Determining the Optimum Application Recipe for Microcapsules of Ozonated Vegetable Oils to Save Antibacterial Activity to Textiles

Öz

This paper proposed to determine optimum application recipe for the microcapsules of the ozonated vegetable oils, in order to save the antibacterial activity to the textiles. For this aim, the olive oil was ozonated during three hours and the ozonated oil was characterized via GC and FTIR analyses and antibacterial property of the oil wasalso researched. After characterizing of the ozonated oil, it was encapsulated into Arabicgum by basic coacervation method. The microcapsules were characterized through optical microscope and FTIR analyses. Finally, in order to determine optimum application recipe for saving the antibacterial activity to textile surfaces, different application solutions were prepared and the prepared solutions applied to the cotton fabrics by padding method. After applications,the SEM images of the fabrics were investigated and the antibacterial efficiencies of samples were also quantitatively evaluated by the ASTM 2149 01 against Escherichia coli. The results of the study showed that the ozone could easily react with the double bonds of the olive oils and the antibacterial properties of the olive oil improved. The ozonated olive oil was able to be microcapsulated with basic coacervation method, successfully. In addition, the optimum application recipe for the microcapsules of the ozonated vegetable oils could be determined.

Anahtar Kelimeler

• Ozonated vegetable oil,Microcapsule

Tekstil Yüzeylerine Antibakteriyel Aktivite Kazandırmak için OzonlanmıŞ Bitkisel Yağ Mikrokapsüllerinin Aktarılacağı En Uygun Aplikasyon Reçetesinin Belirlenmesi

Öz

Bu makale, tekstil yüzeylerine antibakteriyel aktivite kazandırılmak için ozonlanmış bitkisel yağ mikrokapsüllerinin aktarılacağı en uygun aplikasyon reçetesini belirlemeyi amaçlamıştır. Bu amaçla zeytin yağı 3 saat ozonlanmış ve ozonlanmış yağ GC ve FTIR analizleri ile karakterize edilmiştir, aynı zamanda yağın antibakteriyel özelliği araştırılmıştır. Karakterizasyon sonrası ozonlanmış yağ, basit koaservasyon yöntemi ile Arap zamkı içine enkapsüle edilmiştir. Hazırlanan mikrokapsüller optik mikroskop ve FTIR analizleri ile karakterize edilmiştir. Son olarak, tekstil yüzeylerine antibakteriyel aktivite kazandıracak optimum aplikasyon reçetesinin belirlenebilmesi amacıyla, farklı aplikasyon çözeltileri hazırlanmış ve hazırlanan çözeltiler pamuklu kumaşlara emdirme yöntemi ile aplike edilmiştir. Aplikasyon sonrası kumaşların SEM görüntüleri incelenmiş ve E.coli bakterisine karşı antibakteriyel etkinliği ASTM E 2149 01 standardına göre kantitatif olarak değerlendirilmiştir. Sonuçlar, ozonun zeytinyağındaki çift bağlarla kolaylıkla reaksiyona girebildiğini ve yağın antibakteriyel aktivitesini geliştirdiğini göstermiştir. Ozonlanmış yağ basit koaservasyon yöntemi ile başarılı bir şekilde kapsüllenebilmiştir. Ayrıca, ozonlanmış bitkisel yağ mikrokapsülleri için optimum aplikasyon reçetesi belirlenebilmiştir.

Anahtar Kelimeler

• Ozonlanmış bitkisel yağ,Mikrokapsül,Aplikasyon,Antibakteriyel aktivite,Tekstil

Kaynakça

1. 1. Valacchi, G., Lim Y., Belmonte G., Miracco C., Zanardi I., Bocci V., Travagli V., 2011. Ozonated Sesame Oil Enhances Cutaneous Wound Healing in SKH1 Mice, Wound Repair and Regeneration, vol. 19(1), pp. 107-115.
2. 2. Babucçu, O., 2011. Ozone Therapy: Myth and Fact, Original Research, Turk Plast Surg., vol. 19(3), pp. 105-112.
3. 3. Sakazaki, F., Kataoka, H., Okuno, T., Ueno, H., Semma, M., Ichikawa, A., Nakamuro, K., 2007. Ozonated Olive Oil Enhances the Growth of Granulation Tissue in a Mouse Model of Pressure Ulcer, Ozone: Science & Engineering, vol. 29, pp. 503-507.
4. 4. Zamora, Z., Gonzalez, R., Guanche, D., Merino, N., Menendez, S., Hernandez, F., Alonso, Y., Schulz, S., 2008. Ozonized Sunflower Oil Reduces Oxidative Damage Induced by Indomethacin in Rat Gastric Mucosa, Inflammation Research, vol. 57, pp. 39-43.
5. 5. Lezcano, I., Nuflez, N., Espino, M., Gomez, M., 2000. Antibacterial Activity of Ozonized Sunflower Oil, Oleozon, Against Staphylococcus Aureus and Staphylococcus Epidermidis, Ozone Science & Engineering, vol. 22, pp. 207-214.
6. 6. Sechi, L.A., Lezcano, I., Nunez, N., Espim, M., Dupre, I., Pinna, A., Molicotti, P., Fadda, G., Zanetti, S., 2001. Antibacterial Activity of Ozonized Sunflower Oil (Oleozon), Journal of Applied Microbiology, vol. 90, pp. 279-284.
7. 7. Menendez, S., Falcon, L., Simon, D.R., Landa, N., 2002. Efficacy of Ozonized Sunflower Oil in the Treatment of Tinea Pedis, Mycoses, vol. 45, pp. 329-332.
8. 8. Diaz, M.F., Gavin, J.A., Gomez, M., Curtielles, V., Hernandez, F., 2006. Study of Ozonated Sunflower Oil using H NMR and Microbiological Analysis, Ozone: Science & Engineering, vol. 28, pp. 59-63.

9. 9. Torres, I.F., Pinol, V.C., Urritia, E.S., Regueiferos, M.G., 2006. In vitro Antimicrobial Activity of Ozonized Theobroma Oil Against Candida Albicans, Ozone: Science & Engineering, vol. 28, pp. 187-190.
10. 10. Sancar Beşen, B., Balcı, O., Orhan, M., Güneşoğlu, C., Tatlı, İ.İ., 2015. An Investigation on Antibacterial Activities of Nonwovens Treated with Ozonated Oils, The Journal of Textiles and Engineer, vol. 22 (100), pp. 25-31.
11. 11. Karthikeyan, M., Ramachandran, T., Shanmugasundaram, O.L., 2014. Synthesis, Characterization and Development of Thermally Enhanced Cotton Fabric Using Nanoencapsulated Phase Change Materials Containing Paraffin Wax, The Journal of The Textile Institute, DOI: 10.1080/00405000. 2014.886368.
12. 12. Sancar Beşen, B., 2016. Producing of Microcapsules Including Ozonated Vegetable Oils and Applying them to Textile Surfaces, PhD Thesis, Kahramanmaraş Sütçü İmam University, Kahramanmaraş, pp. 63-148.
13. 13. Özyıldız, F., Karagönüllü, S., Basal, G., Uzel, A., Bayraktar, O., 2012. Micro-encapsulation of Ozonated Red Pepper Seed Oil with Antimicrobial Activity and Application to Nonwoven Fabric, The Society for Applied Microbiology, Letters in Applied Microbiology, vol. 56, pp. 168-179.
14. 14. Zanardi, I., Travagli, V., Gabbrielli, A., Chiasserini, L., Bocci, V., 2008. Physico-Chemical Characterization of Sesame Oil Derivatives, Lipids, vol. 43, pp. 877–886.
15. 15. Almeida, N.R., Beatriz, A., Micheletti, A.C., Arruda, E.J., 2012. Ozonized Vegetable Oils and Therapeutic Properties: A Review, Orbital Electronic Journal of Chemistry, vol. 4 (4), pp. 313-326.