Reyhanlı’da (Hatay, Türkiye) Yeraltı Suyunun Çok Boyutlu Değerlendirmesi: Hidrojeokimya, Sulama Uygunluğu ve Sağlık Riski Değerlendirmesi

Öz

Yeraltı suyu kurak ve yarı kurak bölgelerde içme, sulama ve endüstriyel uygulamalar için değerli bir kaynaktır. Yeraltı suyu kalitesi, hem insan tüketimi hem de tarımsal sulama için izlenmesi gereken önemli bir konudur. Ancak, Türkiye'nin güneyinde yer alan Hatay ilinin Reyhanlı ilçesinde yeraltı suyu kalitesi, yeraltı suyunun sulama için uygunluğu ve insan sağlığı için risk değerlendirmesi yeterince araştırılmamıştır. Bu çalışmada, ilk kez Reyhanlı ilçesindeki yeraltı sularının kimyasal bileşimi, kimyasal bileşimini kontrol eden faktörler/mekanizmalar, sulama için uygunluğunun yanı sıra yeraltı suyundaki metal(oid)lerin yetişkinler ve çocuklar üzerindeki kanserojen olmayan sağlık riski belirlenmiştir. Yeraltı sularında pH, elektriksel iletkenlik (EC), toplam çözünmüş katı madde (TDS) değerlerinin yanı sıra majör iyonlar, bor ve çeşitli metal(oid)lerin (As, Al, Fe, Mn, Ni, Cr, Cu, Co, Cd, Pb, Zn) konsantrasyonları belirlenmiştir. Piper diyagramı, Gibbs diyagramı ve kloroalkali indeksleri sırasıyla yeraltı suyunun hidrokimyasal fasiyeslerini, yeraltı suyu kimyasını kontrol eden ana mekanizmaları ve iyon değişim sürecinin yönünü belirlemek için kullanılmıştır. Yeraltı suyunun sulama için uygunluğu SAR, Na%, SSP, RSC, MH, PI, PS ve KR indisleri hesaplanarak araştırılmıştır. Ayrıca, yeraltı suyunun sulama için uygunluğu Amerika Birleşik Devletleri Tuzluluk Laboratuvarı diyagramı ve Wilcox diyagramı kullanılarak değerlendirilmiştir. Ağırlıklı aritmetik su kalitesi indeksine (WAWQI) göre, tüm yeraltı suları “mükemmel” olarak sınıflandırılmıştır. Tüm yeraltı suyu örneklerindeki metal(oid)lerin seviyeleri WHO'nun içme suyu kılavuz değerleriyle uyumludur. Sağlık risk değerlendirmesinin sonuçları, hem yetişkinler hem de çocuklar için tehlike katsayılarının ve tehlike indeksinin 1’den düşük olduğunu göstermiştir; bu da yeraltı suyunun sağlık riski oluşturmadığını göstermektedir.

Anahtar Kelimeler

• Yeraltı Suyu
• Sulama
• Içme Suyu
• Su Kalitesi Indeksi
• Tehlike Indeksi
• Sağlık Riski

Multidimensional Assessment of Groundwater in Reyhanlı (Hatay, Türkiye): Hydrogeochemistry, Irrigation Suitability and Health Risk Assessment

Öz

Groundwater is a valuable resource for drinking, irrigation, and industrial applications in arid and semi-arid regions. Groundwater quality is an important issue that should be monitored for both human consumption and agricultural irrigation. However, groundwater quality, suitability of groundwater for irrigation, and its risk assessment for human health in the Reyhanlı district of Hatay province, located in southern Türkiye, have not been sufficiently investigated. In this study, for the first time, the chemical composition of groundwater in the Reyhanlı district, the factors/mechanisms controlling its composition, its suitability for irrigation, as well as the non-carcinogenic health risks of metal(loid)s in the groundwater for adults and children were determined. The pH, electrical conductivity (EC), total dissolved solids (TDS) values, as well as concentrations of major ions, boron, and various metal(loid)s (As, Al, Fe, Mn, Ni, Cr, Cu, Co, Cd, Pb, Zn) in groundwater were determined. Piper diagram, Gibbs diagram, and chloroalkaline indices were used to determine the hydrochemical facies of groundwater, the main mechanisms controlling groundwater chemistry, and the direction of the ion exchange process, respectively. The suitability of groundwater for irrigation was investigated by calculating SAR, Na%, SSP, RSC, MH, PI, PS, and KR indices. In addition, the suitability of groundwater for irrigation was assessed using the United States Salinity Laboratory (USSL) diagram and the Wilcox diagram. According to the Weighted Arithmetic Water Quality Index (WAWQI), all groundwater was classified as “excellent”. The levels of metal(loid)s in all groundwater samples comply with the WHO guideline values for drinking water. The results of the health risk assessment have shown that the hazard quotients and hazard index are less than 1 for both adults and children, indicating that the groundwater does not pose a health risk.

Anahtar Kelimeler

• Groundwater
• Irrigation
• Drinking Water
• Water Quality Index
• Hazard Index
• Health Risk

Kaynakça

1. Batarseh M, Imreizeeq E, Tilev S, Al Alaween M, Suleiman W, Al Remeithi AM, et al. Assessment of groundwater quality for irrigation in the arid regions using irrigation water quality index (IWQI) and GIS-Zoning maps: Case study from Abu Dhabi Emirate, UAE. Groundw Sustain Dev 2021;14:100611. https://doi.org/10.1016/j.gsd.2021.100611.
2. Li Z, Lu C, Zhang Y, Wu C, Liu B, Shu L. Mechanisms of evolution and pollution source identification in groundwater quality of the Fen River Basin driven by precipitation. Science of The Total Environment 2024;952:175893. https://doi.org/10.1016/j.scitotenv.2024.175893.
3. Pandey S, Mohapatra G, Arora R. Groundwater quality, human health risks and major driving factors in arid and semi-arid regions of Rajasthan, India. J Clean Prod 2023;427:139149. https://doi.org/10.1016/j.jclepro.2023.139149.
4. Sheng D, Meng X, Wen X, Wu J, Yu H, Wu M, et al. Hydrochemical characteristics, quality and health risk assessment of nitrate enriched coastal groundwater in northern China. J Clean Prod 2023;403:136872. https://doi.org/10.1016/j.jclepro.2023.136872.
5. Ghosh A, Bera B. Hydrogeochemical assessment of groundwater quality for drinking and irrigation applying groundwater quality index (GWQI) and irrigation water quality index (IWQI). Groundw Sustain Dev 2023;22:100958. https://doi.org/10.1016/j.gsd.2023.100958.
6. Prapanchan VN, Subramani T, Karunanidhi D, Gopinathan P. Groundwater quality assessment for drinking and irrigation purposes and its human health risks in the Sevathur mine region, south India. Desalination Water Treat 2024;320:100883. https://doi.org/10.1016/j.dwt.2024.100883.
7. Eekhout JPC, Delsman I, Baartman JEM, van Eupen M, van Haren C, Contreras S, et al. How future changes in irrigation water supply and demand affect water security in a Mediterranean catchment. Agric Water Manag 2024;297:108818. https://doi.org/10.1016/j.agwat.2024.108818.
8. Hussein EE, Derdour A, Zerouali B, Almaliki A, Wong YJ, Ballesta-de los Santos M, et al. Groundwater Quality Assessment and Irrigation Water Quality Index Prediction Using Machine Learning Algorithms. Water (Basel) 2024;16:264. https://doi.org/10.3390/w16020264.

9. Dao PU, Heuzard AG, Le TXH, Zhao J, Yin R, Shang C, et al. The impacts of climate change on groundwater quality: A review. Science of The Total Environment 2024;912:169241. https://doi.org/10.1016/j.scitotenv.2023.169241.
10. Kavurmacı M, Karakuş CB. Evaluation of Irrigation Water Quality by Data Envelopment Analysis and Analytic Hierarchy Process-Based Water Quality Indices: the Case of Aksaray City, Turkey. Water Air Soil Pollut 2020;231:55. https://doi.org/10.1007/s11270-020-4427-z.
11. Tanvir Rahman MATM, Saadat AHM, Islam MdS, Al-Mansur MdA, Ahmed S. Groundwater characterization and selection of suitable water type for irrigation in the western region of Bangladesh. Appl Water Sci 2017;7:233–43. https://doi.org/10.1007/s13201-014-0239-x.
12. M’nassri S, El Amri A, Nasri N, Majdoub R. Estimation of irrigation water quality index in a semi-arid environment using data-driven approach. Water Supply 2022;22:5161–75. https://doi.org/10.2166/ws.2022.157.
13. Li X, Huang X, Zhang Y. Spatio-temporal analysis of groundwater chemistry, quality and potential human health risks in the Pinggu basin of North China Plain: Evidence from high-resolution monitoring dataset of 2015–2017. Science of The Total Environment 2021;800:149568. https://doi.org/10.1016/j.scitotenv.2021.149568.
14. Hwang JY, Park S, Kim H-K, Kim M-S, Jo H-J, Kim J-I, et al. Hydrochemistry for the Assessment of Groundwater Quality in Korea. J Agric Chem Environ 2017;6:1–29. https://doi.org/10.4236/jacen.2017.61001.
15. Madhav S, Ahamad A, Kumar A, Kushawaha J, Singh P, Mishra PK. Geochemical assessment of groundwater quality for its suitability for drinking and irrigation purpose in rural areas of Sant Ravidas Nagar (Bhadohi), Uttar Pradesh. Geology, Ecology, and Landscapes 2018;2:127–36. https://doi.org/10.1080/24749508.2018.1452485.
16. Shankar K, Aravindan S, Rajendran S. Hydrochemical profile for assessing the groundwater quality of Paravanar River Sub-Basin, Cuddalore District, Tamil Nadu, India. Current World Environment 2011;6:45–52. https://doi.org/10.12944/CWE.6.1.05.
17. Saha A, Pal SC, Islam ARMdT, Islam A, Alam E, Islam MdK. Hydro-chemical based assessment of groundwater vulnerability in the Holocene multi-aquifers of Ganges delta. Sci Rep 2024;14:1265. https://doi.org/10.1038/s41598-024-51917-8.
18. Dimple, Singh PK, Kothari M, Yadav KK, Bhakar SR. Groundwater quality analysis using different water quality indices in the hard rock aquifer region in semi-arid environment. Water Supply 2023;23:2727–44. https://doi.org/10.2166/ws.2023.150.
19. Yu D, Deng J, Jiang Q, Liu H, Yu C, Ma H, et al. Evaluation of groundwater quality with multi-source pollution based on source identification and health risks. Science of The Total Environment 2024;949:175064. https://doi.org/10.1016/j.scitotenv.2024.175064.
20. Elemile OO, Ibitogbe EM, Okikiola BT, Ejigboye PO. Groundwater quality using indices for domestic and irrigation purposes in Akure, Nigeria. Results in Engineering 2022;13:100347. https://doi.org/10.1016/j.rineng.2022.100347.
21. Kumar PM, Kumar SA, Pradeep T, Suresh M, Ramesh S. Assessment of the groundwater quality for irrigation purposes in Rasipuram Taluk, Tamilnadu, India. Asian J Res Soc Sci Humanit 2016;6:547. https://doi.org/10.5958/2249-7315.2016.01033.9.
22. Das R, Das M, Pradhan AA, Goswami S. Hydrogeochemistry of Banki Subdivision, Cuttack District Orissa. Utkal University: 2011, p. 18–28.
23. Mahmoudi N, Nakhaei M, Porhemmat J. Assessment of hydrogeochemistry and contamination of Varamin deep aquifer, Tehran Province, Iran. Environ Earth Sci 2017;76:370. https://doi.org/10.1007/s12665-017-6698-2.
24. Al Chalabi AS. A Review of different methods used to compute the drinking water quality index. International Journal of Advances in Scientific Research and Engineering 2024;10:86–93.
25. Sarwar S, Ahmmed I, Mustari S, Shaibur MR. Use of weighted arithmetic water quality index (wawqi) to determine the suitability of groundwater of Chaugachcha and Manirampur Upazila, Jashore, Bangladesh. Environmental and Biological Research 2020;2:37–48.
26. Lencha SM, Tränckner J, Dananto M. Assessing the water quality of Lake Hawassa Ethiopia—Trophic state and suitability for anthropogenic uses—Applying Common Water Quality Indices. Int J Environ Res Public Health 2021;18:8904. https://doi.org/10.3390/ijerph18178904.
27. Karim MA, Uddin MH, Barua S, Nath B, Chowdhury AI, Hoque MdA, et al. Pollution source identification of halda river water using field observation, laboratory analysis and GIS technique. Oriental Journal Of Chemistry 2019;35:1480–90. https://doi.org/10.13005/ojc/350502.
28. Ram A, Tiwari SK, Pandey HK, Chaurasia AK, Singh S, Singh Y V. Groundwater quality assessment using water quality index (WQI) under GIS framework. Appl Water Sci 2021;11:46. https://doi.org/10.1007/s13201-021-01376-7.
29. Yılmaz D, Aras E, Vaheddoost B. A statistical assessment of drinking water quality: a case study of doburca treatment plant, Bursa. Fırat Üniversitesi Mühendislik Bilimleri Dergisi 2024;36:167–78. https://doi.org/10.35234/fumbd.1316569.
30. Ghaderpoori M, Najafpoor AA, Ghaderpoury A, Shams M. Data on fluoride concentration and health risk assessment of drinking water in Khorasan Razavi province, Iran. Data Brief 2018;18:1596–601. https://doi.org/10.1016/j.dib.2018.04.045.
31. Waqas H, Shan A, Khan YG, Nawaz R, Rizwan M, Rehman MS-U-, et al. Human health risk assessment of arsenic in groundwater aquifers of Lahore, Pakistan. Human and Ecological Risk Assessment: An International Journal 2017;23:836–50. https://doi.org/10.1080/10807039.2017.1288561.
32. USEPA. Risk Assessment Guidance for Superfund Volume I, Human Health Evaluation Manual (Part A) 1989;EPA/540/1-89/002.
33. Shahmirnoori A, Hasani Zonoozi M, Samadi M. Evaluating groundwater quality using health risk assessment and irrigation indexes: Saveh Aquifer, Iran. Water Pract Technol 2023;18:3333–46. https://doi.org/10.2166/wpt.2023.216.
34. Zheng X, Zhao W, Yan X, Shu T, Xiong Q, Chen F. Pollution characteristics and health risk assessment of airborne heavy metals collected from Beijing Bus Stations. Int J Environ Res Public Health 2015;12:9658–71. https://doi.org/10.3390/ijerph120809658.
35. Berhe BA, Çelik M, Dokuz UE. Investigation of irrigation water quality of surface and groundwater in the Kütahya plain, Turkey. Bulletin of the Mineral Research and Exploration 2015;150:145–62. https://doi.org/10.19111/bmre.95431.
36. Piper AM. A graphic procedure in the geochemical interpretation of water‐analyses. Eos, Transactions American Geophysical Union 1944;25:914–28. https://doi.org/10.1029/TR025i006p00914.
37. Atasoy A, Geçen R. Salinization problem in soil of Reyhanlı district. Türk Coğrafya Dergisi 2014;0:21–8. https://doi.org/10.17211/tcd.14463.
38. Adimalla N, Li P. Occurrence, health risks, and geochemical mechanisms of fluoride and nitrate in groundwater of the rock-dominant semi-arid region, Telangana State, India. Human and Ecological Risk Assessment: An International Journal 2019;25:81–103. https://doi.org/10.1080/10807039.2018.1480353.
39. Yu N, Lv Y, Liu G, Zhuang F, Wang Q. Spatial–temporal changes in shallow groundwater quality with human health risk assessment in the Luxi Plain (China). Water (Basel) 2023;15:4120. https://doi.org/10.3390/w15234120.
40. Marghade D, Malpe DeepakB, Duraisamy K, Patil PD, Li P. Hydrogeochemical evaluation, suitability, and health risk assessment of groundwater in the watershed of Godavari basin, Maharashtra, Central India. Environmental Science and Pollution Research 2021;28:18471–94. https://doi.org/10.1007/s11356-020-10032-7.
41. Kaur T, Bhardwaj R, Arora S. Assessment of groundwater quality for drinking and irrigation purposes using hydrochemical studies in Malwa region, southwestern part of Punjab, India. Appl Water Sci 2017;7:3301–16. https://doi.org/10.1007/s13201-016-0476-2.
42. Mohamed A, Asmoay A, Alshehri F, Abdelrady A, Othman A. Hydro-geochemical applications and multivariate analysis to assess the water–rock interaction in arid environments. Applied Sciences 2022;12:6340. https://doi.org/10.3390/app12136340.
43. Schoeller H. Geochemistry of groundwater. Groundwater studies—an international guide for research and practice. UNESCO 1977:1–18.
44. Wen Y, Qiu J, Cheng S, Xu C, Gao X. Hydrochemical evolution mechanisms of shallow groundwater and its quality assessment in the estuarine coastal zone: a case study of Qidong, China. Int J Environ Res Public Health 2020;17:3382. https://doi.org/10.3390/ijerph17103382.
45. Karakoyun M, Öztürk Erdem S. The effect of different irrigation water ph on root and shoot development in mulberry green cuttings. ISPEC Journal of Agricultural Sciences 2023;7:255–62.
46. Guimarães J de J, Sousa FGG de, Román RMS, Dal Pai A, Rodrigues SA, Sarnighausen VCR. Effect of irrigation water pH on the agronomic development of hops in protected cultivation. Agric Water Manag 2021;253:106924. https://doi.org/10.1016/j.agwat.2021.106924.
47. Schiavon M, Moore KK. How to properly read your irrigation water analysis for turf and landscape: ENH1352 EP616. EDIS 2021;2021. https://doi.org/10.32473/edis-ep616-2021.
48. Hakami RA, Naser RamzySM, El-Bakkali M, Othman MDM, Yahya MS, Raweh S, et al. Groundwater quality deterioration evaluation for irrigation using several indices and geographic information systems: A case study. Desalination Water Treat 2024;320:100645. https://doi.org/10.1016/j.dwt.2024.100645.
49. Marandi A, Polikarpus M, Jõeleht A. A new approach for describing the relationship between electrical conductivity and major anion concentration in natural waters. Applied Geochemistry 2013;38:103–9. https://doi.org/10.1016/j.apgeochem.2013.09.003.
50. Yavuz D, Kılıç E, Seymen M, Dal Y, Kayak N, Kal Ü, et al. The effect of irrigation water salinity on the morph-physiological and biochemical properties of spinach under deficit irrigation conditions. Sci Hortic 2022;304:111272. https://doi.org/10.1016/j.scienta.2022.111272.
51. Hussain Z, Khattak RA, Irshad M, Mahmood Q, An P. Effect of saline irrigation water on the leachability of salts, growth and chemical composition of wheat (Triticum aestivum L.) in saline-sodic soil supplemented with phosphorus and potassium. J Soil Sci Plant Nutr 2016;16:604–20. https://doi.org/10.4067/S0718-95162016005000031.
52. Republic of Türkiye Reyhanlı District Governorship. www.reyhanli.gov.tr 2025.
53. Machado R, Serralheiro R. Soil Salinity: Effect on vegetable crop growth. management practices to prevent and mitigate soil salinization. Horticulturae 2017;3:30. https://doi.org/10.3390/horticulturae3020030.
54. WHO. Total dissolved solids in Drinking-water background document for development of WHO Guidelines for Drinking-water Quality 2003;WHO/SDE/WSH/03.04/16.
55. Badmus BS, Ozebo VC, Idowu OA, Ganiyu SA, Olurin OT. Groundwater assessment of hand dug wells around open landfill in ibadan metropolis for domestic and irrigation purposes. J Water Resour Prot 2014;06:1412–24. https://doi.org/10.4236/jwarp.2014.615130.
56. Narsimha A, Sudarshan V, Swathi P. Groundwater and Its assessment for Irrigation purpose in Hanmakonda Area, Warangal District, Andhra Pradesh, India. International Journal of Research in Chemistry and Environment 2013;3:196–200.
57. Rhoades JD, Kandiah A, Mashali AM. The use of saline waters for crop production - FAO irrigation and drainage paper 48 1992.
58. Ravikumar P, Prakash KL, Somashekar RK. Evaluation of water quality using geochemical modeling in the Bellary Nala Command area, Belgaum district, Karnataka State, India. Carbonates Evaporites 2013;28:365–81. https://doi.org/10.1007/s13146-012-0124-3.
59. Wilcox L V. Classification and Use of Irrigation Waters. US Department of Agriculture 1955;Circular 969:Washington DC.
60. Abualhaija M, Mohammad A-H. Assessing water quality of Kufranja Dam (Jordan) for drinking and irrigation: application of the water quality index. Journal of Ecological Engineering 2021;22:159–75. https://doi.org/10.12911/22998993/141531.
61. Robbins CW, Meyer WS, Prathapar SA, White RJG. Understanding salt and sodium in soils, irrigation water and shallow groundwaters a companion to the software program, SWAGMAN®-Whatif. Division of Water Resources Seeking Solutions Water Resources Series No. 4, 1991.
62. Wiesman Z. Biotechnologies for intensive production of olives in desert conditions. Desert Olive Oil Cultivation Advanced Biotechnologies, Elsevier; 2009, p. 87–133. https://doi.org/10.1016/B978-0-12-374257-5.00006-3.
63. Amwele HR, Kgabi NA, Kandjibi LI. Sustainability of groundwater for irrigation purposes in semi-arid parts of Namibia. Frontiers in Water 2021;3:767496. https://doi.org/10.3389/frwa.2021.767496.
64. Sajil Kumar PJ, Elango L, James EJ. Assessment of hydrochemistry and groundwater quality in the coastal area of South Chennai, India. Arabian Journal of Geosciences 2014;7:2641–53. https://doi.org/10.1007/s12517-013-0940-3.
65. Rawat KS, Singh SK, Gautam SK. Assessment of groundwater quality for irrigation use: a peninsular case study. Appl Water Sci 2018;8:233. https://doi.org/10.1007/s13201-018-0866-8.
66. Kumari D, Ranpariya KB, Davara MA, Polara J V. Soil properties as influenced by use of irrigation water having variable RSC and different varieties of groundnut (Arachis hypogea L.). International Journal of Agricultural Sciences 2022;18:780–5. https://doi.org/10.15740/has/ijas/18.2/780-785.
67. Diedhiou M, Cisse Faye S, Diouf OC, Faye S, Wohnlich S. groundwater quality assessment in a coastal sand aquifer: implications for drinking water and agricultural use. Research Journal of Applied Sciences, Engineering and Technology 2014;8:585–94. https://doi.org/10.19026/rjaset.8.1009.
68. Abdulhussein FM. Hydrochemical Assessment of groundwater of Dibdibba Aquifer in Al-Zubair Area, Basra, South of Iraq and its suitability for irrigation purposes. Iraqi Journal of Science 2018;59:135–43. https://doi.org/10.24996/ijs.2018.59.1A.15.
69. Kelly WP. Use of saline irrigation water. Soil Sci 1963;95:385–91.
70. Doneen LD. Notes on water quality in agriculture. Water Science and Engineering, University of California, Davis 1964.
71. Mokhtar A, Elbeltagi A, Gyasi-Agyei Y, Al-Ansari N, Abdel-Fattah MK. Prediction of irrigation water quality indices based on machine learning and regression models. Appl Water Sci 2022;12:76. https://doi.org/10.1007/s13201-022-01590-x.
72. Doneen LD. Salination of soil by salts in the irrigation water. Transactions, American Geophysical Union 1954;35:943–50.
73. Rehman N ur, Ali W, Muhammad S, Tepe Y. Evaluation of drinking and irrigation water quality, and potential risks indices in the Dera Ismail Khan district, Pakistan. Kuwait Journal of Science 2024;51:100150. https://doi.org/10.1016/j.kjs.2023.11.001.
74. Tas İ, Yeter T, Ozkay F, Gorgisen C, Cosge B. Effects of high boron containing irrigation waters on plant characteristics of basil (Ocimum Basilicum L.). Journal of Agricultural Faculty of Gaziosmanpasa University 2016;33:46–46. https://doi.org/10.13002/jafag1121.
75. Halder A, Poddar R, Dey A, Kundu R, Patra SK. Frequency of irrigation and boron on growth, yield, water use efficiency and economics of summer green gram in humid sub-tropical climate. Commun Soil Sci Plant Anal 2022;53:180–98. https://doi.org/10.1080/00103624.2021.1984514.
76. Niaz A, Sultana S, Majeed A, Aslam A, Wakeel A, Ehsan-ul-Haq, et al. Boron concentration in irrigation water used for wheat-cotton cropping system in alkaline calcareous soils of southern Punjab. Science Letters 2018;6:6–12.
77. Cömert A, Kale Çelik S. Determination of Effects on bean yield of irrigation water boron level under different soil textures. Harran Tarım ve Gıda Bilimleri Dergisi 2017;21:323–31. https://doi.org/10.29050/harranziraat.339349.
78. Rékási M, Ragályi P, Füzy A, Uzinger N, Dobosy P, Záray G, et al. Effect of the Boron Concentration in Irrigation Water on the Elemental Composition of Edible Parts of Tomato, Green Bean, Potato, and Cabbage Grown on Soils With Different Textures. Front Plant Sci 2021;12. https://doi.org/10.3389/fpls.2021.658892.
79. Vera A, Bastida F, Patiño-García M, Moreno JL. The effects of boron-enriched water irrigation on soil microbial community are dependent on crop species. Applied Soil Ecology 2023;181:104677. https://doi.org/10.1016/j.apsoil.2022.104677.
80. Connery E. Boron in Irrigation Water. UC Master Gardener Program of Contra Costa County, The University of California 2011.
81. Ayers RS, Westcot DW. Water quality for agriculture FAO irrigation and drainage paper 29 Rev. 1. Food and Agriculture Organization of the United Nations, Rome 1985.
82. Bichi MH, Bello UF. Heavy metal pollution in surface and ground waters used for irrigation along River Tatsawarki in the Kano, Nigeria. IOSR Journal of Engineering 2013;3:1–9. https://doi.org/10.9790/3021-03830109.
83. Madera CA, Silva J, Mara DD, Torres P. Wastewater use in agriculture: Irrigation of sugar cane with effluents from the Cañaveralejo wastewater treatment plant in Cali, Colombia. Environ Technol 2009;30:1011–5. https://doi.org/10.1080/09593330903020498.
84. Nik Abdul Ghani NR, Jami MS, Alam MZ. The role of nanoadsorbents and nanocomposite adsorbents in the removal of heavy metals from wastewater: A review and prospect. Pollution 2021;7:153–79.
85. Batvari BPD, Surendran A. Assessment of heavy metal contamination in Chemberambakkam lake water, Chennai, Tamil Nadu, India. J Chem Pharm Res 2015;7:865–9.
86. Gautam D, Vaid U, Khaki QZ. Suitability evaluation of groundwater for drinking and agriculture purpose in Una District, Himachal Pradesh (India). IOP Conf Ser Earth Environ Sci 2023;1110:012019. https://doi.org/10.1088/1755-1315/1110/1/012019.
87. Balamurugan P, Kumar PS, Shankar K, Nagavinothini R, Vijayasurya K. Non-carcinogenic risk assessment of groundwater in southern part of salem district in tamilnadu, india. Journal of the Chilean Chemical Society 2020;65:4697–707. https://doi.org/10.4067/S0717 97072020000104697.
88. Xu B, Zhou T, Kuang C, Wang S, Liao C, Liu J, et al. Water quality assessment in a large plateau lake in China from 2014 to 2021 with machine learning models: Implications for future water quality management. Science of The Total Environment 2024;946:174212. https://doi.org/10.1016/j.scitotenv.2024.174212.
89. Sang C, Tan L, Cai Q, Ye L. Long-term (2003−2021) evolution trend of water quality in the Three Gorges Reservoir: an evaluation based on an enhanced water quality index. Science of The Total Environment 2024;915:169819. https://doi.org/10.1016/j.scitotenv.2023.169819.
90. Mohseni U, Pande CB, Chandra Pal S, Alshehri F. Prediction of weighted arithmetic water quality index for urban water quality using ensemble machine learning model. Chemosphere 2024;352:141393. https://doi.org/10.1016/j.chemosphere.2024.141393.
91. Şener Ş, Şener E, Davraz A. Evaluation of water quality using water quality index (WQI) method and GIS in Aksu River (SW-Turkey). Science of The Total Environment 2017;584–585:131–44. https://doi.org/10.1016/j.scitotenv.2017.01.102.
92. Nawaz R, Nasim I, Irfan A, Islam A, Naeem A, Ghani N, et al. Water quality index and human health risk assessment of drinking water in selected urban areas of a mega city. Toxics 2023;11:577. https://doi.org/10.3390/toxics11070577.