TABAN SICAKLIĞININ ZnO FİLMLERİNİN YAPISAL VE ELEKTRİKSEL ÖZELLİKLERİNE ETKİSİ
Yıl 2006,
Cilt: 7 Sayı: 2, 153 - 159, 05.08.2016
Müjdat Çaglar
Saliha Ilıcan
Yasemin Çağlar
Öz
Çinko oksit (ZnO) filmleri püskürtme yöntemi kullanılarak farklı taban sıcaklıklarında üretilmiştir. Üretilen bu filmlerin yapısal ve elektriksel özelliklerine taban sıcaklığının etkisi incelenmiştir. Filmlerin x-ışınları kırınım desenlerinden polikristal ve hekzagonal yapıda oldukları görülmüştür. Buradan tanecik boyutu ve yapılanma katsayısı (TC) hesaplanmıştır. ZnO filmlerinin iletkenlikleri karanlıkta ve oda sıcaklığında alınan akım-voltaj ölçümlerinden belirlenmiştir. Bütün filmlerin ohmik iletim mekanizmasına sahip olduğu gözlenmiştir.
Kaynakça
- 1. BACHARI EM, BAUD G, BEN AMOR S, JACQUET M. Structural and optical properties of sputtered ZnO films. Thin Solid Films. 348: 165-172, 1999.
- 2. BARRET CS, MASSALSKI TB. Structure of Metals, Pergamon Press, Oxford, 1980.
- 3. CULLITY BD. Elements of X-ray diffraction, 2nd ed., Addison Wesley, 1978.
- 4. ILICAN S, CAGLAR Y, CAGLAR M. X-Ray diffraction studies of undoped and In-doped Cd0.22Zn0.78S films deposited by spray pyrolysis. Çankaya University Journal of Arts and Sciences. 3: 85-94, 2005.
- 5. KOZUKA H, YOKO T, OHYAMA M. Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution. Thin Solid Films. 306: 78-85, 1997.
- 6. KRUNKS M, MELLIKOV E. Zinc oxide thin films by the spray pyrolysis method. Thin Solid Films. 270: 33- 36, 1995.
- 7. LI XH, HUANG AP, ZHU MK, XU SHL, CHEN J, WANG H, WANG B, YAN H. Influence of substrate temperature on the orientation and optical properties of sputtered ZnO films. Materials Letters. 57: 4655-
- 4659, 2003. 8. MESSAOUDI C, SAYAH D, ABD-LEFDIL M. Transparent conducting and Indium-doped zinc oxide films prepared by spray pyrolysis. Phys. Stat. Sol. (a). 151: 93, 1995
- 9. MINAMI T, OOHASHI K, TAKATA S, MOURI T, OGAWA N. Preparations of ZnO:Al transparent conducting films by d.c. magnetron sputtering. Thin Solid Films. 193-194: 721-729, 1990.
- 10. NATSUME Y, SAKATA H. Zinc oxide films prepared by sol-gel spin-coating. Thin Solid Films. 372: 30- 36, 2000.
- 11. NUNES P, FERNANDES B, FORTUNATO E, VILARINHO P, MARTINS R. Performances presented by zinc oxide thin films deposited by spray pyrolysis. Thin Solid Films. 337: 176-179, 1999.
- 12. NUNES P, FORTUNATO E, MARTINS R. Influence of the annealing conditions on the properties of ZnO thin films. Thin Solid Films. 3: 1125-1128, 2001.
- 13. OHYA Y, SAIKI H, TAKAHASHI Y. Preparation of transparent, electrically conducting ZnO film from zinc acetate and alcoxide. Journal of Materials Science. 29: 4099-4103, 199
- 14. OKTIK S, RUSSELL GJ, BRINKMAN AW. Properties of ZnO layers deposited by “Photo-Assisted”. Journal of Crystal Growth. 159: 195-199, 1996.
- 15. PARAGUAY F, ESTRADA W L, ACOSTA NDR, ANDRADE E, MIKI-YOSHIDA M. Growth, structure and optical characterization of high quality ZnO thin films obtained by spray pyrolysis. Thin Solid Films. 350: 192-202 ,1999.
- 16. RIAD AS, MAHMOUD SA, IBRAHIM AA. Structural and DC electrical investigations of ZnO thin films prepared by spray pyrolysis technique. Physica B. 296: 319-325, 2001.
- 17. SANCHEZ-JUAREZ A, TIBURCIO-SILVER A, ORTIZ A. Properties of fluorine-doped ZnO deposited onto glass by spray pyrolysis. Solar Energy Materials and Solar Cells. 52: 301-311, 1998.
- 18. SHAN FK, YU YS. Band gap energy of pure and Al-doped ZnO thin films. Journal of The European Ceramic Society. 24: 1869-1872, 2004.
- 19. TIBURCIO-SILVER A, SANCHEZ-JUAREZ A, AVILA-GARCIA A. Properties of gallium-doped ZnO deposited onto glass by spray pyrolysis. Solar Energy Materials and Solar Cells. 55: 3-10, 1998.
- 20. TRAN NH, HARTMANN AJ, LAMB RN. Structural order of nanocrystalline ZnO films. J. Phys. Chem. B. 103: 4264-4268, 1999.
- 21. VAN HEERDEN JL, SWANEPOEL R, XRD analysis of ZnO thin films prepared by spray pyrolysis. Thin Solid Films. 299: 72-77, 1997.
- 22. WANG Y, WANG H, LIU S, LIU H, ZHOU S, HANG Y, XU J, YE J, GU S, ZHANG R. MOCVD growth and properties of ZnO thin films on LiNbO3 substrates Journal of Crystal Growth. 277: 378-381, 2005.
INFLUENCE OF SUBSTRATE TEMPERATURE ON STRUCTURAL AND ELECTRICAL PROPERTIES OF ZnO FILMS
Yıl 2006,
Cilt: 7 Sayı: 2, 153 - 159, 05.08.2016
Müjdat Çaglar
Saliha Ilıcan
Yasemin Çağlar
Öz
Zinc oxide (ZnO) films have been deposited by spray pyrolysis technique at different substrate temperatures. The effects of substrate temperature on the structural and electrical properties of ZnO films produced by this technique have been investigated. X-ray diffraction spectra of the films have shown that the films are polycrystalline and hexagonal wurtzite in structure. From these spectra, grain size and texture coefficient (TC) are calculated. The conductivity of ZnO films was determined from current-voltage characteristics measured at room temperature and in dark. The ohmic conduction mechanism was observed to take place in all the films.
Kaynakça
- 1. BACHARI EM, BAUD G, BEN AMOR S, JACQUET M. Structural and optical properties of sputtered ZnO films. Thin Solid Films. 348: 165-172, 1999.
- 2. BARRET CS, MASSALSKI TB. Structure of Metals, Pergamon Press, Oxford, 1980.
- 3. CULLITY BD. Elements of X-ray diffraction, 2nd ed., Addison Wesley, 1978.
- 4. ILICAN S, CAGLAR Y, CAGLAR M. X-Ray diffraction studies of undoped and In-doped Cd0.22Zn0.78S films deposited by spray pyrolysis. Çankaya University Journal of Arts and Sciences. 3: 85-94, 2005.
- 5. KOZUKA H, YOKO T, OHYAMA M. Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution. Thin Solid Films. 306: 78-85, 1997.
- 6. KRUNKS M, MELLIKOV E. Zinc oxide thin films by the spray pyrolysis method. Thin Solid Films. 270: 33- 36, 1995.
- 7. LI XH, HUANG AP, ZHU MK, XU SHL, CHEN J, WANG H, WANG B, YAN H. Influence of substrate temperature on the orientation and optical properties of sputtered ZnO films. Materials Letters. 57: 4655-
- 4659, 2003. 8. MESSAOUDI C, SAYAH D, ABD-LEFDIL M. Transparent conducting and Indium-doped zinc oxide films prepared by spray pyrolysis. Phys. Stat. Sol. (a). 151: 93, 1995
- 9. MINAMI T, OOHASHI K, TAKATA S, MOURI T, OGAWA N. Preparations of ZnO:Al transparent conducting films by d.c. magnetron sputtering. Thin Solid Films. 193-194: 721-729, 1990.
- 10. NATSUME Y, SAKATA H. Zinc oxide films prepared by sol-gel spin-coating. Thin Solid Films. 372: 30- 36, 2000.
- 11. NUNES P, FERNANDES B, FORTUNATO E, VILARINHO P, MARTINS R. Performances presented by zinc oxide thin films deposited by spray pyrolysis. Thin Solid Films. 337: 176-179, 1999.
- 12. NUNES P, FORTUNATO E, MARTINS R. Influence of the annealing conditions on the properties of ZnO thin films. Thin Solid Films. 3: 1125-1128, 2001.
- 13. OHYA Y, SAIKI H, TAKAHASHI Y. Preparation of transparent, electrically conducting ZnO film from zinc acetate and alcoxide. Journal of Materials Science. 29: 4099-4103, 199
- 14. OKTIK S, RUSSELL GJ, BRINKMAN AW. Properties of ZnO layers deposited by “Photo-Assisted”. Journal of Crystal Growth. 159: 195-199, 1996.
- 15. PARAGUAY F, ESTRADA W L, ACOSTA NDR, ANDRADE E, MIKI-YOSHIDA M. Growth, structure and optical characterization of high quality ZnO thin films obtained by spray pyrolysis. Thin Solid Films. 350: 192-202 ,1999.
- 16. RIAD AS, MAHMOUD SA, IBRAHIM AA. Structural and DC electrical investigations of ZnO thin films prepared by spray pyrolysis technique. Physica B. 296: 319-325, 2001.
- 17. SANCHEZ-JUAREZ A, TIBURCIO-SILVER A, ORTIZ A. Properties of fluorine-doped ZnO deposited onto glass by spray pyrolysis. Solar Energy Materials and Solar Cells. 52: 301-311, 1998.
- 18. SHAN FK, YU YS. Band gap energy of pure and Al-doped ZnO thin films. Journal of The European Ceramic Society. 24: 1869-1872, 2004.
- 19. TIBURCIO-SILVER A, SANCHEZ-JUAREZ A, AVILA-GARCIA A. Properties of gallium-doped ZnO deposited onto glass by spray pyrolysis. Solar Energy Materials and Solar Cells. 55: 3-10, 1998.
- 20. TRAN NH, HARTMANN AJ, LAMB RN. Structural order of nanocrystalline ZnO films. J. Phys. Chem. B. 103: 4264-4268, 1999.
- 21. VAN HEERDEN JL, SWANEPOEL R, XRD analysis of ZnO thin films prepared by spray pyrolysis. Thin Solid Films. 299: 72-77, 1997.
- 22. WANG Y, WANG H, LIU S, LIU H, ZHOU S, HANG Y, XU J, YE J, GU S, ZHANG R. MOCVD growth and properties of ZnO thin films on LiNbO3 substrates Journal of Crystal Growth. 277: 378-381, 2005.