Cinnamomum verum Ekstraktı Kullanılarak Farklı Çinko Tuzlarından Elde Edilen Çinko Oksit Nanopartiküllerinin Biyojenik Sentezi, Karakterizasyonu ve Metilen Mavisinin Bozunması

Yıl 2024, Cilt: 29 Sayı: 3, 939 - 954, 31.12.2024

Burcu Aydoğdu , İlkay Ünal

https://doi.org/10.53433/yyufbed.1518986

Öz

Bu çalışmada çinko asetat, çinko nitrat, çinko sülfat ve çinko klorür gibi farklı çinko tuzlarından Cinnamomum verum ekstraktı kullanılarak çinko oksit nanopartikülleri (ZnONP'ler) sentezlendi. Sentezlenen ZnONP'ler, X-ışını kırınımı (XRD), dinamik ışık saçılımı (DLS), Fourier dönüşümü kızılötesi spektroskopisi (FT-IR) ve transmisyon elektron mikroskobu (TEM) kullanılarak karakterize edildi. Ayrıca ZnO nanopartiküllerinin fotokatalitik aktiviteleri güneş ışığının varlığında ve yokluğunda test edildi. Tarçın ekstraktı DPPH radikal temizleme aktivitesi ve toplam fenolik içerik (TPC) açısından analiz edildi. Çalışma sonuçları, kullanılan çinko tuzunun türünün ZnO nanopartiküllerinin morfolojisini, boyutunu ve kristal yapısını önemli ölçüde etkilediğini gösterdi. Çinko asetattan (ZnONPsA) sentezlenen ZnONP'ler her iki durumda da üstün fotokatalitik aktivite gösterdi.

Anahtar Kelimeler

Biyojenik, Çinko oksit nanopartikül, DPPH, Metilen mavisi boyası, Toplam fenolik içerik

Biogenic Synthesis, Characterization and Degradation of Methylene Blue Dye of Zinc Oxide Nanoparticles from Different Zinc Salts Using Cinnamomum verum Extract

Öz

In this study, zinc oxide nanoparticles (ZnONPs) were synthesized using Cinnamomum verum extract from different zinc salts such as zinc acetate, zinc nitrate, zinc sulfate, and zinc chloride. The synthesized ZnONPs were characterized using X-ray diffraction (XRD), dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FT-IR), and transmission electron microscopy (TEM). Additionally, The photocatalytic activities of ZnO nanoparticles were tested in the presence and absence of sunlight. Cinnamomum verum extract was analyzed for DPPH radical scavenging activity and total phenolic content (TPC). The study results showed that the type of zinc salt used significantly affects the morphology, size, and crystal structure of the ZnO nanoparticles. ZnONPs synthesized from zinc acetate (ZnONPsA) showed superior photocatalytic activity in the presence and absence of sunlight.

Anahtar Kelimeler

Biogenic, DPPH, Methylene blue dye, Total phenolic content, Zinc oxide nanoparticle

Kaynakça

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