Yanma ürünü olan is (siyah karbon) parçacıkları topaklanarak atmosfere
yayılırlar. Kanserojene yol açan (PAH) molekül içermeleri nedeniyle
toksikolojik etkilere sahiptirler ve ışınım özelliklerinin artması nedeniyle
global ısınmaya güçlü etkilerinin olduğu bilinmektedir. Bu çalışmada, siyah
karbon topaklanmalarının ışınım özelliklerine topaklanma yapısının ve
büyüklüğünün etkileri, Discrete Dipole Approximation (DDA) yöntemi ile analiz
edilmiştir. N = 200 parçacıktan
oluşan iki ayrı yapıdaki topaklanma örneği 0.532 ve 1.064 μm dalga boylarında
ışınım saçılımı açısından incelenmiştir. Her iki topaklanma yapısı, üç farklı
yapısal durumda yani parçacıklar nokta temaslı, iç içe geçmiş ve topaklanmanın
hacimsel büyütülmüş durumları için topaklanmaların ışınım özellikleri
hesaplanmıştır. Yapılan analizlerden, is topaklanmalarının ışınım
özelliklerinin topaklanma hacim eşdeğer yarıçapları ve incelenen dalga boyundan
oldukça etkilendiği görülmüştür. Parçacık temaslı topaklanma genişlemesi ile
parçacıkları iç içe geçen topaklanmaların ışınım özelliklerinin aynı değerlere
sahip olduğu saptanmıştır.
Adachi, K., Chung, S. H., Buseck, P. R. (2010), Shapes of Soot Aerosols Particles and Implications for Their Effects on Climate. J. Geophys. Res., 115, D15206. http://dx.doi:10.1029/2009JD012868
Al Zaitone, B., Schmid, H-J., Peukert, W. (2009), Simulation of structure and mobility of aggregates formed by simultaneous coagulation, sintering and surface growth, Aerosol Sci, 40, 950-964. http://dx.doi:10.1016/j.jaerosci.2009.08.007
Ayrancı, I., Vaillon, R., Selçuk, N. (2007), Performance of discrete dipole approximation for prediction of amplitude and phase of electromagnetic scattering by particles, J. Quant Spectrosc Radiat Transf, 103, 83–101. http://doi.org/10.1016/j.jqsrt.2006.06.006
Bescond, A., Yon, J., Girasole, T., Jouen, C., Rozé, C., Coppalle, A. (2013), Numerical investigation of the possibility to determine the primary particle size of fractal aggregates by measuring light depolarization, J Quant Spectrosc Radiat Transfer, 126, 130–139. http://dx.doi.org/10.1016/j.jqsrt.2012.10.011
Brasil, A.M., Farias, T.L., Carvalho, M.G. (1999), A recipe for image characterization of fractal-like aggregates, J. Aerosol Sci., Vol. 30 No. 10, 1379-1389. http://dx.doi.org/10.1016/S0021-8502(99)00026-9
Dalzell, W.H., Sarofim, A.F., Optical constants of previous termsootnext term and their application to heat-flux calculations, J. Heat Transfer, (1969), 91, 100-4.
Di Stasio, S. (2002), Experiments on depolarized optical scattering to sense in situ the onset of early agglomeration between nano-size particles, J Quant Spectrosc Radiat Transfer, 126, 423–432. http://dx.doi.org/10.1016/S0022-4073(01)00224-2
Dobbins, R.A. ve Megaridis, C. M. (1991), Absorption and scattering of light by polydisperse aggregates, Applied Optics, Vol. 30 (33), 4747-4754. https://doi.org/10.1364/AO.30.004747
Draine, B.T. ve Goodman, J. (1993), Beyond Clausius –Mossotti-Wave Propagation on a Polarizable Point Lattice and the Discrete Dipole Approximation, Astrophys., J., 405, 685-697. http:// http://adsabs.harvard.edu/full/1993apj...405..685d
Draine, B.T., Flatau, P.J. (1994), Discrete-dipole approximation for scattering calculations, J. Opt. Soc. Am., 11, 1491-1499. https://doi.org/10.1364/JOSAA.11.001491
Draine, B.T., Flatau, P.J. (2014), User Guide to the Discrete Dipole Approximation Code DDSCAT 7.3. http://arXiv:1305.6497
Eggersdorfer, M.L., Pratsinis, S.E. (2013), Restructuring of Aggregates and Their Primary Particle Size Distribution During Sintering, AIChE Journal, Vol.59, No. 4, 1118-1126. http://dx.doi:10.1002/aic
Francis, M., Renard, J.-B., Hadamcik, E., Coute, B., Gaubicher, B., Jeanot, M. (2011), New-studies on scattering properties of different kinds of soot and carbon-black, J Quant Spectrosc Radiat Transfer, 112, 1766–1775. http://dx.doi:10.1016/j.jqsrt.2011.01.009
Kahnert, M. (2010), On the Discrepancy between Modeled and Measured Mass Absorption Cross Sections of Light Absorbing Carbon Aerosols, Aerosol Sci Technol, 44, 453-460. http://dx.doi.org/10.1080/02786821003733834
Kandilian, R., Heng, R. L., ve Pilon, L. (2015). Absorption and Scattering by Fractal Aggregates and by their Equivalent Coated Spheres. J. Quant. Spectrosc. Radiat. Transfer, 151, 310–326. http://dx.doi.org/10.1016/j.jqsrt.2014.10.018
Li, S., Cheng, X., Mei, P., Lu, S., Yang, H., Zhang, H. (2014), Multiple scattering of light transmission in a smoke layer, Optik, 125, 2185–2190. http://dx.doi.org/10.1016/j.ijleo.2013.10.040
Litton, C. D. ve Perera, I. E. (2014), Modeling the optical properties of combustion-generated fractal aggregates, Fuel, 130, 215–220. http://dx.doi.org/10.1016/j.fuel.2014.04.043
Liu, F. ve Smallwood, G. J. (2010), Effect of aggregation on the absorption cross-section of the fractal soot aggregates and its impact on LII modelling, J Quant Spectrosc Radiat Transfer, 111, 302–308. http://dx.doi:10.1016/j.jqsrt.2009.06.017
Liu, F. ve Snelling, D. R. (2008), Evaluation of the Accuracy the RDG Approximation for the Absorption and Scattering Properties of Fractal Aggregates of Flame-Generated Soot, 40th Thermophysics Conference, 23-26 June, Seattle, Washington, USA. http://dx.doi.org/10.2514/6.2008-4362
Liu, L. ve Mishchenko, M. I. (2005) Effects of aggregation on scattering and radiative properties of soot aerosols, Journal of Geophysical Research, Vol. 110, 262–273. http://dx.doi:10.1029/2004JD005649
Liu, L. ve Mishchenko, M. I. (2007) Scattering and radiative properties of complex soot and soot-containing aggregate particles, J Quant Spectrosc Radiat Transfer, 106, 262–273. http://dx.doi:10.1016/j.jqsrt.2007.01.020
Liu, L., ve Mishchenko, M. I., Arnott W. P. (2008), A study of radiative properties of fractal soot aggregates using the superposition T-Matrix method, J Quant Spectrosc Radiat Transfer, 109, 2656–2663. http://dx.doi:10.1016/j.jqsrt.2008.05.001
Lu, N. ve Sorensen, C.M. (1994), Depolarized light scattering from fractal soot aggregates, Phys Rev E, 50 (4), 3109-3115. https://doi.org/10.1103/PhysRevE.50.3109
Oh, C. ve Sorensen, C.M. (1997), The effect of overlap between monomers on the determination of the fractal cluster morphology, J Colloid Interface Sci., 193 (1), 17-25. http://dx.doi.org/10.1006/jcis.1997.5046
Olofsson, N.-E. (2014), Laser-Induced Incandescense and Complementary Diagnostics for Flame soot characterization, Doctoral Dissertation, Lund University, İsveç. https://lup.lub.lu.se/search/publication/4864518
Prasanna, S., Rivière, Ph., Soufiani A. (2014), Effect of fractal parameters on absorption properties of soot in the infrared region, J Quant Spectrosc Radiat Transfer, 148, 141–155. http://dx.doi.org/10.1016/j.jqsrt.2014.07.004
Scarnato, B.V., Vahidinia, S., Richard D.T., Kirchstetter T.W. (2013), Effects of internal mixing and aggregate morphology on optical properties of black carbon using a discrete dipole approximation model, Atmos. Chem. Phys., 13, 5089-5101. http://dx.doi:10.5194/acp-13-5089-2013
Schmid, H.-J., Tejwani, S., Artelt, C., Peukert, W. (2004), Monte Carlo simulation of aggregate morphology for simultaneous coagulation and sintering, Journal of Nanoparticle Research, 6: 613-626. http://dx.doi:10.1007/s11051-004-2161-x
Shen, Y., Draine, B.T. ve Johnson, E. T. (2008), Modeling Porous Grains with Ballistic Aggregates. I. Geometry and Optical Properties, Astrophys., J., 689, 260-275. http://dx.doi:10.1086/592765
Soewono, A. ve Rogak, S. N. (2013), Morphology and Optical Properties of Numerically Simulated Soot Aggregates, Aerosol Sci Technol, 47, 267–274, http://dx.doi.org/10.1080/02786826.2012.749972
Van-Hulle, P., Weill, M.-E., Talbaut, M., Coppalle, A. (2002), Comparison of Numerical Studies Characterizing Optical Properties of Soot Aggregates for Improved EXSCA Measurements, Part. Part. Syst. Charact., 19, 47-57. http://dx.doi:10.1002/1521-4117(200204)19:1<47::AID-PPSC47>3.0.CO;2-W
Yon, J., Bescond, A., Liu, F. (2015), On the radiative properties of soot aggregates part 1: Necking and overlapping, J Quant Spectrosc Radiat Transfer, 162, 197–206. http://dx.doi.org/10.1016/j.jqsrt.2015.03.027
Yon, J., Liu, F., Bescond, A., Caumont-Prim, C., Rozé, C., Ouf, F.-X., Coppalle, A. (2014), Effects of multiple scattering on radiative properties of soot fractal aggregates, J Quant Spectrosc Radiat Transfer, 133, 374–381. http://dx.doi.org/10.1016/j.jqsrt.2013.08.022
Doner, N., ve Liu, F. (2017), Impact of morphology on the radiative properties of fractal soot aggregates, J Quant Spectrosc Radiat Transfer, 187, 10–19. http://dx.doi.org/10.1016/j.jqsrt.2016.09.005
Effects of Morphology on the Radiative Properties of Fractal Soot Aggregates
The soot (black carbon) particles which are
produced by combustion emits into atmosphere in forms of aggregates. The
aggregates contain of PAH molecules that are causing carcinogens have
toxicological effects. It is well known that soot aggregates which are enlarged
of radiative properties effect on global warming. In this study, the impact of
morphology on the radiative properties of fractal soot aggregates was
investigated using the discrete dipole approximation (DDA). The radiative
properties of aggregates of N = 200
primary particles were numerically evaluated at 0.532 and 1.064 μm wavelength.
The radiative properties of three different cases, formed by point-touching,
overlapping and aggregate expansion for soot aggregates were calculated. The effects
of radiative properties of soot aggregates vary strongly with the volume
equivalent radius aeff and
wavelength. It was found that the expansion of aggregates has the same effect
on radiative properties as overlapping.
Adachi, K., Chung, S. H., Buseck, P. R. (2010), Shapes of Soot Aerosols Particles and Implications for Their Effects on Climate. J. Geophys. Res., 115, D15206. http://dx.doi:10.1029/2009JD012868
Al Zaitone, B., Schmid, H-J., Peukert, W. (2009), Simulation of structure and mobility of aggregates formed by simultaneous coagulation, sintering and surface growth, Aerosol Sci, 40, 950-964. http://dx.doi:10.1016/j.jaerosci.2009.08.007
Ayrancı, I., Vaillon, R., Selçuk, N. (2007), Performance of discrete dipole approximation for prediction of amplitude and phase of electromagnetic scattering by particles, J. Quant Spectrosc Radiat Transf, 103, 83–101. http://doi.org/10.1016/j.jqsrt.2006.06.006
Bescond, A., Yon, J., Girasole, T., Jouen, C., Rozé, C., Coppalle, A. (2013), Numerical investigation of the possibility to determine the primary particle size of fractal aggregates by measuring light depolarization, J Quant Spectrosc Radiat Transfer, 126, 130–139. http://dx.doi.org/10.1016/j.jqsrt.2012.10.011
Brasil, A.M., Farias, T.L., Carvalho, M.G. (1999), A recipe for image characterization of fractal-like aggregates, J. Aerosol Sci., Vol. 30 No. 10, 1379-1389. http://dx.doi.org/10.1016/S0021-8502(99)00026-9
Dalzell, W.H., Sarofim, A.F., Optical constants of previous termsootnext term and their application to heat-flux calculations, J. Heat Transfer, (1969), 91, 100-4.
Di Stasio, S. (2002), Experiments on depolarized optical scattering to sense in situ the onset of early agglomeration between nano-size particles, J Quant Spectrosc Radiat Transfer, 126, 423–432. http://dx.doi.org/10.1016/S0022-4073(01)00224-2
Dobbins, R.A. ve Megaridis, C. M. (1991), Absorption and scattering of light by polydisperse aggregates, Applied Optics, Vol. 30 (33), 4747-4754. https://doi.org/10.1364/AO.30.004747
Draine, B.T. ve Goodman, J. (1993), Beyond Clausius –Mossotti-Wave Propagation on a Polarizable Point Lattice and the Discrete Dipole Approximation, Astrophys., J., 405, 685-697. http:// http://adsabs.harvard.edu/full/1993apj...405..685d
Draine, B.T., Flatau, P.J. (1994), Discrete-dipole approximation for scattering calculations, J. Opt. Soc. Am., 11, 1491-1499. https://doi.org/10.1364/JOSAA.11.001491
Draine, B.T., Flatau, P.J. (2014), User Guide to the Discrete Dipole Approximation Code DDSCAT 7.3. http://arXiv:1305.6497
Eggersdorfer, M.L., Pratsinis, S.E. (2013), Restructuring of Aggregates and Their Primary Particle Size Distribution During Sintering, AIChE Journal, Vol.59, No. 4, 1118-1126. http://dx.doi:10.1002/aic
Francis, M., Renard, J.-B., Hadamcik, E., Coute, B., Gaubicher, B., Jeanot, M. (2011), New-studies on scattering properties of different kinds of soot and carbon-black, J Quant Spectrosc Radiat Transfer, 112, 1766–1775. http://dx.doi:10.1016/j.jqsrt.2011.01.009
Kahnert, M. (2010), On the Discrepancy between Modeled and Measured Mass Absorption Cross Sections of Light Absorbing Carbon Aerosols, Aerosol Sci Technol, 44, 453-460. http://dx.doi.org/10.1080/02786821003733834
Kandilian, R., Heng, R. L., ve Pilon, L. (2015). Absorption and Scattering by Fractal Aggregates and by their Equivalent Coated Spheres. J. Quant. Spectrosc. Radiat. Transfer, 151, 310–326. http://dx.doi.org/10.1016/j.jqsrt.2014.10.018
Li, S., Cheng, X., Mei, P., Lu, S., Yang, H., Zhang, H. (2014), Multiple scattering of light transmission in a smoke layer, Optik, 125, 2185–2190. http://dx.doi.org/10.1016/j.ijleo.2013.10.040
Litton, C. D. ve Perera, I. E. (2014), Modeling the optical properties of combustion-generated fractal aggregates, Fuel, 130, 215–220. http://dx.doi.org/10.1016/j.fuel.2014.04.043
Liu, F. ve Smallwood, G. J. (2010), Effect of aggregation on the absorption cross-section of the fractal soot aggregates and its impact on LII modelling, J Quant Spectrosc Radiat Transfer, 111, 302–308. http://dx.doi:10.1016/j.jqsrt.2009.06.017
Liu, F. ve Snelling, D. R. (2008), Evaluation of the Accuracy the RDG Approximation for the Absorption and Scattering Properties of Fractal Aggregates of Flame-Generated Soot, 40th Thermophysics Conference, 23-26 June, Seattle, Washington, USA. http://dx.doi.org/10.2514/6.2008-4362
Liu, L. ve Mishchenko, M. I. (2005) Effects of aggregation on scattering and radiative properties of soot aerosols, Journal of Geophysical Research, Vol. 110, 262–273. http://dx.doi:10.1029/2004JD005649
Liu, L. ve Mishchenko, M. I. (2007) Scattering and radiative properties of complex soot and soot-containing aggregate particles, J Quant Spectrosc Radiat Transfer, 106, 262–273. http://dx.doi:10.1016/j.jqsrt.2007.01.020
Liu, L., ve Mishchenko, M. I., Arnott W. P. (2008), A study of radiative properties of fractal soot aggregates using the superposition T-Matrix method, J Quant Spectrosc Radiat Transfer, 109, 2656–2663. http://dx.doi:10.1016/j.jqsrt.2008.05.001
Lu, N. ve Sorensen, C.M. (1994), Depolarized light scattering from fractal soot aggregates, Phys Rev E, 50 (4), 3109-3115. https://doi.org/10.1103/PhysRevE.50.3109
Oh, C. ve Sorensen, C.M. (1997), The effect of overlap between monomers on the determination of the fractal cluster morphology, J Colloid Interface Sci., 193 (1), 17-25. http://dx.doi.org/10.1006/jcis.1997.5046
Olofsson, N.-E. (2014), Laser-Induced Incandescense and Complementary Diagnostics for Flame soot characterization, Doctoral Dissertation, Lund University, İsveç. https://lup.lub.lu.se/search/publication/4864518
Prasanna, S., Rivière, Ph., Soufiani A. (2014), Effect of fractal parameters on absorption properties of soot in the infrared region, J Quant Spectrosc Radiat Transfer, 148, 141–155. http://dx.doi.org/10.1016/j.jqsrt.2014.07.004
Scarnato, B.V., Vahidinia, S., Richard D.T., Kirchstetter T.W. (2013), Effects of internal mixing and aggregate morphology on optical properties of black carbon using a discrete dipole approximation model, Atmos. Chem. Phys., 13, 5089-5101. http://dx.doi:10.5194/acp-13-5089-2013
Schmid, H.-J., Tejwani, S., Artelt, C., Peukert, W. (2004), Monte Carlo simulation of aggregate morphology for simultaneous coagulation and sintering, Journal of Nanoparticle Research, 6: 613-626. http://dx.doi:10.1007/s11051-004-2161-x
Shen, Y., Draine, B.T. ve Johnson, E. T. (2008), Modeling Porous Grains with Ballistic Aggregates. I. Geometry and Optical Properties, Astrophys., J., 689, 260-275. http://dx.doi:10.1086/592765
Soewono, A. ve Rogak, S. N. (2013), Morphology and Optical Properties of Numerically Simulated Soot Aggregates, Aerosol Sci Technol, 47, 267–274, http://dx.doi.org/10.1080/02786826.2012.749972
Van-Hulle, P., Weill, M.-E., Talbaut, M., Coppalle, A. (2002), Comparison of Numerical Studies Characterizing Optical Properties of Soot Aggregates for Improved EXSCA Measurements, Part. Part. Syst. Charact., 19, 47-57. http://dx.doi:10.1002/1521-4117(200204)19:1<47::AID-PPSC47>3.0.CO;2-W
Yon, J., Bescond, A., Liu, F. (2015), On the radiative properties of soot aggregates part 1: Necking and overlapping, J Quant Spectrosc Radiat Transfer, 162, 197–206. http://dx.doi.org/10.1016/j.jqsrt.2015.03.027
Yon, J., Liu, F., Bescond, A., Caumont-Prim, C., Rozé, C., Ouf, F.-X., Coppalle, A. (2014), Effects of multiple scattering on radiative properties of soot fractal aggregates, J Quant Spectrosc Radiat Transfer, 133, 374–381. http://dx.doi.org/10.1016/j.jqsrt.2013.08.022
Doner, N., ve Liu, F. (2017), Impact of morphology on the radiative properties of fractal soot aggregates, J Quant Spectrosc Radiat Transfer, 187, 10–19. http://dx.doi.org/10.1016/j.jqsrt.2016.09.005
Döner, N. (2017). İS (SİYAH KARBON) TOPAKLANMALARINDA YAPISAL DURUMLARIN IŞINIM ÖZELLİKLERİNE ETKİLERİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 22(1), 125-138. https://doi.org/10.17482/uumfd.309456
AMA
Döner N. İS (SİYAH KARBON) TOPAKLANMALARINDA YAPISAL DURUMLARIN IŞINIM ÖZELLİKLERİNE ETKİLERİ. UUJFE. Nisan 2017;22(1):125-138. doi:10.17482/uumfd.309456
Chicago
Döner, Nimeti. “İS (SİYAH KARBON) TOPAKLANMALARINDA YAPISAL DURUMLARIN IŞINIM ÖZELLİKLERİNE ETKİLERİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 22, sy. 1 (Nisan 2017): 125-38. https://doi.org/10.17482/uumfd.309456.
EndNote
Döner N (01 Nisan 2017) İS (SİYAH KARBON) TOPAKLANMALARINDA YAPISAL DURUMLARIN IŞINIM ÖZELLİKLERİNE ETKİLERİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 22 1 125–138.
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