Usability of calcite mineral, which develops in the crack fillings of carbonate rocks, as ornamental stone

Öz

Turkey has a significant amount of mineral content from a geological perspective, offering essential resources, especially in mining (ornamental stone production). In this study, methods are being developed for the extraction, processing, and usability of calcite minerals, which develop as vein fillings (secondary formations) among fragmented limestone along the Bayburt-Erzurum highway for ornamental stone use. The chemical and crystallographic properties of the mineral were determined through XRD and FTIR analyses, and its suitability for ornamental stone use was evaluated. (durable, clean, and transparent) epoxy was used as a binding material for ornamental stone production, and the use of calcite minerals in jewelry production was examined, revealing its potential economic value in terms of durability, aesthetics, and rarity. Generally, while calcite minerals are widely used in various industrial fields, their use as ornamental stones remains limited. This study presents a new perspective on evaluating calcite minerals as ornamental stones, demonstrating the possibility of processing a low-hardness mineral as an ornamental stone using binding materials and its potential economic value. These findings significantly evaluate natural minerals in different applications and enhance their financial potential.

Anahtar Kelimeler

• Geology
• Calcite
• Ornamental stone
• XRD analysis
• FTIR analysis

Kaynakça

1. Y. Eşme, Anadolu’da Bilinen Önemli Süstaşları Jeolojik ve Ekonomik Potansiyeli (Unpublished), Bornova, İzmir, 1994.
2. İ.K. Akbudak, Z. Başıbüyük, M. Gürbüz, Yozgat “Aydıncık” kalsedon-ametist oluşumlarının mineralojisi-petrografisi ve ekonomikliliğinin incelenmesi, DÜMF Mühendislik Dergisi 9(1), 2018, 313-324.
3. S. Ghorbani, S.H. Hoseinie, E. Ghasemi, T. Sherizadeh, A review on rock hardness testing methods and their applications in rock engineering, Arab J Geosci, 15 (11) (2022).
4. M. Camuzcuoğlu, Peridotitin Epoksi (Reçine) İçerisinde Renk Verici Pigment Olarak Kullanılabilirliği ve Süstaşı Yapımı, European Confereces 2nd International Conference on Health, Engineering and Applied Science, 4-6 August, Belgrade, 2023.
5. Mineral Research and Exploration (MTA), Türkiye, 2024, https://www.mta.gov.tr/v3.0/bilgi-merkezi/kalsit (Access; 18.05.2024).
6. Mineral Research and Exploration (MTA), Yerbilimleri, Türkiye, 2024 http://yerbilimleri.mta.gov.tr/anasayfa.aspx (Access; 27.04.2024).
7. T. Rızaoğlu, M. Camuzcuoğlu, Usability of Obsidian with Special Refraction as an Ornamental Stone by Bonding with Epoxy Resin, Systemy Wspomagania w Inżynierii Produkcji, 11(2), 2022, 96-103.
8. https://www.mta.gov.tr/v3.0/bilgi-merkezi/sustasi (Access; 12.05.2024).

9. C. Simonet, E. Fritsch, B. Lasnier, 2008). A classification of gem corundum deposits aimed towards gem exploration, Ore Geol Rev, 34 (1-2), 2008, 127-133.
10. W. Harris, W.G. Norman, X-ray diffraction techniques for soil mineral identification. In Methods of Soil Analysis Part 5-Mineralogical Methods, American Society of Agronomy and Soil Science Society of America, 2015, 81-115.
11. MinDAT 2024 https://www.mindat.org/min-859.html (Access; 07.06.2024).
12. D.S. Volkov, O.B. Rogova, M.A. Proskurnin, Organic Matter and Mineral Composition of Silicate Soils: FTIR Comparison Study by Photoacoustic, Diffuse Reflectance, and Attenuated Total Reflection Modalities, Agronomy, 11(9), 2021,1-30.
13. M. Fan, D. Dai, B. Huang, Fourier transform infrared spectroscopy for natural fibres. Fourier transform-materials analysis, 3, 2012, 45-68.
14. R. Bardestani, G.S. Patience, S. Kaliaguine, Experimental methods in chemical engineering: specific surface area and pore size distribution measurements-BET, BJH, and DFT, Can J Chem Eng, 97(11), 2019, 2781-2791.
15. D. Shan, S. Wang, H. Xue, S. Cosnier, Direct electrochemistry and electrocatalysis of hemoglobin entrapped in composite matrix based on chitosan and CaCO3 nanoparticles. Electrochem Commun, 9, (2007), 529-534.
16. S. Hajji, T. Turki, A. Boubakri, M. Ben Amor, N. Mzoughi, Study of cadmium adsorption onto calcite using full factorial experiment design, Desalin Water Treat, 83, (2017), 222-233.