Year 2021, Volume 11 , Issue 2, Pages 1329 - 1340 2021-06-01

Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry
Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry

Ergül MEYVACI [1] , Temel ÖZTÜRK [2] , Bedrettin SAVAŞ [3]


Poly(ε-caprolactone-block-ethylene glycol methyl ether) [poly(RCL-b-mEG)] block copolymers were synthesized by "click" chemistry of polyethylene glycol methyl ether propargyl (mPEG-propargyl) and poly(ε-caprolactone) azido (RPCL-N3). Thus, mPEG-propargyl was acquired through the reaction of polyethylene glycol methyl ether with propargyl bromine. 2-[2-(2-Azidoethoxy)ethoxy]ethanol (N3ol) was synthesized by using 2-[2-(2-chloroethoxy)ethoxy]ethanol and sodium azide. Synthesis of RPCL-N3 was acquired using ROP of ε-caprolactone and N3ol. By using mPEG-propargyl and RPCL-N3, poly(RCL-b-mEG) block copolymers were obtained via "click" chemistry. The monofunctional homopolymers in the study were utilized for the syntheses of poly(RCL-b-mEG) block copolymers. The outputs were identified by scanning electron microscopy, 1H-nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, Fourier-transform infrared spectroscopy, gel permeation chromatography, and dynamic light scattering instruments. The spectroscopic and thermal analysis of the block copolymers monitor that the copolymers were built through combination of ROP and "click" chemistry.
Poly(ε-caprolactone-block-ethylene glycol methyl ether) [poly(RCL-b-mEG)] block copolymers were synthesized by "click" chemistry of polyethylene glycol methyl ether propargyl (mPEG-propargyl) and poly(ε-caprolactone) azido (RPCL-N3). Thus, mPEG-propargyl was acquired through the reaction of polyethylene glycol methyl ether with propargyl bromine. 2-[2-(2-Azidoethoxy)ethoxy]ethanol (N3ol) was synthesized by using 2-[2-(2-chloroethoxy)ethoxy]ethanol and sodium azide. Synthesis of RPCL-N3 was acquired using ROP of ε-caprolactone and N3ol. By using mPEG-propargyl and RPCL-N3, poly(RCL-b-mEG) block copolymers were obtained via "click" chemistry. The monofunctional homopolymers in the study were utilized for the syntheses of poly(RCL-b-mEG) block copolymers. The outputs were identified by scanning electron microscopy, 1H-nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, Fourier-transform infrared spectroscopy, gel permeation chromatography, and dynamic light scattering instruments. The spectroscopic and thermal analysis of the block copolymers monitor that the copolymers were built through combination of ROP and "click" chemistry.
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Primary Language en
Subjects Engineering, Chemical
Published Date Haziran-2021
Journal Section Kimya / Chemistry, Kimya Mühendisliği / Chemical Engineering
Authors

Orcid: 0000-0003-3530-1316
Author: Ergül MEYVACI
Institution: Giresun University
Country: Turkey


Orcid: 0000-0002-7856-9809
Author: Temel ÖZTÜRK (Primary Author)
Institution: Giresun Üniversitesi
Country: Turkey


Orcid: 0000-0002-6620-5493
Author: Bedrettin SAVAŞ
Institution: KAFKAS UNIVERSITY
Country: Turkey


Supporting Institution Giresun üniversitesi
Project Number FEN-BAP-C-281119-76
Dates

Application Date : December 5, 2020
Acceptance Date : December 30, 2020
Publication Date : June 1, 2021

Bibtex @research article { jist836346, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Igdir University}, year = {2021}, volume = {11}, pages = {1329 - 1340}, doi = {10.21597/jist.836346}, title = {Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry}, key = {cite}, author = {Meyvacı, Ergül and Öztürk, Temel and Savaş, Bedrettin} }
APA Meyvacı, E , Öztürk, T , Savaş, B . (2021). Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry . Journal of the Institute of Science and Technology , 11 (2) , 1329-1340 . DOI: 10.21597/jist.836346
MLA Meyvacı, E , Öztürk, T , Savaş, B . "Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry" . Journal of the Institute of Science and Technology 11 (2021 ): 1329-1340 <https://dergipark.org.tr/en/pub/jist/issue/61423/836346>
Chicago Meyvacı, E , Öztürk, T , Savaş, B . "Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry". Journal of the Institute of Science and Technology 11 (2021 ): 1329-1340
RIS TY - JOUR T1 - Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry AU - Ergül Meyvacı , Temel Öztürk , Bedrettin Savaş Y1 - 2021 PY - 2021 N1 - doi: 10.21597/jist.836346 DO - 10.21597/jist.836346 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 1329 EP - 1340 VL - 11 IS - 2 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.836346 UR - https://doi.org/10.21597/jist.836346 Y2 - 2020 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry %A Ergül Meyvacı , Temel Öztürk , Bedrettin Savaş %T Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry %D 2021 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 11 %N 2 %R doi: 10.21597/jist.836346 %U 10.21597/jist.836346
ISNAD Meyvacı, Ergül , Öztürk, Temel , Savaş, Bedrettin . "Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry". Journal of the Institute of Science and Technology 11 / 2 (June 2021): 1329-1340 . https://doi.org/10.21597/jist.836346
AMA Meyvacı E , Öztürk T , Savaş B . Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry. Iğdır Üniv. Fen Bil Enst. Der.. 2021; 11(2): 1329-1340.
Vancouver Meyvacı E , Öztürk T , Savaş B . Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry. Journal of the Institute of Science and Technology. 2021; 11(2): 1329-1340.
IEEE E. Meyvacı , T. Öztürk and B. Savaş , "Syntheses And Characterizations Of Poly(ε-Caprolactone-b-Ethylene Glycol Methyl Ether) Block Copolymers Via Ring-Opening Polymerization And "Click" Chemistry", Journal of the Institute of Science and Technology, vol. 11, no. 2, pp. 1329-1340, Jun. 2021, doi:10.21597/jist.836346