Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry

Dilges Baskin

doi:10.53433/yyufbed.1718800

TR EN

Alevli Atomik Absorpsiyon Spektrometresi ile Atık Su Matrisinde Kobalt(II) Tayini için Hiyerarşik MnSb₂O₆ Parçacıklarının Dağılımlı Katı Faz Ekstraksiyonunda Kullanımı

Öz

Bu çalışmada, hiyerarşik yapılı MnSb₂O₆ manyetik çiçek-şekilli parçacıkların (MFSP) alevli atomik absorpsiyon spektrometresi (AAAS) ile metal iyonlarının tayininde adsorban olarak etkinliği, dağılımlı katı faz ekstraksiyonu (DKFE) yöntemi kapsamında değerlendirilmiştir. pH, adsorban miktarı, karıştırma türü ve süresi, elüent tipi ve hacmi ile adsorban türü (manyetik ve manyetik olmayan) gibi parametreler optimize edilerek DKFE–AAAS performansı iyileştirilmiştir. MFSP–DKFE–AAAS yöntemi, Co²⁺ iyonları için 5.0–100 ng mL⁻¹ aralığında dinamik bir doğrusal çalışma aralığı sunmuş ve korelasyon katsayısı 0.9996 olarak elde edilmiştir. Ayrıca, manyetik adsorban kullanılan yöntem doğrudan AAAS’a kıyasla 86 kat daha yüksek duyarlılık göstermiştir. Van Su ve Kanalizasyon İdaresi’nden (VASKİ) temin edilen atık su (evsel atıksu) örneği ile yapılan geri kazanım çalışmasında %94–108 aralığında başarılı sonuçlar elde edilmiştir. Bu çalışma, ilk kez manyetik MnSb₂O₆ ve manyetik olmayan SbO₂ çiçek şeklindeki parçacıkların birlikte kullanımını, manyetik özelliklerin DSPE performansındaki rolünü ortaya koymak ve gerçek atıksu analizlerinde uygulanabilirliğini doğrulamak için rapor etmektedir. Geliştirilen yöntem, çevresel matrislerin analizinde karşılaşılan zorlukları aşmada etkili olmuş ve manyetik özelliklerin metal iyonlarının seçici ve verimli adsorpsiyonundaki belirleyici rolünü ortaya koymuştur.

Anahtar Kelimeler

Alevli atomik absorpsiyon spektrometrisi, Çevresel analiz, Dağılımlı katı faz ekstraksiyonu, Kobalt tayini

Proje Numarası

FHD-2024-11276

Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry

Öz

The efficacy of hierarchical MnSb₂O₆ magnetic flower-shaped particles (MFSP) as adsorbents for the determination of metal ions using flame atomic absorption spectrometry (FAAS) was evaluated through dispersive solid-phase extraction (DSPE) in this study. Key parameters, including pH, sorbent amount, mixing type and duration, eluent type and volume, and sorbent type (magnetic and non-magnetic) were optimized to improve DSPE–FAAS performance. The MFSP–DSPE–FAAS method demonstrated a dynamic linear range of 5.0–100 ng mL⁻¹ for Co²⁺ ions with a correlation coefficient of 0.9996. Moreover, the magnetic sorbent–DSPE–FAAS method exhibited an 86-fold increase in sensitivity for Co²⁺ compared to FAAS alone, underscoring the significant contribution of the hierarchical magnetic flower-shaped particles in achieving selective and efficient adsorption. A recovery study using a wastewater (domestic effluent) sample from the General Directorate of VASKİ (Van Water and Sewerage Administration) yielded recoveries between 94% and 108%. This study highlights, for the first time, the combined use of magnetic MnSb₂O₆ and non-magnetic SbO₂ flower-shaped particles to reveal the role of magnetic properties in DSPE performance and to validate their applicability in real wastewater analysis. The developed method not only addressed the challenges posed by complex environmental matrices but also demonstrated the crucial role of magnetic properties in facilitating efficient metal ion adsorption.

Anahtar Kelimeler

Cobalt determination, Dispersive solid-phase extraction, Environmental analysis, Flame atomic absorption spectrometry

Destekleyen Kurum

This study was supported by Van Yüzüncü Yıl University Scientific Research Projects Coordination Unit under the project number FHD-2024-11276.

Proje Numarası

FHD-2024-11276

Etik Beyan

The author declares that the research and publication ethics were fully observed throughout the study.

Teşekkür

The authors gratefully acknowledge the support provided by the Van Yüzüncü Yıl University Science Research and Application Centre (https://www.yyu.edu.tr/images/files/Lab_Catalogue_Final.pdf) for material characterization analyses.

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Analitik Spektrometri, Analitik Kimya (Diğer)

Bölüm

Araştırma Makalesi

Yazarlar

Dilges Baskin ^*
0000-0001-7099-3763
Türkiye

Yayımlanma Tarihi

24 Aralık 2025

Gönderilme Tarihi

13 Haziran 2025

Kabul Tarihi

29 Ekim 2025

Yayımlandığı Sayı

Yıl 2025 Cilt: 30 Sayı: 3

DOI

https://doi.org/10.53433/yyufbed.1718800

IZ

https://izlik.org/JA76WR68NT

APA

Baskin, D. (2025). Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry. Yüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 30(3), 907-921. https://doi.org/10.53433/yyufbed.1718800

AMA

1.Baskin D. Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry. YYUFBED. 2025;30(3):907-921. doi:10.53433/yyufbed.1718800

Chicago

Baskin, Dilges. 2025. “Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry”. Yüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi 30 (3): 907-21. https://doi.org/10.53433/yyufbed.1718800.

EndNote

Baskin D (01 Aralık 2025) Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry. Yüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi 30 3 907–921.

IEEE

[1]D. Baskin, “Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry”, YYUFBED, c. 30, sy 3, ss. 907–921, Ara. 2025, doi: 10.53433/yyufbed.1718800.

ISNAD

Baskin, Dilges. “Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry”. Yüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi 30/3 (01 Aralık 2025): 907-921. https://doi.org/10.53433/yyufbed.1718800.

JAMA

1.Baskin D. Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry. YYUFBED. 2025;30:907–921.

MLA

Baskin, Dilges. “Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry”. Yüzüncü Yıl Üniversitesi Fen Bilimleri Enstitüsü Dergisi, c. 30, sy 3, Aralık 2025, ss. 907-21, doi:10.53433/yyufbed.1718800.

Vancouver

1.Dilges Baskin. Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry. YYUFBED. 01 Aralık 2025;30(3):907-21. doi:10.53433/yyufbed.1718800

Alevli Atomik Absorpsiyon Spektrometresi ile Atık Su Matrisinde Kobalt(II) Tayini için Hiyerarşik MnSb₂O₆ Parçacıklarının Dağılımlı Katı Faz Ekstraksiyonunda Kullanımı

Öz

Anahtar Kelimeler

Proje Numarası

Hierarchical MnSb₂O₆ Particles for Dispersive Solid-Phase Extraction of Co(II) from Wastewater by Flame Atomic Absorption Spectrometry

Öz

Anahtar Kelimeler

Destekleyen Kurum

Proje Numarası

Etik Beyan

Teşekkür

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

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