The investigation of the effect of sodium chlorite and phosphonic acid catalysts on cotton bleaching process conditions

Yıl 2023, Cilt: 5 Sayı: 1, 61 - 69, 30.06.2023

Salih Zeki Yıldız , Sami Dursun

https://doi.org/10.51435/turkjac.1296586

Öz

Today's environmental and living conditions necessitate reconsideration of traditional cotton fabric bleaching processes. For this reason, it is very important for the environment and the economy to obtain higher whiteness values by using less water and chemicals in bleaching. Sodium chlorite (NaClO2), the source of chlorine dioxide (ClO2) as the most important disinfectant, which gained popularity and availability during the COVID-19 pandemic, is an appropriate oxidant for the purpose. Using NaClO2 as bleaching agent has significant advantages, such as reducing the amount of washing proses and increasing of cotton strength. Another advantage of this reagent is that it causes less fabric weight loss than other reagents. Therefore, the present work was intended to improve the process conditions (different temperatures, concentrations, and times) of bleaching of cotton fabric by using NaClO2. Optimum temperature and time were determined as 30 min at 65 °C and 30 min at 85 °C, and a high whiteness index (W.I.=88) was obtained by using phosphonic acid (HEDP). Moreover, the tensile strength, weight loss and morphologies of the samples were examined. It has been observed that sodium chlorite causes little damage to cotton fibers and requires less water for rinsing since it does not form alkaline residues.

Anahtar Kelimeler

Chlorine dioxide, cotton bleach, whitening grade, HEDP

Teşekkür

The authors extend their appreciation to the TUROKSI Chemical Co. Ltd. for providing the cotton fabric and some chemicals.

Kaynakça

• [1] E.S. Abdel-Halim, Simple and economic bleaching process for cotton fabric, Carbohydr Polym, 88, 2012 1233–8.
• [2] H. Liu, C. Wang, and G. Wang, Photocatalytic advanced oxidation processes for water treatment: recent advances and perspective, Chem-Asian J, 15, 2020, 3239–3253.
• [3] G.K. Günaydin, O. Avinc, S. Palamutcu, A. Yavas, A.S. Soydan, Naturally colored organic cotton and naturally colored cotton fiber production, Organic cotton, Springer, 2019, 81–99.
• [4] A.K. Samanta, A. Konar, Dyeing of textiles with natural dyes, Nat dyes, 2011, 30–56.
• [5] A. Davulcu, H. Benli, Y. Şen, M.I. Bahtiyari, Dyeing of cotton with thyme and pomegranate peel, Cellulose, 21, 2014, 4671–4680.
• [6] A. Nadi, A. Boukhriss, A. Bentis, E. Jabrane, S. Gmouh, Evolution in the surface modification of textiles: a review, Text Prog, 50, 2018, 67–108.
• [7] A. Haji, M. Naebe, Cleaner dyeing of textiles using plasma treatment and natural dyes: A review, J Clean Prod, 265, 2020, 121866.
• [8] T. Adane, A. T. Adugna, E. Alemayehu, Textile industry effluent treatment techniques, J Chem, 2021,1–14.
• [9] N. J. Lant, A. S. Hayward, M. M. Peththawadu, K. J. Sheridan, J. R. Dean, Microfiber release from real soiled consumer laundry and the impact of fabric care products and washing conditions, PloS one, 15, 2020, 1–18.
• [10] C.A.H. Aguilar, J. Narayanan, N. Singh, P. Thangarasu, Kinetics and mechanism for the oxidation of anilines by ClO2: a combined experimental and computational study, J Phys Org Chem, 27, 2014, 440–449.
• [11] A. Ivanovska, L. Pavun, B. Dojčinović, M. Kostić, Kinetic and isotherm studies for the biosorption of nickel ions by jute fabrics, J Serb Chem Soc, 86, 2021, 885–897.
• [12] S. Xu, D. Huo, K. Wang, Q. Yang, Q. Hou, F. Zhang, Facile preparation of cellulose nanofibrils (CNFs) with a high yield and excellent dispersibility via succinic acid hydrolysis and NaClO2 oxidation, Carbohydr Polym, 266, 2021, 118118.
• [13] M. Beroual, L. Boumaza, O. Mehelli, D. Trache, A. F. Tarchoun, K. Khimeche, Physicochemical properties and thermal stability of microcrystalline cellulose isolated from esparto grass using different delignification approaches, J Polym Environ, 29, 2021, 130–42.
• [14] C.A. Hubbell, A. J. Ragauskas, Effect of acid-chlorite delignification on cellulose degree of polymerization, Bioresour Technol, 101, 2010, 7410–7415.
• [15] G.D. Callachan, Novel methods for the removal of chlorine dioxide gas from aqueous solution and sodium chlorite production, Master's Thesis, Heriot Watt University, School of Engineering and Physical Sciences, 2019.
• [16] M. Hirota, N. Tamura, T. Saito, A. Isogai, Oxidation of regenerated cellulose with NaClO2 catalyzed by TEMPO and NaClO under acid-neutral conditions, Carbohydr Polym, 78, 2009, 330–335.
• [17] W. Ye, Y. Hu, H. Ma, L. Liu, J. Yu, Y. Fan, Comparison of cast films and hydrogels based on chitin nanofibers prepared using TEMPO/NaBr/NaClO and TEMPO/NaClO/NaClO2 systems, Carbohydr Polym, 237, 2020, 116125.
• [18] T.L. Chen, Y.H. Chen, Y.L. Zhao, P.C. Chiang, Application of gaseous ClO2 on disinfection and air pollution control: A mini review, Aerol Air Qual Res, 20, 2020, 2289–2298.
• [19] I.C. Eduardo, B.G. Blanca, A. Yohanny, C. Patricia, S.A. Maria, A.B.A. San Martín, C.O. Gonzales, Determination of the Effectiveness of Chlorine Dioxide in the Treatment of COVID 19, Mol Genet Genomic Med, 2021, 1–11.
• [20] B. A. Annous, D. A. Buckley, D. H. Kingsley, Efficacy of chlorine dioxide gas against hepatitis A virus on blueberries, blackberries, raspberries, and strawberries, Food Environ Virol, 13, 2021, 241–247.
• [21] D. ASTM, E313-73: Standard Test Method for Indices of Whiteness and Yellowness of Near-White, Opaque Mater, 1993.
• [22] H. Fahmy, Enhancing some performance properties of ester crosslinked cotton fabric by pre-quaternization, Egypt J Chem, 47, 2004, 627–640.
• [23] S. R. Karmakar, Chemical technology in the pre-treatment processes of textiles: Elsevier, 1999.
• [24] C. A. Hubbell, A. J. Ragauskas, Effect of acid-chlorite delignification on cellulose degree of polymerization, Bioresource technol, 101,2010, 7410–7415.
• [25] A. Kozioł, K. Środa-Pomianek, A. Górniak, A. Wikiera, K. Cyprych, M. Malik, Structural determination of pectins by spectroscopy methods, Coatings, 12, 2022, 546.
• [26] J. Sun, F. Xu, X. Sun, B. Xiao, R. Sun, Physico-chemical and thermal characterization of cellulose from barley straw, Polym Degrad Stab, 88, 2005, 521–531.
• [27] Z. Yang, S. Xu, X. Ma, S. Wang, Characterization and acetylation behavior of bamboo pulp, Wood Sci Technol, 42, 2008, 621–632.
• [28] V. Sangeetha, T. Varghese, S. K. Nayak, Isolation and characterisation of nanofibrillated cellulose from waste cotton: effects on thermo-mechanical properties of polylactic acid/MA-g-SEBS blends, Iran Polym J, 28, 2019, 673–683.
• [29] M. Joonobi, J. Harun, P. M. Tahir, L. H. Zaini, S. SaifulAzry, M. D. Makinejad, Characteristic of nanofibers extracted from kenaf core, BioResour, 5, 2010, 2556–2566.
• [30] S. Yang, X. Pan, Z. Han, D. Zheng, J. Yu, P. Xia, B. Liu, Z. Yan, Nitrogen oxide removal from simulated flue gas by UV-irradiated sodium chlorite solution in a bench-scale scrubbing reactor, Ind Eng Chem Res, 56, 2017, 3671–3678.
• [31] R. Hao, X. Wang, Y. Liang, Y. Lu, Y. Cai, X. Mao, B. Yuan, Y. Zhao, Reactivity of NaClO2 and HA-Na in air pollutants removal: active species identification and cooperative effect revelation, J Chem Eng, 330, 2017, 1279–1288.
• [32] P. Gong, X. Li, Promoting effect of H+ and other factors on NO removal by using acidic NaClO2 solution, Energies, 12, 2019, 2966.
• [33] T. L. Vigo, Textile processing and properties: Preparation, dyeing, finishing and performance: Elsevier, 2013.