The relationship between hydrothermal alteration and element accumulation in Sessile Oak (Quercus petraea L.): A case study from the Canca hydrothermal alteration zone (Gümüşhane, Türkiye)

Öz

The aim of this study is to investigate the element accumulation capability of oak trees, specifically focusing on their ability and characteristics to accumulate trace elements in the context of plants/trees in alteration zones. The Canca hydrothermal alteration zone (Gümüşhane, Türkiye) is located in Gümüşhane, one of Turkey's significant mining provinces, which hosts numerous mineralizations. The area has been subjected to intense hydrothermal alteration, making it particularly notable for signs of precious and base metal mineralization. Sessile oak (Quercus petraea L.) leaves were collected from the Canca hydrothermal alteration zone, and their analyses were conducted using MP-AES and ICP-MS. The trace element concentrations in the oak leaves were evaluated geostatistically, and the element distributions in the Canca area were examined using element distribution maps created by spatial geostatistical methods. When the findings were collectively evaluated, it was determined that the trace element contents in the oak leaves were generally higher than normal element contents, associated with the alteration in the area. Notably, a more significant enrichment of Mo, Cu, As, Zn, and Pb elements was found to be related to the alteration.

Anahtar Kelimeler

• Hydrothermal Alteration
• Biogeochemistry
• Exploration Geochemistry
• Trace Elements
• Element Accumulation

Destekleyen Kurum

Tübitak

Etik Beyan

Makalenin içeriği itibariyile etik izne ihtiyacı yoktur

Teşekkür

This research was supported by Scientific Research Projects of Tübitak under Grant Number: 113Y569.

Kaynakça

1. A. Vural, Investigation of the relationship between rare earth elements, trace elements, and major oxides in soil geochemistry, Environ. Monit. Assess., 192 (2020) 124. https://doi.org/10.1007/s10661-020-8069-9
2. A. Vural, Gold and Silver Content of Plant Helichrysum Arenarium, Popularly Known as the Golden Flower, Growing in Gümüşhane, NE Turkey, Acta Phys. Pol. A, 132 (2017) 978–980.
3. A. Vural, Canca (Gümüşhane) Alterasyon Sahasında Toprak ve Bitki Jeokimyası Çalışmaları ile Altın Potansiyelinin Araştırılması, Ankara, Türkiye, 2014.
4. A. Vural, Assessment of Sessile Oak (Quercus petraea L) Leaf as Bioindicator for Exploration Geochemistry, Acta Phys. Pol. A, 130 (2016) 191–193.
5. G. Kırat, N. Aydın, Pb-Zn Accumulation in Plants Grown in and Around a Pb-Zn Mine, Polish J. Environ. Stud., 24 (2015) 545–554.
6. G. Kirat, N. Aydin, Phytoremediation with plants for soils polluted by boron at Akdagmadeni Pb-Zn mining district and surroundings, Yozgat, Turkey, Gazi Univ. J. Sci., 29 (2016) 963–970.
7. G. Kirat, Investigation of the Biogeochemical Anomalies of Euphorbia cyparissias plant in Gümüshac  köy — Amasya Pb-Zn-Ag Deposits, Turkey, 13 (2020).
8. A. Vural, S. Kaya, N. Başaran, O.T. Songören, Anadolu Madenciliğinde İlk Adımlar, Maden Tetkik ve Arama Genel Müdürlüğü, MTA Kültür Serisi-3, Ankara, Türkiye, 2009.

9. A. Vural, A. Kaygusuz, Geochronology, petrogenesis and tectonic importance of Eocene I-type magmatism in the Eastern Pontides, NE Turkey, Arab. J. Geosci., 14 (2021) 467.
10. A. Vural, A. Kaygusuz, Petrographic and geochemical characteristics of late Cretaceous volcanic rocks in the vicinity of Avliyana (Gümüşhane, NE Turkey ), J. Eng. Res. Appl. Sci., 10 (2021) 1796–1810.
11. G. Topuz, R. Altherr, W. Siebel, W.H. Schwarz, T. Zack, A. Hasözbek, M. Barth, M. Satir, C. Şen, Carboniferous high-potassium I-type granitoid magmatism in the Eastern Pontides: The Gümüşhane pluton (NE Turkey), Lithos, 116 (2010) 92–110.
12. A. Kaygusuz, Geochronological age relationships of Carboniferous Plutons in the Eastern Pontides (NE Turkey), J. Eng. Res. Appl. Sci., 9 (2020) 1299–1307.
13. G. Topuz, R. Altherr, W.H. Schwarz, A. Dokuz, H.P. Meyer, Variscan amphibolite-facies rocks from the Kurtoǧlu metamorphic complex (Gümüşhane area, Eastern Pontides, Turkey), Int. J. Earth Sci., 96 (2007) 861–873.
14. M. Eren, Gümüşhane-Kale Arasının Jeolojisi ve Mikrofasiyes incelemesi, Karadeniz Teknik Üniversitesi, 1983.
15. S. Pelin, Alucra (Giresun) Güneydoğu Yöresinin Petrol Olanakları Bakımından Jeolojik İncelenmesi, Karadeniz Teknik Üniversitesi, 1977.
16. S. Tokel, Stratigraphical and volcanic history of Gümüşhane region, 1972.
17. A. Kaygusuz, W. Siebel, C. Şen, M. Satir, Petrochemistry and petrology of I-type granitoids in an arc setting: the composite Torul pluton, Eastern Pontides, NE Turkey, Int. J. Earth Sci., 97 (2008) 739–764.
18. A. Kaygusuz, Torul ve çevresinde yüzeylenen kayaçların petrografik ve jeokimyasal incelenmesi, Doktora Tezi, Karadeniz Teknik Üniversitesi, Trabzon, 227s, 2000.
19. Ç. Saydam Eker, Petrography and geochemistry of Eocene sandstones from eastern Pontides (NE TURKEY): Implications for source area weathering, provenance and tectonic setting, Geochemistry Int., 50 (2012) 683–701.
20. A. Kaygusuz, M. Öztürk, Geochronology, geochemistry, and petrogenesis of the Eocene Bayburt intrusions, Eastern Pontide, NE Turkey: implications for lithospheric mantle and lower crustal sources in the high-K calc-alkaline magmatism, J. Asian Earth Sci., 108 (2015) 97–116.
21. İ. Temizel, E. Abdioğlu Yazar, M. Arslan, A. Kaygusuz, Z. Aslan, Mineral chemistry, whole-rock geochemistry and petrology of Eocene I-type shoshonitic plutons in the Gölköy area (Ordu, NE Turkey), Bull. Miner. Res. Explor., 157 (2018) 121–152.
22. I. Temizel, M. Arslan, C. Yücel, E. Abdioğlu Yazar, A. Kaygusuz, Z. Aslan, Eocene tonalite–granodiorite from the Havza (Samsun) area, northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting, Int. Geol. Rev., 62 (2020) 1131–1158.
23. A. Kaygusuz, A. Arslan, W. Siebel, C. Şen, Geochemical and Sr-Nd Isotopic Characteristics of Post-Collisional Calc-Alkaline Volcanics in the Eastern Pontides (NE Turkey), Turkish J. Earth Sci., 20 (2011) 137–159.
24. A. Vural, Hidrotermal Alterasyona Bağlı Element Kirliliği : Canca (Gümüşhane - Türkiye), J. Investig. Eng. Technol., 5 (2022) 87–103.
25. A. Vural, G. Külekçi, Zenginleştirilmiş Jeoturizm Güzergahı:Gümüşhane-Bahçecik Köyü, Euroasia J. Math. Eng. Nat. Med. Sci., 8 (2021) 1–23.
26. B. Karayigit, N. Colak, F. Ozogul, A. Gundogdu, H. Inceer, N. Bilgiçli, F.A. Ayaz, The biogenic amine and mineral contents of different milling fractions of bread and durum wheat (Triticum L) cultivars, Food Biosci., 37 (2020) 100676.
27. A. Kurt, N. Colak, A. Bengu, A. Gundogdu, E. Akpinar, S. Hayirlioglu-Ayaz, F.A. Ayaz, A nutritional evaluation of the berry of a new grape: “Karaerik” (Vitis vinifera L), Int. J. Food Stud., 7 (2018) 98–116.
28. J.Y. Park, S.H. Jeon, J.N. Kim, H.T. Chon, A biogeochemical orientation study in Mo skarn deposits, Jecheon district in Korea, J. Geochemical Explor., 146 (2014) 9–16.
29. D.G. Krige, A stastical Approach to Some Basic Mine Valuation Problems on the Witwatersrand, J. Chem. Metall. Soc. South Min. Africa, 52 (1951) 119–139.
30. G. Matheron, Principles of geostatistics, Econ. Geol., 58 (1963) 1246–1266.
31. A. Vural, Assessment of Heavy Metal Accumulation in the Roadside Soil and Plants of Robinia pseudoacacia, in Gumushane, Northeastern Turkey, Ekoloji, 22 (2013) 1–10.
32. C. Anjos, C.M.F. Magalhaes, M.M. Abreu, Metal (Al, Mn, Pb and Zn) soils extractable reagents for available fraction assessment: Comparison using plants, and dry and moist soils from the Braçal abandoned lead mine area, Portugal, J. Geochemical Explor., 113 (2012) 45–55.
33. H. Turan, Z. Özdemir, S. Zorlu, Çiftehan (Ulukışla-Niğde) Bölgesinin Biyoeokimyasal Anomalilerinin Araştırılması, İstanbul Üniversitesi Mühendislik Fakültesi Yerbilim. Derg., 19 (2006) 131–140.