Mersin sütleğeni (Euphorbia myrsinites L.) ekstraktının kumaşların bazı mekanik özellikleri üzerine etkisinin araştırılması

Öz

Tekstil ürünleri gıda maddelerinden sonra insan vücuduyla en doğrudan ilişkiye sahiptir. Giysilerimizdeki boya kalıntıları ve kimyasallar terleme ve solunum yoluyla vücudumuza nüfuz edebilir ve sağlığımızı etkileyebilir. Bu çalışmanın amacı, Euphorbia myrsinites L.'den elde edilen ekstraktın kumaşların çeşitli mekanik özellikleri üzerindeki etkisini araştırmak ve bu özellikleri iyileştirmek için şu anda kullanılan kimyasallara doğal alternatifler bulmaktır. Çalışmada kurutulmuş E. myrsinites örneklerinden kaynatma yöntemiyle bir ekstrakt elde edilmiştir. En uygun kumaşı belirlemek için ekstrakt çeşitli kumaşlara uygulanmış ve bir numune kumaş üretilmiştir. Üretilen numune ve standart kumaşlar üzerinde sürtünme haslığı, dokunma, yanıcılık, kırışma direnci ve aşınma direnci testleri yapılmıştır. Çalışma sonucunda, sütleğen ekstraktı kullanılarak üretilen numune kumaşın, ıslak ve kuru sürtünme haslığı, kırışma direnci ve mekanik sürtünme direnci testlerinde standart kumaştan daha iyi performans gösterdiği ortaya çıkmıştır. Ayrıca dokunma testinde de istenilen tokluk, yoğunluk ve pürüzsüzlük seviyelerini göstermiştir. Kumaşın yanıcılık testlerinde yaklaşık 13-14 saniyede tutuşmasıyla birlikte, gelişmiş laboratuvarlarda yapılan bu testlerde kriter 10 saniye olduğu için bu sonuç olumlu olarak değerlendirilmiştir. Bu çalışmanın bulgularına dayanarak, sağlığa zararlı kimyasallar yerine sütleğen ekstraktı kullanılarak kırışmayan, çabuk yıpranmayan ve kolay yanmayan kumaşlar üretilebileceği ileri sürülebilir.

Anahtar Kelimeler

• Sütleğen ekstraktı
• doğal kumaş
• boya dökme
• sürtünme direnci
• yanma direnci

Investigation of the effect of myrtle spurge (Euphorbia myrsinites L.) extract on some mechanical properties of fabrics

Öz

Textile products have the most direct relationship with the human body after food products. Dye residues and chemicals on our clothes can penetrate our bodies through sweating and respiration which affects our health. The purpose of this study was to investigate the effect of the extract obtained from Euphorbia myrsinites L. on various mechanical properties of fabrics and to find natural alternatives to currently used chemicals to improve these properties. In the study, an extract was obtained from the dried E. myrsinites samples by the decoction method. The extract was applied to various fabrics to determine the most suitable fabric, and a sample fabric was produced. The friction fastness, touching, flammability, crease resistance, and abrasion resistance tests were performed on the produced sample and standard fabrics. As a result of the study, it was revealed that the sample fabric produced using Euphorbia extract outperformed the standard fabric in wet and dry friction fastness, crease resistance, and mechanical friction resistance tests. It also reached the desired levels of toughness, density, and smoothness in the touching test. The fabric ignited approximately 13-14 seconds in flammability tests, and this result was considered positive as the criterion for these tests performed in advanced laboratories is 10 seconds. Based on the findings of this study, it can be suggested that fabrics which do not wrinkle, wear out quickly, or burn easily can be produced by using Euphorbia extract instead of chemicals that are harmful to health.

Anahtar Kelimeler

• Euphorbia extract
• natural fabric
• dye releasing
• friction resistance
• fire resistance

Kaynakça

1. Ahmed S, Yousaf M, Mothan RA, Al-Rehaily AJ. (2016). Studies on wound healing activity of some Euphorbia species on experimental rats. African Journal of Traditional, Complementary and Alternative Medicines 13 (5):145-152.
2. Ashraf A, Sarfraz RA, Rashid MA, Shahid M (2015). Antioxidant, antimicrobial, antitumor, and cytotoxic activities of an important medicinal plant (Euphorbia royleana) from Pakistan. Journal of Food and Drug Analysis 23(1):109-115.
3. Atakan R , Bical A, Celebi E, Ozcan G, Soydan N, Sarac S (2019). Development of a flame retardant chemical for finishing of cotton, polyester, and CO/PET blends. Journal of Industrial Textiles 49(2): 141-161.
4. Başaran AA (2012). Ülkemizdeki Bitkisel İlaçlar ve Ürünlerde Yasal Durum. MİSED 27(28): 22-26.
5. Baytop T (1999). Türkiye’de Bitkilerle Tedavi - Geçmişte ve Bugün. İstanbul: İstanbul Üniversitesi Yayınları.
6. Bhandari NL, Bist K, Ghimire J, Chaudhary S, Pandey PD, Adhikari R (2020). Feasibility study of the Euphorbia pulcherrima plant extract as natural dye with different mordants for fabric dyeing. Journal of Institute of Science and Technology 25(1): 30-36.
7. Bhatia H, Manhas RK, Kumar K, Magotra R (2014). Traditional knowledge on poisonous plants of Udhampur district of Jammu and Kashmir, India. Journal of Ethnopharmacology 152: 207-216.
8. Chaabi M, Freund-Michel V, Frossard N, Randriantsoa A, Andriantsitohaina R, Lobstein A (2007). Anti-proliferative effect of Euphorbia stenoclada in human airway smooth muscle cells in culture. Journal of Ethnopharmacology 109(1):134-139.

9. Çatal SR (2015). Döşemelik Kumaş Üretimi (Seminer). Bursa: Uludağ Üniversitesi.
10. Dabholkar DA, Kaicker PK, Diwan RK (1991). Euphorbia latex - Its chemistry and industrial applications. Research Industry 36: 126-131.
11. Dartay M, Ateşşahin T (2010). İhtiyotoksit bitkilerin bileşiminde bulunan kimyasal maddeler ve balık avcılığında yaygın olarak kullanılması. Fırat Üniversitesi Doğu Araştırmaları Dergisi 8(2): 28-34.
12. Eren T, Aşçı A (2015). Synthesis and Characterization of phosphonate based polynorbornene polymers derived from romp (ring opening metathesis polymerization) method and investigation their flame retardant properties. Sigma Journal Engineering and Natural Sciences 33(4):615-625.
13. Ernst M, Grace OM, Saslis-Lagoudakis CH, Nilsson N, Simonsen HT, Rønsted N (2015). Global medicinal uses of Euphorbia L. (Euphorbiaceae). Journal of Ethnopharmacology 176:90-101.
14. Ersöz T (2010). Bitkisel Ürünler ve Güvenilirliği. Bitkilerle Tedavi Sempozyumu, Zeytinburnu/İstanbul Bildiri Kitabı pp.89-93.
15. Fueki T, T Makino T, Matsuoka T, Beppu M, Sunaga T, Tanaka K, Nagamine K, Namiki T (2015). Quick and easy preparation method fordecoction of Kampo formula inspired bythe method of boiling powdered crude drugsin the Song period of China. Traditional & Kampo Medicine 2(2):1-7.
16. Gallagher M, Wysocki CJ, Leyden JJ, Spielman AI, Sun X, Preti G (2008). Analyses of volatile organic compounds from human skin. British Journal of Dermatology 159(4):780-791.
17. Gaonkar O (2021). An Overvıew of Toxic Chemicals in Textiles. Technical Report-India.
18. Gupta PJ (2011). The efficacy of Euphorbia prostrata in early grades of symptomatic hemorrhoids – a pilot study. European Review for Medical and Pharmacological Sciences 15(2):199-203.
19. Gürcüm BH (2010). Dokuma kumaşların öznel algısı ile bazı fiziksel özellikleri arasındaki ilişkinin belirlenmesi. Tekstil ve Konfeksiyon 20 (2):101-108.
20. Gürhan G, Ezer N (2004). Halk arasında hemoroit tedavisinde kullanılan bitkiler-I. Hacettepe Üniversitesi Eczacılık Fakültesi Dergisi 24(1): 37-55.
21. Haba H, Lavaud C, Harkat H, Alabdul Magid A, Marcourt L, Benkhaled M (2007). Diterpenoids and triterpenoids from Euphorbia guyoniana. Phytochemistry 68(9):1255-1260.
22. Hargreaves BJ (1991). The spurges of Botswana. Botswana Notes and Records 23:115-130.
23. Hohmann J, Molnár J, Rédei D, Evanics F, Forgo P et al (2002). Discovery and biological evaluation of a new family of potent modulators of multidrug resistance: reversal of multidrug resistance of mouse lymphoma cells by new natural jatrophane diterpenoids isolated from Euphorbia species. Journal of Medicinal Chemistry 45(12):2425-31.
24. Horn WJ, van Ee BV, Morawetz JJ, Riina R, Steinmann VW et al. (2012). Phylogenetics and the evolution of major structural characters in the giant genus Euphorbia L. (Euphorbiaceae). Molecular Phylogenetics and Evolution 63 (2):305-326.
25. Horrocks AR, Kandola BK, Davies PJ, Zhang F, Padbury SA (2005). Developments in flame retardant textiles–a review. Polymer Degradation and Stability 88: 3-12.
26. Hsieh WT, Lin HY, Chen JH, Lin WC, Kuo YH et al. (2015). Latex of Euphorbia antiquorum-induced S-phase arrest via active ATM kinase and MAPK pathways in human cervical cancer HeLa cells. Environmental Toxicology 30: 1205-1215.
27. ISO 6940 (2004). Textile fabrics - Burning behaviour - Determination of ease of ignition of vertically oriented specimens.
28. Kaval I, Behcet L, Cakilcioglu U (2014). Ethnobotanical study on medicinal plants in Gecitli and its surrounding (Hakkari-Turkey). Journal of Ethnopharmacology 155(1): 171-184.
29. Koo H, Park Y (2022). Mechanical properties and dyeability of silk dyed with Euphorbia humifusa extract with addition of CNF Hydrogel. Fibers and Polymers 23: 1324-1331.
30. Kumari S, Kumar R, Kumar G (2020). Study on the modification of polyester resin bamboo fiber-based composite with euphorbia coagulum and their effect on mechanical and thermal properties. Journal of Composite Materials 54(24): 100-120.
31. Lai XZ, Yang YB, Shan XL (2004). The investigation of Euphorbiaceous medicinal plants in southern China. Economic Botany 28: 307320.
32. Lensen G, Jungbauer F, Gonçalo M, Coenraads PJ (2007). Airborne irritant contact dermatitis and conjunctivitis after occupational exposure to chlorothalonil in textiles. Contact Dermatitis 57(3):181-186.
33. Mali PY, Panchal SS (2017a). Euphorbia tirucalli L.: Review on morphology, medicinal uses, phytochemistry and pharmacological activities. Asian Pacific Journal of Tropical Biomedicine 7: 603-613.
34. Mali PY, Panchal SS (2017b). Euphorbia neriifolia L.: Review on botany, ethnomedicinal uses, phytochemistry and biological activities. Asian Pacific Journal of Tropical Biomedicine: 10 430-438.
35. Maurya AK, Tripathi S, Ahmed Z, Sahu RK (2012). Antidiabetic and antihyperlipidemic effect of Euphorbia hirta instreptozotocin induced diabetic rats. Scholars Research Library 4(2): 703-707.
36. Mwaikambo LY, Tucker N, Clark AJ (2024). Mechanical properties of hemp fibre reinforced Euphorbia composites. Macromolecular Materials and Engineering 292(9): 993-1000.
37. Ömeroğulları Başyiğit Z (2021). Application technologies for functional finishing of textile materials. In: Kumar P (ed.). Textiles for Functional Applications. London: IntechOpen, pp.1-20.
38. Önem E, Mutlu M M, Günay S, Azeri H (2012). Soğan (Allium cepa) yumru dış kabuğundan doğal boyarmadde ekstraksiyonu ve deri boyamada kullanımı. Tekstil ve Mühendislik Dergisi 19(88): 1-8.
39. Öztürk A (2021). Günlük yaşamda kimyasal madde maruziyeti ve insan sağlığına etkileri. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 9:1547-1562.
40. Rai B, Kumar G, Diwan RK, Khandal RK (2011). Study on effect of Euphorbia coagulum on physico-mechanical and fire retardant properties of polyester-banana fiber composite. Indian Journal of Science and Technology 4(4):443-446.
41. Rizk AFM (1987). The chemical constituents and economic plants of the Euphorbiaceae. Botanical Journal of the Linnean Sociely 94:293–326.
42. Salehi B, Iriti M, Vitalini S, Antolak H, Pawlikowska E et al. (2019). Euphorbia-derived natural products with potential for use in health maintenance. Biomolecules 9(8): 337-350.
43. Toprak T, Anis P (2017). Textile industry’s environmental effects and approaching cleaner production and sustainability, an overview. Journal of Textile Engineering & Fashion Technology 2(4): 429-442.
44. Topuzoğlu İ, Orhun H (1993). “Türk Tabipleri Birliği, İş Hekimliği Ders Notları”. Ankara: Türk Tabipleri Birliği Yayını.
45. Toro-Vazquez JF, Morales-Rueda JA, Dibildox-Alvarado E, Charó-Alonso M, Alonzo-Macias M, González-Chávez MM (2007).Thermal and textural properties of organogels developed by candelilla wax in shower oil. Journal of the American Oil Chemists' Society 84: 989–1000.
46. Van der Veen I, de Boer J (2012). Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis. Chemosphere 88: 1119-1153.
47. Van Sam H, Baas P, Keßler PJA (2008). Traditional medicinal plants in Ben En National Park, Vietnam. Blumea 53:569–601.
48. Vasas A, Hohmann J (2014). Euphorbia diterpenes: Isolation, structure, biological activity, and synthesis (2008-2012). Chemical Reviews 114(17) 8579-8612.
49. Velicangil S, Velicangil Ö (1987). “Endüstri Sağlığı (İşçi Sağlığı-İş Hijyeni) ve Meslek Hastalıkları”. Ankara: Çalışma Bakanlığı Yayınları.
50. Xing JB, Shui CH, Liui Y (2002). Determination of quercetin in the Herba Euphorbiae Humifusae. Zhongguo Zhong Yao Za Zhi, 27(10):758-760.
51. Zhao X (2010). Synthesis and application of a durable phosphorus/silicon flame-retardant for cotton. The Journal of The Textile Institute 101(6): 538-546.