan sağlığına ve çevreye karşı tehlike oluşturan sentetik boyarmaddelere alternatif olarak doğal ve sürdürülebilir özellikteki çay posası ile %100 pamuklu kumaşların baskı prosesinde renklendirilmesini kapsamaktadır. Bu amaçla sentetik boyarmadde yerine çay atığının ekstraksiyon yöntemi ile doğal boyarmadde ekstratı elde edilmiş ve ardından çay atığının ekstraktesi baskı patına ilave edilmiş ve baskı işlemi gerçekleştirilmiştir. Çay atıklarından elde edilen doğal boyarmaddenin tekrarlanan yıkamalara karşı dayanıklı hale gelebilmesi için yumuşatıcı apre reçetesine farklı oranlarda kuaterner amonyum bileşiği ilave edilmiştir. Çalışma kapsamında, bu yöntem kullanılarak %100 pamuklu dokuma kumaşların renklendirilmesinde çay atığı ekstraktının uygulanabilirliği araştırılmış ve çay atığı ile renklendirilen %100 pamuklu dokuma kumaşların yıkama dayanımları incelenmiştir. Elde edilen kumaşların ilgili standartlar doğrultusunda haslık testleri yapılmıştır. Test sonuçları incelendiğinde, haslık değerlerinin gri skalaya göre en üst seviyelerde olduğu gözlemlenmiştir. SEM ile atık çay posasının ve kumaş numunelerinin karakterizasyon analizleri, SEM-EDX ile materyalin temel bileşenleri incelenmiştir. Test sonuçlarına göre çay posası ile baskı işlemi görmüş kumaşın K/S renk verimi değeri işlem görmemiş kumaşa göre en yüksek seviyede olduğu görülmüştür. İşlem veya yıkama işleminden sonra haslık değerleinin ciddi derecede değişim göstermediği belirlenmiştir. SEM görüntülerine göre, işlem görmüş numunlerde lifler arası kimyasal birikmeler tespit edilmiştir. Böylece çay atıklarının geri kazanımı ve tekstil terbiyesinde kullanımı sağlanarak sürdürülebilir tekstil ürünleri üretilmiştir.

Anahtar Kelimeler

Sürdürülebilirlik, dokuma kumaş, çay atığı, ekstrakte, baskı.

SUSTAINABLE TEXTILES COLORED WITH TEA WASTE IN THE PRINTING PROCESS

Öz

The primary aim of the study is to explore the use of tea waste, a natural and sustainable material, as an alternative to synthetic dyes that pose risks to human health and the environment in the printing process of 100% cotton fabrics. For this purpose, tea waste was processed using an extraction method to obtain a natural dye extract, which was then added to the printing paste to carry out the printing process. To enhance the wash durability of fabrics dyed with the natural dye derived from tea waste, a softener formulation was modified by incorporating different ratios of quaternary ammonium compounds. The study investigated the applicability of tea waste extract in dyeing 100% cotton woven fabrics and examined the wash fastness of these fabrics. Fastness tests were conducted on the dyed fabrics in accordance with relevant standards, and the results showed that the fastness values were at the highest levels based on the gray scale evaluation. SEM was employed to perform characterization analyses on tea waste and fabric samples. Additionally, SEM-EDX was used to analyze the elemental composition of the materials. According to thes test results, it was found that cotton fabric dyed using tea waste as a natural dye pigment had the highest K/S value when compared to untreated fabric. Fastness properties did not change significantly after application or washing processes. According to SEM analysis, it was determined that the chemical particles of the printing paste were located between the fibers of the treated samples. By repurposing tea waste for use in textile finishing, the study contributes to the production of sustainable textile products.

Anahtar Kelimeler

Sustainability, woven fabric, tea waste, extraction, printing.

Kaynakça

• Keleş, R. & Hamamcı, C., (2002), Çevrebilim, 4. Baskı, İmge Kitabevi, Ankara.
• Houshyar, S. and Amirshahi, S.H., (2002), Treatment of cotton with chitosan and its effect on dyeability with reactive dyes, Iranian Polymer Journal, Vol.11, 295-302.
• Sunerli, E., & Aydın, M. Ç., (2019), Doğal boyamanın farklı tekstil lifleri ile oluşturulan yüzeylere etkisi, The Journal of International Lingual Social and Educational Sciences, 5(1), 196-203.
• Kunz, A., Mansilla, H., & Duran, N., (2002), A degradation and toxicity study of three textile reactive dyes by ozone, Environmental technology, 23(8), 911-918.
• Schneider, K., Hafner., C. and Jäger, I., (2004), Mutagenicity of textile dye products, J. Appl. Toxicol, 24: 83-91.
• Brüschweiler, B., & Merlot, C., (2017), Azo dyes in clothing textiles can be cleaved into a series of mutagenic aromatic amines which are not regulated yet. Regulatory Toxicology and Pharmacology, 88, 214–226.
• Azhdarpoor, A., Nikmanesh, R., & Khademi, F. (2014), A study of Reactive Red 198 adsorption on iron filings from aqueous solutions, Environmental Technology, 35, 2956 - 2960.
• Jabeen, N., & Jabeen, A., (2017), To identify hazards and risks (Health and safety) in the textile dyeing industry, Asian Journal of Home Science, 12, 182-187.
• Basak, S., Senthilkumar, T., Krishnaprasad, G., & Jagajanantha, P. (2020), Sustainable Development in Textile Processing, Sustainable Green Chemical Processes and their Allied Applications,559-573.
• Slama, H., Bouket, A., Pourhassan, Z., Alenezi, F., Silini, A., Cherif-Silini, H., Oszako, T., Luptakova, L., Golińska, P., & Belbahri, L. (2021)., Diversity of Synthetic Dyes from Textile Industries, Discharge Impacts and Treatment Methods, Applied Sciences.
• Fobiri, G., (2022)., Synthetic Dye Application in Textiles: A Review on the Efficacies and Toxicities Involved, Textile & Leather Review.
• Hanafi, M., & Sapawe, N., (2021)., A review on the water problem associate with organic pollutants derived from phenol, methyl orange, and remazol brilliant blue dyes, Materials Today: Proceedings.
• Pizzicato, B., Pacifico, S., Cayuela, D., Mijas, G., & Riba-Moliner, M., (2023)., Advancements in Sustainable Natural Dyes for Textile Applications: A Review, Molecules, 28.
• Jordeva, S., Kertakova, M., Zhezhova, S., Golomeova-Longurova, S., & Mojsov, K., (2020), Dyeing of textiles with natural dyes. Tekstilna industrija.
• Chungkrang, L., & Bhuyan, S., (2020)., Natural Dye Sources and its Applications in Textiles: A Brief Review. International Journal of Current Microbiology and Applied Sciences, 9, 261-269.
• Savvidis, G., Karanikas, E., Nikolaidis, N., Eleftheriadis, I., & Tsatsaroni, E., (2014), Ink‐jet printing of cotton with natural dyes, Coloration Technology, 130, 200-204.
• Patel, B., & Kanade, P., (2019)., Sustainable dyeing and printing with natural colours vis-à-vis preparation of hygienic viscose rayon fabric, Sustainable Materials and Technologies, 22.
• Mondal, B., Kabir, S., Ali, A., & Hannan, M., (2022)., Sustainable Natural Printing of Cotton Fabric Without Metal-Based Mordan,. Journal of Natural Fibers, 19, 15327 - 15342.
• Moldovan, S. Ferrándiz, M. Franco, E. Mira, E. Capablanca, L. & Bonet, M., (2017), Printing of cotton with eco-friendly, red algal pigment from Gracilaria sp., IOP Conference Series: Materials Science and Engineering, 254.
• Rana, M. Hasan, M. Islam, M. Rokonuzzaman, M. Khandaker, S. & Bashar, M., (2022), Printing Effects of Different Natural Colourants on Cotton Fabric, Textile & Leather Review,5,280-295.
• Z., Yusuf, N., Arung, A., & , S., (2020), Characteristic and quality of silk fabric colored using natural dyes, IOP Conference Series: Earth and Environmental Science, 575.
• Turgut, H., Elgün, B., & Yarar, Ö., (2023), Wash fastness properties of pre-mordanting cotton fabrics dyed with natural dyes, Journal of Innovative Engineering and Natural Science.
• Bechtold, T. Turcanu, A. Ganglberger, E. & Geissler, S., (2003), Natural dyes in modern textile dyehouses — how to combine experiences of two centuries to meet the demands of the future? Journal of Cleaner Production, 11, 499-509.
• Baliarsingh, S. Panda, A. Jena, J. Das, T. & Das, N., (2012), Exploring sustainable technique on natural dye extraction from native plants for textile: identification of colourants, colourimetric analysis of dyed yarns and their antimicrobial evaluation, Journal of Cleaner Production, 37, 257-264.
• Nam, C., & Xiang, C. (2019), Natural dyeing application of used coffee grounds as a potential resource, International Journal of Fashion Design, Technology and Education, 12, 335 - 345.
• Zarkogianni, M., Mikropoulou, E., Varella, E., & Tsatsaroni, E. (2011), Colour and fastness of natural dyes: revival of traditional dyeing techniques, Coloration Technology, 127, 18-27.
• El-Apasery, M., Hussein, A., Saleh, M., Eladasy, A., & El-Din, N. (2021), Microwave-assisted dyeing of wool fabrics with natural dyes as eco- friendly dyeing method: part II. The effect of using different mordants. The Egyptian Journal of Chemistry, 0-0.
• Sharif, S., Ahmad, S., & Izhar‐ul‐Haq, M. M. (2007), Role of quaternary ammonium salts in improving the fastness properties of anionic dyes on cellulose fibres, Coloration Technology, 123(1), 8-17.
• Mikhailovskaya, A. P., Serova, N. E., Kalugina, M. S., & Kiselev, A. M. (2014), Evaluation of the intensifying effect of quaternary ammonium salts in the course of dyeing of cellulose materials with active dyes, Russian Journal of Applied Chemistry, 87, 108-113.
• Patel, B. & Kanade, P., (2019), Sustainable dyeing and printing with natural colours vis-à-vis preparation of hygienic viscose rayon fabric, Sustainable Materials and Technologies, 22.
• Haji, A. & Naebe, M., (2020), Cleaner dyeing of textiles using plasma treatment and natural dyes: A review. Journal of Cleaner Production, 265, 121866.
• Kayahan, E. Karaboycı, M. & Dayık, M., (2016), Bitkisel atıklar kullanılarak yün, pamuk ve rejenere soya lifleri için ekolojik boyama, Tekstil ve Mühendis, 23(102), 111-125.
• Tutak, M. & Benli, H., (2008)., Bazı bitkilerden elde edilen doğal boyar maddelerin yünü boyama özelliğinin incelenmesi, Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 10(2), 53-59.
• Arifeen, W. U., Rehman, F. U., Adeel, S., Zuber, M., Ahmad, M. N., & Ahmad, T. (2021), Environmental friendly extraction of walnut bark-based juglone natural colorant for dyeing studies of wool fabric, Environmental Science and Pollution Research, 28(36), 49958-49966.
• Yan, X., Hong, L., Pei, S., Hamilton, A., Sun, H., Yang, R., ... & Yang, L. (2021), A natural yellow colorant from Buddleja officinalis for dyeing hemp fabric, Industrial Crops and Products, 171, 113968.
• Tri, Y. & Nooryan, B., (2023), The development and analysis of eco-print and screen printing combination using natural dyes, Fibres Text, 30, 51-55.
• Ayvaz, K. M. & Teker, M. S., (2023), Türkiye’de doğal boya kullanan tekstil işletmeleri ve bitki atıkları ile sürdürülebilir bir yaklaşım önerisi, Yüzüncü Yıl Üniversitesi Sosyal Bilimler Enstitüsü Dergisi, 59, 348-362.
• Hassan, S. R., & Rahim, N. A. B. C. A. (2021), Extraction of natural dye from black tea waste for cotton dyeing application, Journal of Engineering Science and Technology.
• Sukemi, Pratumyot, K., Srisuwannaket, C., Niamnont, N., & Mingvanish, W. (2019), Dyeing of cotton with the natural dye extracted from waste leaves of green tea (Camellia sinensis var. assamica), Coloration Technology, 135(2), 121-126.
• Hayat, T., Adeel, S., Batool, F., Amin, N., Ahmad, T., & Ozomay, M. (2022), Waste black tea leaves (Camelia sinensis) as a sustainable source of tannin natural colorant for bio-treated silk dyeing, Environmental Science and Pollution Research, 29(16), 24035-24048.
• Sarker, M. K. U., Haque, M. M., Hasan, M. R., Sultana, S., Ray, S. K., & Shaikh, M. A. A. (2024), Utilization of factory tea (Camellia sinensis) wastes in eco-friendly dyeing of jute packaging fabrics. Heliyon, 10(10).
• Triwiswara, M., & Indrayani, L., (2020), Utilization of black tea waste as natural batik dyes on cotton and silk. In IOP Conference Series: Earth and Environmental Science, 456, 1, p. 012051.
• R, P., & Rani, N., (2023)., Dyeıng at home from kıtchen waste - tea and coffee resıdue, ShodhKosh: Journal of Visual and Performing Arts.
• TS EN ISO 13937-2: 13.03.2002, Tearing properties of fabrics - Part 2: Determination of tearing strength of test specimens in trouser form (single tearing method).
• TS EN ISO 105-C06: 12.04.2012, Colour fastness tests - Part C06: Colour fastness to domestic and commercial washing.
• TS EN ISO 105-E04: 12.06.2013, Colour fastness tests - Part E04: Colour fastness to sweat.
• TS EN ISO 105-E01: 12.06.2013, Colour fastness tests, Part E01: Colour fastness to water.
• TS EN ISO 105-X12: 09.12.2016, Colour fastness tests - Part X12: Determination of colour fastness to rubbing.
• Öner, E., (2007), Optik Ağartma İşlemi Görmüş veya Fluoresans Boyarmaddeler ile Boyanmış Tekstil Materyallerinde Renk Ölçümü, XI. Tekstil Teknolojisi ve Kimyasındaki Son Gelişmeler Sempozyumu, 1-12, 2007, Bursa, Türkiye.
• Mršić, G., & Žugaj, S., (2007), Analiza GSR čestica upotrebom elektronskog mikroskopa (SEM/EDX), Policija i sigurnost, 16(3-4), 179-200.
• Zhang, S. Yang, X. Tang, B. Yuan, L. Wang, K. Liu, X. Zhu, X. Li, J. Ge, Z. & Chen, S., (2018), New insights into synergistic antimicrobial and antifouling cotton fabrics via dually finished with quaternary ammonium salt and zwitterionic sulfobetaine, Chemical Engineering Journal, 336, 123-132.
• Akpınar, E. S., (2019), Antibakteriyel bitim işleminin pamuklu çarşaflık kumaşların bazı mekanik özellikleri üzerindeki etkilerinin incelenmesi (Master's thesis, Pamukkale Üniversitesi Fen Bilimleri Enstitüsü).
• Can, Y., & Kırtay, E., (2007), Pamuklu bezayağı kumaşların yırtılma mukavemetlerine etki eden iplik özellikleri. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 7(2), 65-78.
• Mršić, G., & Žugaj, S., (2007), Analiza GSR čestica upotrebom elektronskog mikroskopa (SEM/EDX) Policija i sigurnost, 16(3-4), 179-200.
• Litim, N., Baffoun, A., & Abdessalem, S., (2016), Impact of Modified Dmdheu and Copolymer Acrylic Resin Using Spraying Treatment Before and After an Enzymatic Washing on the Mechanical Properties of Denim Cotton Fabric, viXra.
• Xu, F., Yang, Y., Zhang, G., Zhang, F., & Zhang, Y., (2015), A self-stiffness finishing for cotton fabric with N-methylmorpholine-N-oxide. Cellulose, 22, 2837-2844.
• Gündüz, G. Ş. (2024), İpliği Boyalı Pamuklu Kumaşlarda Sürtme Haslığının Aşınma ve Yıkama Etkisiyle Değişimi, Karadeniz Fen Bilimleri Dergisi, 14(2), 434-447.
• Akar, E., Bulut, M. O., & Baydar, H. (2013), Katyonikleştirilmiş pamuklu kumaşın gül posası ile doğal boyanması ve haslık özelliklerinin incelenmesi, Erciyes Üniversitesi Fen Bilimleri Enstitüsü Fen Bilimleri Dergisi, 29(3), 213-219.
• Uzdigim, G., & Akyol, A. A. (2017), Prof. Ülker Muncuk Müzesinde Bulunan Örtülerde Belgeleme Çalışmaları ve Boyarmadde Analizleri, Sanat ve Tasarım Dergisi, (20), 287-299.
• Duran K,. (2001), Tekstilde Renk Ölçümü ve Reçete Çıkarma, Ege Üniversitesi.
• Yakupoğlu, T., & Özdemir, N. (2007), Erozyona uğramış topraklara uygulanan arıtma çamuru ve çay endüstrisi atığının toprakların mikro element içeriklerine etkileri, Anadolu Tarım Bilimleri Dergisi, 22(2), 207-213.
• Müftüoğlu, N. M., Türkmen, C., & Kavdır, Y. (2019), Çay çöpünden kompost yapımı ve oluşan kompostun bazı özellikler, Mediterranean Agricultural Sciences, 32, 109-114.
• Li, T., Xu, S., Wang, Y., Wei, Y., Shi, L., Xiao, Z., ... & Ning, J. (2021), Quality chemical analysis of crush–tear–curl (CTC) black tea from different geographical regions based on UHPLC‐Orbitrap‐MS, Journal of Food Science, 86(9), 3909-3925.
• Liu, J., Dong, C., Zhang, Z., Sun, H., Kong, D., & Lu, Z. (2020), Durable flame retardant cotton fabrics modified with a novel silicon–phosphorus–nitrogen synergistic flame retardant, Cellulose, 27, 9027-9043.
• Nallathambi, A., & Rengaswami, G. D. V. (2016), Salt-free reactive dyeing of cotton hosiery fabrics by exhaust application of cationic agent, Carbohydrate Polymers, 152, 1-11.
• Sergin, E., & Akşit, A. (2024), Pamuklu kumaşların boyama ve güç tutuşurluk bitim işlemlerinin sol-jel yöntemi ile tek adımda uygulanması, Tekstil ve Mühendis, 31(135), 155-167.
• Eduok, U., Faye, O., & Szpunar, J. (2017), Recent developments and applications of protective silicone coatings: A review of PDMS functional materials, Progress in Organic Coatings, 111, 124-163.
• Pfleiderer, B., Moore, A., Tokareva, E., Ackerman, J., & Garrido, L. (1999), Biodegradation of polysiloxanes in lymph nodes of rats measured with 29Si NMR, Biomaterials, 20 6, 561-71.
• Zuo, Y., Gou, Z., Cao, J., Li, X., & Feng, S. (2016), A new approach for the synthesis of sulfur-bridged polysiloxanes via thiol–ene “click” reaction and their post-functionalization to obtain luminescent materials, RSC Advances, 6, 45193-45201.
• Deng, S. L., Zhao, J. X., & Wen, Z. X. (2018), Self-assembly of quaternary ammonium gemini surfactants in cyclohexane upon reinforcement by simple counterions, RSC advances, 8(34), 18880-18888.