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Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers

Year 2025, Volume: 11 Issue: 4, 1024 - 1039, 31.07.2025

Abstract

Nanofluids have gained increasing attention because of their superior thermophysical properties compared to the base fluid. However, the environmental impact of the nanofluids has raised concerns together with their potential use in practical applications. This study aims to explore the impact of using Fe3O4 nanofluids stabilized by synthetic and natural stabilizers (CTAB and gelatin) to enhance thermal efficiency while minimizing environmental impact. The Fe3O4 nanoparticles were synthesized by using a hydrothermal method with an average particle size of 200 nm. The nanofluids were prepared by dispersing the nanoparticles (0.1 wt% Fe3O4) in the presence of the stabilizers with concentrations between 0.2 and 1.0 wt% in deionized water. The impact of stabilizer type and concentration on the nanofluids’ stability was monitored through visual inspection. The thermal efficiency of the nanofluids was investigated experimentally on a laboratory-scale cooling tower at 45°C, with a 0.06 m3 /h volume flow rate, and between 0.02 and 0.07 kg/s air mass flow rates. The results show that nanofluid with 0.8 wt% gelatin achieves maximum stability for up to three weeks, significantly outperforming the nanofluid with the CTAB, which stabilized for only up to one week. The nanofluid with 0.8 wt% gelatin achieved a higher efficiency of 47 % at the air mass flow rate of 0.04 kg/s, consistently outperformed its CTAB counterpart. These results show that gelatin, a natural polypeptide, is more suitable than CTAB for nanofluid formulations, offering both thermal efficiency enhancement and environmental benefits due to its non-toxic and low-cost nature.

References

  • [1] Afshari F, Dehghanpour H. A review study on cooling towers; types, performance and application. ALKU Fen Bilim Derg 2019:1–10.
  • [2] Lemouari M, Boumaza M, Kaabi A. Experimental analysis of heat and mass transfer phenomena in a direct contact evaporative cooling tower. Energy Convers Manag 2009;50:1610–7. [CrossRef]
  • [3] DHI Solution. Improving the energy efficiency of cooling systems. Available at: https://www.dhigroup.com/upload/publications/misc/Energy_SolutionFlyer_Improving%20the%20energy%20efficiency%20of%20cooling%20systems.pdf. Accessed June 27, 2025.
  • [4] Cortinovis GF, Paiva JL, Song TW, Pinto JM. A systemic approach for optimal cooling tower operation. Energy Convers Manag 2009;50:2200–9. [CrossRef]
  • [5] Mousa MH, Yang CM, Nawaz K, Miljkovic N. Review of heat transfer enhancement techniques in two-phase flows for highly efficient and sustainable cooling. Renew Sustain Energy Rev 2022;155:111896. [CrossRef]
  • [6] Mousavi SB, Heris SZ, Estellé P. Viscosity, tribological and physicochemical features of ZnO and MoS₂ diesel oil-based nanofluids: An experimental study. Fuel 2021;293:120481. [CrossRef]
  • [7] Nam NH, Luong NH. Nanoparticles: Synthesis and applications. In: Mozafari M, editor. Materials for biomedical engineering. Amsterdam: Elsevier; 2019. p. 211–40. [CrossRef]
  • [8] Yu W, Xie H. A review on nanofluids: Preparation, stability mechanisms, and applications. J Nanomater. 2012;2012:435873. [CrossRef]
  • [9] Bakthavatchalam B, Habib K, Saidur R, Saha BB, Irshad K. Comprehensive study on nanofluid and ionanofluid for heat transfer enhancement: A review on current and future perspective. J Mol Liq 2020;305:112787. [CrossRef]
  • [10] Akroot A, Namlı L. Performance assessment of an electrolyte-supported and anode supported planar solid oxide fuel cells hybrid system. J Therm Eng 2021;7:1921–35.
  • [11] Javadi FS, Saidur R, Kamalisarvestani M. Investigating performance improvement of solar collectors by using nanofluids. Renew Sustain Energy Rev 2013;28:232–45. [CrossRef]
  • [12] Assael MJ, Antoniadis KD, Wakeham WA, Zhang X. Potential applications of nanofluids for heat transfer. Int J Heat Mass Transf 2019;138:597–607. [CrossRef]
  • [13] Bacha HB, Ullah N, Hamid A, Shah NA. A comprehensive review on nanofluids: Synthesis, cutting-edge applications, and future prospects. Int J Thermofluids 2024;22:100595. [CrossRef]
  • [14] Zou J, He S, Long G, Sun F, Gao M. Field test on ventilation performance for high level water collecting wet cooling tower under crosswind conditions. Appl Therm Eng 2018;133:439–45. [CrossRef]
  • [15] Gao M, Guo C, Ma C, Shi Y, Sun F. Thermal performance for wet cooling tower with different layout patterns of fillings under typical crosswind conditions. Energies 2017;10:65. [CrossRef]
  • [16] Gao M, Zou J, He S, Sun F. Thermal performance analysis for high level water collecting wet cooling tower under crosswind conditions. Appl Therm Eng 2018;136:568–75. [CrossRef]
  • [17] Zhang Z, Gao M, Dang Z, He S, Sun F. An exploratory research on performance improvement of super-large natural draft wet cooling tower based on the reconstructed dry-wet hybrid rain zone. Int J Heat Mass Transf 2019;142:118465. [CrossRef]
  • [18] Zhang Z, Wang M, Liu Y, Gao M, He S, Shi Y. An exploratory research on performance improvement of super-large natural draft wet cooling tower based on the reconstructed dry-wet hybrid rain zone, part 2: Crosswind effects. Int J Heat Mass Transf 2020;160:120225. [CrossRef]
  • [19] Rahmati M, Alavi SR, Sedaghat A. Thermal performance of natural draft wet cooling towers under cross-wind conditions based on experimental data and regression analysis. In: 2016 6th Conf Therm Power Plants CTPP. IEEE; 2016:1–5. [CrossRef]
  • [20] Dang Z, Gao M, Long G, Zou J, He S, Sun F. Crosswind influence on cooling capacity in different zones for high level water collecting wet cooling towers based on field test. J Wind Eng Ind Aerodyn 2019;190:134–42. [CrossRef]
  • [21] Yu W, Xie H, Li Y, Chen L, Wang Q. Experimental investigation on the heat transfer properties of Al2O3 nanofluids using the mixture of ethylene glycol and water as base fluid. Powder Technol 2012;230:14–9. [CrossRef]
  • [22] Fares MN, Al-Mayyahi MA, Salman AD. Performance evaluation of a wet cooling water tower using graphene nanofluids. JP J Heat Mass Transf 2018;15:935–51. [CrossRef]
  • [23] Mousavi H, Ghomshe SMT, Rashidi A, Mirzaei M. Hybrids carbon quantum dots as new nanofluids for heat transfer enhancement in wet cooling towers. Heat Mass Transf 2022;58:309–20. [CrossRef]
  • [24] Siricharoenpanich A, Wiriyasart S, Srichat A, Naphon P. Thermal cooling system with Ag/Fe3O4 nanofluids mixture as coolant for electronic devices cooling. Case Stud Therm Eng 2020;20:100641. [CrossRef]
  • [25] Afshari F, Mandev E, Rahimpour S, Muratçobanoğlu B, Şahin B, Manay E, Teimuri-Mofrad R. Experimental and numerical study on air-to-nanofluid thermoelectric cooling system using novel surface-modified Fe3O4 nanoparticles. Microfluid Nanofluidics 2023;27:26. [CrossRef]
  • [26] Mahbubul IM, Shahrul IM, Khaleduzzaman SS, Saidur R, Amalina MA, Turgut ALPASLAN. Experimental investigation on effect of ultrasonication duration on colloidal dispersion and thermophysical properties of alumina–water nanofluid. Int J Heat Mass Transf 2015;88:73–81. [CrossRef]
  • [27] Qamar A, Anwar Z, Ali H, Shaukat R, Imran S, Arshad A, et al. Preparation and dispersion stability of aqueous metal oxide nanofluids for potential heat transfer applications: A review of experimental studies. J Therm Anal Calorim 2020;1–24. [CrossRef]
  • [28] Shima PD, Philip J, Raj B. Influence of aggregation on thermal conductivity in stable and unstable nanofluids. Appl Phys Lett 2010;97:153113. [CrossRef]
  • [29] Ioniţă M, Vlăsceanu GM, Watzlawek AA, Voicu SI, Burns JS, Iovu H. Graphene and functionalized graphene: Extraordinary prospects for nanobiocomposite materials. Compos B Eng 2017;121:34–57. [CrossRef]
  • [30] Khan Z, Singh T, Hussain JI, Hashmi AA. Au (III)–CTAB reduction by ascorbic acid: Preparation and characterization of gold nanoparticles. Colloids Surf B Biointerfaces 2013;104:11–7. [CrossRef]
  • [31] Yonezawa T, Kamoshita K, Tanaka M, Kinoshita T. Easy preparation of stable iron oxide nanoparticles using gelatin as stabilizing molecules. Jpn J Appl Phys 2008;47:138992. [CrossRef]
  • [32] Harun MA, Sidik NAC, Rohaizan MAM. A review on stability and heat transfer performance of nanofluid using surfactants. J Adv Res Mater Sci 2020;75:1–9. [CrossRef]
  • [33] Lei J, Luo Z, Qing S, Huang X, Li F. Effect of surfactants on the stability, rheological properties, and thermal conductivity of Fe3O4 nanofluids. Powder Technol 2022;399:117197. [CrossRef]
  • [34] Arora N, Gupta M. An experimental analysis of CTAB surfactant on thermo-physical properties and stability of MWCNT/water nanofluids. Appl Nanosci 2022;12:1941–66. [CrossRef]
  • [35] Shen LH, Bao JF, Wang D, Wang YX, Chen ZW, Ren L, et al. One-step synthesis of monodisperse, water-soluble ultra-small Fe3O4 nanoparticles for potential bio-application. Nanoscale 2013;5:2133–41. [CrossRef]
  • [36] Abareshi M, Goharshadi EK, Zebarjad SM, Fadafan HK, Youssefi A. Fabrication, characterization and measurement of thermal conductivity of Fe3O4 nanofluids. J Magn Magn Mater 2010;322:3895–901. [CrossRef]
  • [37] Sirivat A, Paradee N. Facile synthesis of gelatin-coated Fe3O4 nanoparticle: Effect of pH in single-step co-precipitation for cancer drug loading. Mater Des 2019;181:107942. [CrossRef]
  • [38] Bahaya B, Johnson DW, Yavuzturk CC. On the effect of graphene nanoplatelets on water–graphene nanofluid thermal conductivity, viscosity, and heat transfer under laminar external flow conditions. J Heat Transf 2018;140:064501. [CrossRef]
  • [39] Mehta B, Subhedar D, Panchal H, Sadasivuni KK. Stability and thermophysical properties enhancement of Al2O3-water nanofluid using cationic CTAB surfactant. Int J Thermofluids 2023;20:100410. [CrossRef]
  • [40] Baraı R, Kumar D, Wankhade A. Heat transfer performance of nanofluids in heat exchanger: A review. J Therm Eng 2021;9:86–106. [CrossRef]
  • [41] Varma KK, Naveen NS, Kishore PS, Pujari S, Jogi K, Raju VD. Optimizing the thermal performance of a double-pipe heat exchanger using twisted tapes with variable cuts and Fe3O4 nanofluid. J Therm Eng 2024;10:1184–97. [CrossRef]
  • [42] Philip J, Shima PD, Raj B. Enhancement of thermal conductivity in magnetite based nanofluid due to chainlike structures. Appl Phys Lett 2007;91:203108. [CrossRef]
  • [43] Sundar LS, Singh MK, Sousa AC. Investigation of thermal conductivity and viscosity of Fe3O4 nanofluid for heat transfer applications. Int Commun Heat Mass Transf 2013;44:7–14. [CrossRef]
  • [44] Pastoriza-Gallego MJ, Lugo L, Legido JL, Piñeiro MM. Enhancement of thermal conductivity and volumetric behavior of FexOy nanofluids. J Appl Phys 2011;110:014309. [CrossRef]
  • [45] Hong TK, Yang HS, Choi CJ. Study of the enhanced thermal conductivity of Fe nanofluids. J Appl Phys 2005;97:064311. [CrossRef]
  • [46] Rahmati M, Alavi SR, Tavakoli MR. Investigation of heat transfer in mechanical draft wet cooling towers using infrared thermal images: An experimental study. Int J Refrig 2018;88:229–38. [CrossRef]
  • [47] Ekiciler R, Arslan K, Turgut O. Application of nanofluid flow in entropy generation and thermal performance analysis of parabolic trough solar collector: Experimental and numerical study. J Therm Anal Calorim 2023;148:7299–318. [CrossRef]
  • [48] Holman JP. Experimental methods for engineers. 8th ed. New York: McGraw-Hill; 2021.
  • [49] Moffat RJ. Contributions to the theory of single-sample uncertainty analysis. J Fluids Eng 1982;104:250–8. [CrossRef]
  • [50] Mondal PK, Mukherjee S, Kundu B, Wongwises S. Investigation of the crosswind-influenced thermal performance of a natural draft counterflow cooling tower. Int J Heat Mass Transf 2015;85:1049–57. [CrossRef]
  • [51] Bahadur A, Saeed A, Shoaib M, Iqbal S, Bashir MI, Waqas M, et al. Eco-friendly synthesis of magnetite (Fe3O4) nanoparticles with tunable size: Dielectric, magnetic, thermal and optical studies. Mater Chem Phys 2017;198:229–35. [CrossRef]
  • [52] Xu J, Yang H, Fu W, Du K, Sui Y, Chen J, et al. Preparation and magnetic properties of magnetite nanoparticles by sol–gel method. J Magn Magn Mater 2007;309:307–11. [CrossRef]
  • [53] Daoush WM. Co-precipitation and magnetic properties of magnetite nanoparticles for potential biomedical applications. J Nanomed Res 2017;5:00118. [CrossRef]
  • [54] Dhumal J, Bandgar S, Zipare K, Shahane G. Fe3O4 ferrofluid nanoparticles: Synthesis and rheological behavior. Int J Mater Chem Phys 2015;1:141–5.
  • [55] Aguilar-Méndez MA, Espinosa-Solares T, Guerrero-Toledo FDM, Canseco-González D, Velázquez-Hernández A, Aguilar-Moreno GS, et al. Synthesis and characterisation of magnetite nanoparticles using gelatin and starch as capping agents. IET Nanobiotechnol 2020;14:94–7. [CrossRef]
  • [56] Mehta B, Subhedar D, Panchal H, Sadasivuni KK. Stability and thermophysical properties enhancement of Al2O3-water nanofluid using cationic CTAB surfactant. Int J Thermofluids 2023;20:100410. [CrossRef]
  • [57] Mostafizur RM, Rasul MG, Nabi MN. Effect of surfactant on stability, thermal conductivity, and viscosity of aluminium oxide–methanol nanofluids for heat transfer applications. Therm Sci Eng Prog 2022;31:101302. [CrossRef]
  • [58] Musa A, Ahmad MB, Hussein MZ, Saiman MI, Sani HA. Effect of gelatin-stabilized copper nanoparticles on catalytic reduction of methylene blue. Nanoscale Res Lett 2016;11:1–13. [CrossRef]
  • [59] Anandan D, Rajan KS. Synthesis and stability of cupric oxide-based nanofluid: A novel coolant for efficient cooling. Asian J Sci Res 2012;5:21827. [CrossRef]
  • [60] Sivera M, Kvitek L, Soukupova J, Panacek A, Prucek R, Vecerova R, et al. Silver nanoparticles modified by gelatin with extraordinary pH stability and long-term antibacterial activity. PLoS One 2014;9:e103675. [CrossRef]
  • [61] Rahmati M. Effects of ZnO/water nanofluid on the thermal performance of wet cooling towers. Int J Refrig 2021;131:526–34. [CrossRef]
  • [62] Askari S, Lotfi R, Seifkordi A, Rashidi AM, Koolivand H. A novel approach for energy and water conservation in wet cooling towers by using MWNTs and nanoporous graphene nanofluids. Energy Convers Manag 2016;109:10–8. [CrossRef]
  • [63] Amini M, Zareh M, Maleki S. Thermal performance analysis of mechanical draft cooling tower filled with rotational splash type packing by using nanofluids. Appl Therm Eng 2020;175:115268. [CrossRef]
  • [64] Salman EA, Makki HF, Sharif A. Effect of black carbon and alumina nanofluid on thermal and dynamic efficiency in upward spraying cooling tower. Iraq J Chem Pet Eng 2023;24:11–8. [CrossRef]
  • [65] Elsaid K, Olabi AG, Wilberforce T, Abdelkareem MA, Sayed ET. Environmental impacts of nanofluids: A review. Sci Total Environ 2021;763:144202. [CrossRef]
  • [66] Mottier A, Mouchet F, Pinelli E, Gauthier L, Flahaut E. Environmental impact of engineered carbon nanoparticles: From releases to effects on the aquatic biota. Curr Opin Biotechnol 2017;46:1–6. [CrossRef]
There are 66 citations in total.

Details

Primary Language English
Subjects Aerodynamics (Excl. Hypersonic Aerodynamics)
Journal Section Articles
Authors

Berkman İşçi 0000-0002-8825-072X

Abdulghani Almaksour This is me 0009-0008-5738-2237

Kıymet Yildirim This is me 0009-0001-8080-0694

Nurettin Eltugral This is me 0000-0001-6393-9611

Kamil Arslan 0000-0002-1216-6812

Publication Date July 31, 2025
Submission Date June 10, 2024
Acceptance Date December 31, 2024
Published in Issue Year 2025 Volume: 11 Issue: 4

Cite

APA İşçi, B., Almaksour, A., Yildirim, K., … Eltugral, N. (2025). Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers. Journal of Thermal Engineering, 11(4), 1024-1039. https://doi.org/10.14744/thermal.0000967
AMA İşçi B, Almaksour A, Yildirim K, Eltugral N, Arslan K. Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers. Journal of Thermal Engineering. July 2025;11(4):1024-1039. doi:10.14744/thermal.0000967
Chicago İşçi, Berkman, Abdulghani Almaksour, Kıymet Yildirim, Nurettin Eltugral, and Kamil Arslan. “Enhancement of Thermal Efficiency of a Wet Cooling Tower Using Magnetite Nanofluid With Different Stabilizers”. Journal of Thermal Engineering 11, no. 4 (July 2025): 1024-39. https://doi.org/10.14744/thermal.0000967.
EndNote İşçi B, Almaksour A, Yildirim K, Eltugral N, Arslan K (July 1, 2025) Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers. Journal of Thermal Engineering 11 4 1024–1039.
IEEE B. İşçi, A. Almaksour, K. Yildirim, N. Eltugral, and K. Arslan, “Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers”, Journal of Thermal Engineering, vol. 11, no. 4, pp. 1024–1039, 2025, doi: 10.14744/thermal.0000967.
ISNAD İşçi, Berkman et al. “Enhancement of Thermal Efficiency of a Wet Cooling Tower Using Magnetite Nanofluid With Different Stabilizers”. Journal of Thermal Engineering 11/4 (July2025), 1024-1039. https://doi.org/10.14744/thermal.0000967.
JAMA İşçi B, Almaksour A, Yildirim K, Eltugral N, Arslan K. Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers. Journal of Thermal Engineering. 2025;11:1024–1039.
MLA İşçi, Berkman et al. “Enhancement of Thermal Efficiency of a Wet Cooling Tower Using Magnetite Nanofluid With Different Stabilizers”. Journal of Thermal Engineering, vol. 11, no. 4, 2025, pp. 1024-39, doi:10.14744/thermal.0000967.
Vancouver İşçi B, Almaksour A, Yildirim K, Eltugral N, Arslan K. Enhancement of thermal efficiency of a wet cooling tower using magnetite nanofluid with different stabilizers. Journal of Thermal Engineering. 2025;11(4):1024-39.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK http://eds.yildiz.edu.tr/journal-of-thermal-engineering