Wear Behavior of Rockforce Mineral Fiber and Mica Reinforced Polyamide-6 Composite against Thermoset Polyester Composite Disc

Öz

In this study carried out for use in the electricity industry, 20 % by weight of rock wool mineral fiber and mica reinforced polyamide-6 (PA-6) thermoplastic based polymer composites were investigated against the thermoset-based composite disc surface. The aim of the study is to determine the polymer composite with better wear resistance and thermoset unsaturated polyester composite pair for the electricity sector. Tribological experiments were carried out on a pin-on-disc wear test apparatus. 40 wt.% calcium carbonate and 25wt.% long glass fiber reinforced unsaturated polyester composite material were used as a counter disc material. Tribological tests were carried out at sliding speed of 0.5 m/s and under the pressure of 0.707, 1.415, 2.123 and 3.538 MPa. As a result of the tribological studies, the lowest wear rate was obtained in PA-6 composite with 20 wt.% mica with the value of 1.98x10-14 m2/N. Mica reinforced PA-6 composite was found to be approximately 42 % less wear than rock force mineral fiber reinforced composite. As a result of the study, 20 wt.% mica reinforced PA-6 composite, which is produced for use in electrical applications, has been determined as the most suitable material to be used in electrical contact breakers with 40 wt.% calcium carbonate and 25 wt.% long glass fiber reinforced unsaturated polyester composite material.

Anahtar Kelimeler

• Rockforce mineral fiber
• Mica
• PA-6
• Tribology
• Pressure

Kaya Yünü Mineral Elyaf ve Mika Takviyeli Poliamid-6 Kompozitinin Termoset Polyester Kompozit Diske Karşı Aşınma Davranışları

Öz

Elektrik sektöründe kullanma amaçlı gerçekleştirilen bu çalışmada ağırlık olarak % 20 oranında kaya yünü mineral elyaf (KYME) ve mika takviyeli poliamid-6 (PA-6) termoplastik esaslı polimer kompozitler, termoset esaslı kompozit disk yüzeyine karşı aşınma ve sürtünme davranışları incelenmiştir. Çalışmanın amacı elektrik sektörü için aşınma direnci daha iyi olan polimer kompozit malzeme ile termoset doymamış polyester kompozit çiftini belirlemektir. Tribolojik deneyler disk üzerinde pim düzeneği bulunan bir aşınma cihazında gerçekleştirilmiştir. Karşı disk malzeme olarak ağırlık olarak % 40 kalsiyum karbonat ve % 25 oranında uzun cam elyaf takviyeli doymamış polyester kompozit malzemesi kullanılmıştır. Tribolojik testler, 0,5 m/s kayma hızında 0,707, 1,415, 2,123 ve 3,538 MPa basınç altında gerçekleştirilmiştir. Yapılan tribolojik çalışmalar sonucunda en düşük aşınma oranı 1.98x10-14 m2/N değeri ile %20 oranında mika takviyeli PA-6 kompozitinde elde edilmiştir. Mika takviyeli PA-6 kompoziti kaya yünü mineral elyaf takviyeli kompozite göre yaklaşık olarak % 42 oranında daha az aşındığı belirlenmiştir. Yapılan çalışma sonucunda elektriksel uygulamalarda kullanım amaçlı üretilen kompozit malzemelerden % 20 mika takviyeli PA-6 kompoziti ile %40 kalsiyum karbonat ve % 25 oranında uzun cam elyaf takviyeli doymamış polyester kompozit malzeme çifti elektrik kontak kesicilerde kullanılabilecek en uygun malzeme olarak tespit edilmiştir.

Anahtar Kelimeler

• Kaya yünü mineral elyaf
• Mika
• PA-6
• Triboloji
• Uygulanan basınç

Kaynakça

1. Ana, H., Susana, L., Davim, J. P. (2018). Influence of sliding velocity on the tribological behaviour of PA66GF30 and PA66 + MoS2: an analysis of morphology of sliding surface by digital image processing. Polymer Bulletin, 75, 5113-5131.
2. Pooria, K., Akbar, S. (2017). Improvement of dry sliding tribological properties of polyamide 6 using diamond nanoparticles. Tribology International, 115, 370-377.
3. Raja, V. L., Kumaravel, A. (2014). Comparative Study on the Wear Properties of Fly Ash and Silica Fume Filled Nylon Composites. Applied Mechanics and Materials, 592-594, 1277-1284.
4. Unal, H., Saylan, T., Mimaroglu, A. (2014). Thermal, mechanical and tribological performance of polymer composites rubbed against polymer composites in application in electrical contact breakers. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology. 228(6), 608-615.
5. Suryasarathi, B., Mahanwar, P. A. (2004). Effect of Particle Size of Filler on Properties of Nylon-6. Journal of Minerals & Materials Characterization & Engineering, 3(1), 23-31.
6. Kumar, S. S., Kanagaraj, G. (2016). Investıgatıon on mechanıcal performances of PA-6 and Al2O3 reınforced PA-6 polymer composıtes. International Journal of Advanced Engineering Technology, VII(I), 69-74.
7. Kulkarni, M. V., Elangovan, K., HemachandraReddy, K., Poojari, M., Harsha, S. (2015). Tribological Behaviours of CaSiO3 Reinforced PA6 Polymer–Metal Sliding Combinations under Dry Friction Conditions. Advanced Materials Manufacturing & Characterization, 5(1), 18-23.
8. Kumar, S. S., Kanagaraj, G. (2016). Investigation of Characterization and Mechanical Performances of Al2O3 and SiC Reinforced PA-6 Hybrid Composites. Journal of Inorganic and Organometallic Polymers and Materials, 26, 788-798.

9. Kumar, S. S., Kanagaraj, G. (2016). Investigation on Mechanical and Tribological Behaviours of PA6 and Graphite-Reinforced PA6 Polymer Composites. Arabian Journal for Science and Engineering, 41, 4347-4357.
10. Kim, J., Jang, H., Kim, J. (2014). Friction and wear of monolithic and glass-fiber reinforced PA66 in humid conditions. Wear, 309, 82-88.
11. Shelke, S. D., Pawar, D. S. (2017). Tribological Behaviuor of Polyamide 66 Blend with CF & PTFE. International Journal for Scientific Research & Development, 5(5), 237-242.
12. Orhan, S. A., Shaker, S. H., Ahmed, N. Al-K. (2020). Investigation of Wear Behaviour for Novel Polyamide 66 Composites under Dry Sliding Conditions. International Journal of Nano-electronics and Materials, 13(1), 9-18.
13. Ayesha, A., Islam, M. A. (2015). Wear Behaviours of Micron Size Graphite Particle Reinforced Nylon Composite. International Conference on Mechanical, Industrial and Materials Engineering 2015 (ICMIME2015), 11-13 December, 2015, RUET, Rajshahi, Bangladesh, 1-6.
14. Yi-Lan, Y., Du-Xin, L., Gao-Jie, S., Ruo-Yun, L., Xin, D. (2016). Improvement in the tribological properties of polyamide 6: Talc, glass fiber, graphite, and ultrahigh-molecular-weight polyethylene. Journal of Thermoplastic Composite Materials, 29(4), 494-507.
15. Jawali, N. D., Siddeswarappa, B., Siddaramaiah. (2006). Physico-mechanical Properties, Machinability, and Morphological Behaviour of Short Glass Fiber-reinforced Nylon 6 Composites. Journal of Reinforced Plastics and Composites, 25(13), 1409-1418.
16. Nuruzzaman, D. M., Asif Iqbal, A. K. M., Oumer, A. N., Ismail, N. M., Basri, S. (2016). Experimental investigation on the mechanical properties of glass fiber reinforced nylon. IOP Conf. Series: Materials Science and Engineering, 114, 1-7.
17. Yi-Lan, Y., Du-Xin, L., Gao-Jie, S., Ruo-Yun, L., Xin, D. (2016). Improvement in the tribological properties of polyamide 6: Talc, glass fiber, graphite, and ultrahigh-molecular-weight polyethylene. Journal of Thermoplastic Composite Materials, 29(4), 494–507.
18. Unal, H., Mimaroglu, A. (2014). Evaluation of morphological characteristics and mechanical performance of Rock-force mineral fiber- and glass fiber-reinforced polyamide-6 composites. Science and Engineering of Composite Materials, 21(3), 323-328.
19. Fahmi, A., Jawaid, M., Hassan, A., Wahit, M. U. (2013). Mechanical Properties of Mica-Filled Polycarbonate/Poly(Acrylonitrile-Butadiene-Styrene) Composites, Polymer-Plastics Technology and Engineering. Polymer-Plastics Technology and Engineering, 52, 727-736.
20. Lubomir, L., David, M., Barbora, L., Martin, V., Michal, S., Klara, C., Jakub, V., Kristian, E. W., Richard, W. G., Neil, A. R. (2018). Effect of filler particle shape on plastic-elastic mechanical behaviour of high density poly (ethylene)/mica and poly (ethylene)/wollastonite composites. Composites Part B, 141, 92-99.
21. Unal, H., Mimaroglu, A. (2012). Mechanical and Morphological Properties of Mica and Short Glass Fiber Reinforced Polyamide 6 Composites. International Journal of Polymeric Materials, 61, 834-846.
22. Gan, D., Lu, S., Caisheng, S., Zhijian, W. (2001). Mechanical properties and frictional behaviour of a mica-filled poly (aryl ether ketone) composites. European Polymer Journal, 37, 1359-1365.
23. Aljaž, P., Alja, K., Mitjan, K. (2017). Tribological properties of polyamide (PA6) in self-mated contacts and against steel as a stationary and moving body. Wear, 378–379, 17-26.
24. Said, D., S. Larbi, Ali, B. (2016). Study of the Tribological Behaviour of a Pin on Disc Type of Contact. World Academy of Science, Engineering and Technology International Journal of Mechanical and Mechatronics Engineering, 10(7), 1626-1231.
25. Krol, A., Gocman, K. (2017). The Comparatıve Study of Polymers For Slıdıng Paırs Wıth UNMT (Unıversal Nano/Mıcro Tester). Trıbologıa-Finnish Journal of Tribology, 1-2, 35, 31-39.
26. Abdessalem, K., Khaled, E. (2017). Tribological Behaviour of Wheel-Rail Contact under Different Contaminants Using Pin-On-Disk Methodology. Journal of Tribology, 139(1), 1-9.
27. Demir, Z. (2013). Tribological performance of polymer composites used in electrical engineering applications. Bulletin of Materials Science, 36(2), 341-344.
28. He, D., Jiang, B. (1993). The elastic modulus of filled composites. Journal of Applied Polymer Science, 49(4), 617-621.
29. Kukureka, S.N., Hooke, C.J., Rao, M., Liao, P., Chen, Y.K. (1999). Effect of fibre reinforcement on the friction and wear of polyamide 66 under dry rolling-sliding contact. Tribology International, 32, 107–116.
30. Unal, H., Sen, U., Mimaroglu, A. (2005). Abrasive wear behaviour of polymeric materials. Materials & Design, 26, 705–710.
31. Li, D. X., Xie, Y., Li, W. J. (2013). Tribological and mechanical behaviors of polyamide 6/glass fiber composite filled with various solid lubricants. The Scientific World Journal, 2013(5), 1-9.
32. Bowden, F.P., Tabor, D.T. (1964). Friction and lubrication of solid: Part 2. Oxford: Clarendon Pres, 1.