Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi

Burçin Yıldız

doi:10.35193/bseufbd.1131538

Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi

Öz

Bu çalışma, sulardan C.I. Vat Green 1 boyar maddesinin adsorpsiyonu için mikro ölçekli sıfır değerlikli demirin (mZVI) uygulanabilirliğini göstermektedir. mZVI partikülleri SEM, EDX, BET yüzey alanı analizi ve pHzpc ile karakterize edilmiştir. Analizlerden kullanılan mZVI partiküllerinin yüzey özelliklerinde meydana gelen değişimler ise SEM ve EDX ile belirlenmiştir. 5.2 m2/g BET yüzey alanı ile yaklaşık 5 m’den küçük olan küresel partiküller, yüksek giderim verimini desteklemiştir. Analiz sonrasında partikül boyut ve şekilleri ile elementel bileşimde meydana gelen değişiklikler yüksek adsorpsiyon verimini doğruladığı gibi 5.73 olan pHzpc değeri de düşük pH’larda yüksek giderim veriminin gözlenmesini sağlamıştır. C.I. Vat Green 1’in giderim verimi ile adsorpsiyon kinetik ve izotermlerini değerlendirebilmek için çözelti pH’sı, demir dozajı, reaksiyon sıcaklığı, kirletici konsantrasyonu gibi parametreler kesikli deney serileri ile incelenmiştir. 3’ten büyük pH değerlerinde, 1 g/L’den büyük mZVI dozajlarında ve kirletici derişiminin arttığı durumlarda giderim verimi azalırken 1 g/L’ye kadar olan dozajlarda ve sıcaklık artışı ile verim artmıştır. Optimum pH, 3 ve optimum mZVI dozajı 1 g/L olarak belirlenmiştir. TOK sonuçları da giderim mekanizmasının adsorpsiyon olduğunu doğrulamıştır. Kinetik verilerin en iyi olarak pseudo ikinci dereceden modele uyduğu bulunmuştur. Adsorpsiyon denge verileri Langmuir modeli ile temsil edilmiş ve maksimum adsorpsiyon kapasitesi 36.50 mg/g olarak bulunmuştur.

Anahtar Kelimeler

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Burçin Yıldız ^*
0000-0001-9750-7278
Türkiye

Yayımlanma Tarihi

31 Mayıs 2023

Gönderilme Tarihi

16 Haziran 2022

Kabul Tarihi

13 Şubat 2023

Yayımlandığı Sayı

Yıl 2023 Cilt: 10 Sayı: 1

DOI

https://doi.org/10.35193/bseufbd.1131538

IZ

https://izlik.org/JA68CG26KX

Kaynak Göster

RIS / Bibtex

APA

Yıldız, B. (2023). Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 10(1), 54-67. https://doi.org/10.35193/bseufbd.1131538

AMA

1.Yıldız B. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2023;10(1):54-67. doi:10.35193/bseufbd.1131538

Chicago

Yıldız, Burçin. 2023. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10 (1): 54-67. https://doi.org/10.35193/bseufbd.1131538.

EndNote

Yıldız B (01 Mayıs 2023) Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10 1 54–67.

IEEE

[1]B. Yıldız, “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”, Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, c. 10, sy 1, ss. 54–67, May. 2023, doi: 10.35193/bseufbd.1131538.

ISNAD

Yıldız, Burçin. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi 10/1 (01 Mayıs 2023): 54-67. https://doi.org/10.35193/bseufbd.1131538.

JAMA

1.Yıldız B. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 2023;10:54–67.

MLA

Yıldız, Burçin. “Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi”. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, c. 10, sy 1, Mayıs 2023, ss. 54-67, doi:10.35193/bseufbd.1131538.

Vancouver

1.Burçin Yıldız. Mikro Ölçekli Sıfır Değerlikli Demir (mZVI) Partikülü ile Sulu Çözeltilerden C.I. Vat Green 1 Boyasının Gideriminin İncelenmesi. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi. 01 Mayıs 2023;10(1):54-67. doi:10.35193/bseufbd.1131538

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