Preconcentration of Cu2+, Cr3+, Co2+, and Ni2+ by Solid-Phase Extraction Using a Recently Developed Mixed-Mode Sorbent

Yıl 2024, Cilt: 29 Sayı: 1, 109 - 118, 30.04.2024

Hayriye Aral

https://doi.org/10.53433/yyufbed.1315917

Öz

The enrichment and simultaneous analysis of Cu2+, Cr3+, Co2+, and Ni2+ by solid-phase extraction method were performed using a stationary phase containing amide functional groups, an aromatic benzene ring, and aliphatic groups in a silica-based structure that we had synthesized for HPLC separations in our previous studies. Solid-phase extraction was performed using a column system and the results obtained were analysed by ICP-OES. Effects of pH, amount of sorbent, amount of eluting solvent, sample volume, flow rates of the eluent and the sample, and interfering ions were evaluated in recovery processes for the metals in the sample solutions. Linear range, detection limit, and relative standard deviation (% RSD) values were calculated for each metal. The linear range (ng/mL) was between 0.01 and 0.25 for all ions, while the limit of detection (ng/mL) was found to be 0.64, 1.7, 0.44, and 0.51 and % RSD was 2.8, 2.4, 2.6, and 2.9 for Cu2+, Cr3+, Co2+, ve Ni2+, respectively.

Anahtar Kelimeler

Chromium, Cobalt, Copper, Nickel, Solid-based stationary phase, Solid-phase extraction

Cu2+, Cr3+, Co2+, and Ni2+’nin Son Zamanlarda Geliştirilen Karma Mod Bir Sorbent Kullanılarak Katı Faz Ekstraksiyonu ile Zenginleştirilmesi

Öz

Daha önceki çalışmalarımızda HPLC ayırmaları için sentezlenen silika tabanlı amid fonksiyonel grupları, benzene halkası ve alifatik gruplar içeren bir sabit baz kullanılarak katı faz ekstraksiyonu yöntemi ile Cu2+, Cr3+, Co2+, ve Ni2+’nin zenginleştirilmesi ve eş zamanlı analizi yapıldı. Katı faz ekstraksiyonu kolon sistemi kullanılarak gerçekleştirilmiş ve elde edilen sonuçlar ICP-OES ile analiz edilmiştir. Örnek çözeltilerdeki metaller için geri kazanım proseslerinde pH, sorbent miktarı, elüsyon çözücü miktarı, numune hacmi, eluent ve numunenin akış hızı ve yabancı iyon etkisi incelendi. Her metal için lineer aralık, dedeksiyon limiti ve bağıl standart sapma değerleri hesaplandı. Dedeksiyon limiti (ng/mL) Cu2+, Cr3+, Co2+, ve Ni2+ için sırasıyla 0.64, 1.7, 0.44 ve 0.51 ve bağıl standart sapma 2.8, 2.4, 2.6 ve 2.9 iken, lineer aralık bütün iyonlar için (ng/mL) 0.01 ve 0.25 aralığındadır.

Anahtar Kelimeler

Bakır, Katı faz ekstraksiyonu, Kobalt, Krom, Nikel, Silika tabanlı sabit faz

Kaynakça

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