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Fabrication of TiO2 Nanoscale Thin Films and Its Structural Properties

Year 2016, Volume: 44 Issue: 3, 349 - 354, 01.09.2016

Abstract

The photocatalytic properties of titanium dioxide with extraordinary stability have potential application in chemical industry. Titanium dioxide nanoparticles were synthesized by sol-gel method and used dip-coating method for the preparation of thin films on glass substrate. To study the structural and physical characteristics of the samples, the XRD, UV-VIS and an optical microscope were used. The results show that with increasing the annealing temperature and thickness, larger particle size obtained and energy gap is reduced. Thus, by controlling the annealing temperature and thickness can be achieved to the gap-controlled semiconductors.

References

  • C. Claudia, D. Notter, F. Gottschalk, T. Sun, C. Som, and B. Nowack, Probabilistic environmental risk assessment of five nanomaterials (nano-TiO2, nano- Ag, nano-ZnO, CNT, and fullerenes), Nanotoxicology 10, no., 4 (2016) 436-444.
  • Y. Burak, M. Guida, F. Ciner, B. Aktan, M. I. Aydin, S. Meric, and H. Selcuk, A multifaceted aggregation and toxicity assessment study of sol–gel-based TiO2 nanoparticles during textile wastewater treatment, Desalination and Water Treatment 57, no. 11 (2016) 4966-4973.
  • H. Tae-Hwan, W. Kim, and W. Choi, Photoconversion of Dye-Sensitized Solar Cells with a 3D-Structured Photoelectrode Consisting of Both TiO2 Nanofibers and Nanoparticles, Journal of Electronic Materials 45, no. 6 (2016) 3195-3199.
  • I. Gether, “Determination of the photocatalytic activities of titanium dioxides and other white pigments.” Journal of Applied polymer Science 16, no., 9 (1972) 2387-2395.
  • F. Akira, T. N. Rao, and D.A. Tryk, Titanium dioxide photocatalysis.” Journal of Photochemistry and Photobiology C: Photochemistry Reviews 1, no., 1 (2000): 1-21.
  • T. Singh, N. Srivastava, P.K. Mishra, A.K. Bhatiya, N.L. Singh., Application of TiO Nanoparticle in 2 Photocatalytic Degradation of Organic Pollutants, In Materials Science Forum, vol. 855, pp. 20-32. Trans Tech Publications, 2016. parameters of molecular nanomagnets, Chemical Communications 52, no., 58 (2016) 8972-9008.
  • C.I. Bayly, P. Cieplak, W. Cornell, P.A. Kollman, A well- behaved electrostatic potential based method using charge restraints for deriving atomic charges: the RESP model, The Journal of Physical Chemistry 97, no., 40 (1993) 10269-10280.
  • S.K. Zheng, T.M. Wang, G. Xiang, C. Wang, Photocatalytic activity of nanostructured TiO 2 thin films prepared by dc magnetron sputtering method, Vacuum 62, no., 4 (2001) 361-366.
  • A. Di Paola, G. Marcì, L. Palmisano, M. Schiavello, K. Uosaki, S. Ikeda, B. Ohtani, Preparation of polycrystalline TiO photocatalysts impregnated 2 with various transition metal ions: characterization and photocatalytic activity for the degradation of 4-nitrophenol, The Journal of Physical Chemistry B, 106 (2002) 637-645.
  • F. Bataille, J.L. Lemberton, G. Pérot, P. Leyrit, T. Cseri, N. Marchal, S. Kasztelan, An FT-IR study of the adsorption of aromatic hydrocarbons and of 2, 6-lutidine on H-FER and H-ZSM-5 zeolites 181, Applied Catalysis A: General 220 (2001) 305-307.

Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri

Year 2016, Volume: 44 Issue: 3, 349 - 354, 01.09.2016

Abstract

O lağanüstü kararlılıktaki titanyum dioksit fotokatalitik özellikleri nedeniyle kimya endüstrisinde potansiyel uygulamalara sahiptir. Titanyum dioksit nanopartiküller sol-jel yöntemi ile sentezlenmiş ve daldırmalı kaplama yöntemi ile cam yüzey üzerine ince film hazırlamak için kullanılmıştır. Örneklerin yapısal ve fiziksel özelliklerini karaterize etmek için XRD, UV-VIS ve optik mikroskop kullanılmıştır. Sonuçlar yakma sıcaklığı ve kalınlık arttıkça, partikül boyutunun arttığını ve enerji aralığının azaldığını göstermiştir. Enerji aralığı kontrollü yarı iletkenler, yakma sıcaklığını ve kalınlığı kontrol ederek üretilebilir

References

  • C. Claudia, D. Notter, F. Gottschalk, T. Sun, C. Som, and B. Nowack, Probabilistic environmental risk assessment of five nanomaterials (nano-TiO2, nano- Ag, nano-ZnO, CNT, and fullerenes), Nanotoxicology 10, no., 4 (2016) 436-444.
  • Y. Burak, M. Guida, F. Ciner, B. Aktan, M. I. Aydin, S. Meric, and H. Selcuk, A multifaceted aggregation and toxicity assessment study of sol–gel-based TiO2 nanoparticles during textile wastewater treatment, Desalination and Water Treatment 57, no. 11 (2016) 4966-4973.
  • H. Tae-Hwan, W. Kim, and W. Choi, Photoconversion of Dye-Sensitized Solar Cells with a 3D-Structured Photoelectrode Consisting of Both TiO2 Nanofibers and Nanoparticles, Journal of Electronic Materials 45, no. 6 (2016) 3195-3199.
  • I. Gether, “Determination of the photocatalytic activities of titanium dioxides and other white pigments.” Journal of Applied polymer Science 16, no., 9 (1972) 2387-2395.
  • F. Akira, T. N. Rao, and D.A. Tryk, Titanium dioxide photocatalysis.” Journal of Photochemistry and Photobiology C: Photochemistry Reviews 1, no., 1 (2000): 1-21.
  • T. Singh, N. Srivastava, P.K. Mishra, A.K. Bhatiya, N.L. Singh., Application of TiO Nanoparticle in 2 Photocatalytic Degradation of Organic Pollutants, In Materials Science Forum, vol. 855, pp. 20-32. Trans Tech Publications, 2016. parameters of molecular nanomagnets, Chemical Communications 52, no., 58 (2016) 8972-9008.
  • C.I. Bayly, P. Cieplak, W. Cornell, P.A. Kollman, A well- behaved electrostatic potential based method using charge restraints for deriving atomic charges: the RESP model, The Journal of Physical Chemistry 97, no., 40 (1993) 10269-10280.
  • S.K. Zheng, T.M. Wang, G. Xiang, C. Wang, Photocatalytic activity of nanostructured TiO 2 thin films prepared by dc magnetron sputtering method, Vacuum 62, no., 4 (2001) 361-366.
  • A. Di Paola, G. Marcì, L. Palmisano, M. Schiavello, K. Uosaki, S. Ikeda, B. Ohtani, Preparation of polycrystalline TiO photocatalysts impregnated 2 with various transition metal ions: characterization and photocatalytic activity for the degradation of 4-nitrophenol, The Journal of Physical Chemistry B, 106 (2002) 637-645.
  • F. Bataille, J.L. Lemberton, G. Pérot, P. Leyrit, T. Cseri, N. Marchal, S. Kasztelan, An FT-IR study of the adsorption of aromatic hydrocarbons and of 2, 6-lutidine on H-FER and H-ZSM-5 zeolites 181, Applied Catalysis A: General 220 (2001) 305-307.
There are 10 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Sara Mohammadi Bilankohi This is me

Majid Ebrahimzadeh This is me

Publication Date September 1, 2016
Published in Issue Year 2016 Volume: 44 Issue: 3

Cite

APA Bilankohi, S. M., & Ebrahimzadeh, M. (2016). Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri. Hacettepe Journal of Biology and Chemistry, 44(3), 349-354.
AMA Bilankohi SM, Ebrahimzadeh M. Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri. HJBC. September 2016;44(3):349-354.
Chicago Bilankohi, Sara Mohammadi, and Majid Ebrahimzadeh. “Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi Ve Yapısal Özellikleri”. Hacettepe Journal of Biology and Chemistry 44, no. 3 (September 2016): 349-54.
EndNote Bilankohi SM, Ebrahimzadeh M (September 1, 2016) Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri. Hacettepe Journal of Biology and Chemistry 44 3 349–354.
IEEE S. M. Bilankohi and M. Ebrahimzadeh, “Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri”, HJBC, vol. 44, no. 3, pp. 349–354, 2016.
ISNAD Bilankohi, Sara Mohammadi - Ebrahimzadeh, Majid. “Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi Ve Yapısal Özellikleri”. Hacettepe Journal of Biology and Chemistry 44/3 (September 2016), 349-354.
JAMA Bilankohi SM, Ebrahimzadeh M. Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri. HJBC. 2016;44:349–354.
MLA Bilankohi, Sara Mohammadi and Majid Ebrahimzadeh. “Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi Ve Yapısal Özellikleri”. Hacettepe Journal of Biology and Chemistry, vol. 44, no. 3, 2016, pp. 349-54.
Vancouver Bilankohi SM, Ebrahimzadeh M. Titanyum Dioksit Nano Ölçek İnce Filmlerin Üretimi ve Yapısal Özellikleri. HJBC. 2016;44(3):349-54.

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