Eu (III) 'un Narcissus Tazetta L. Yaprak Tozu Üzerine Biyosorpsiyonu

Yıl 2019, Cilt: 21 Sayı: 63, 955 - 966, 20.09.2019

Süleyman İnan , Bekir Özkan

https://doi.org/10.21205/deufmd.2019216324

Cited By: 1

Öz

Bu
çalışmada, yeni bir biyosorbent olan Narcissus
Tazetta L. yaprak tozunun sulu çözeltilerden Eu(III) iyonlarının
ayrılmasında biyosorpsiyon davranışları incelenmiştir. Eu(III) alımında temas
süresi, başlangıç pH’sı, başlangıç Eu(III) derişimi, biyosorbent dozajı ve
sıcaklık gibi çeşitli parametrelerin etkisini incelemek için kesikli denemeler
yürütülmüştür. Biyosorpsiyon prosesi hızlıdır ve 30 dakikalık temas süresi
sonunda dengeye ulaşılmıştır. pH 4-7 aralığında materyalin Eu(III) için önemli
bir biyosorpsiyon kapasitesine sahip olduğu bulunmuştur. Biyosorpsiyon verisi
Langmuir tek tabaka izotermi ve yalancı ikinci derece kinetik model ile uyum
göstermiştir. pH 7’de yaprak tozunun biyosorpsiyon kapasitesi 122.0 mg g^-1
olarak bulunmuştur. Termodinamik analiz biyosorpsiyonun kendiliğinden
gerçekleştiğini ve endotermik yapıda olduğunu göstermiştir. 0.1 mol L^-1
HNO₃ çözeltisi ile tek kademede %97.17’lik desorpsiyon verimine
ulaşılmıştır. Biyosorbentin yüzey alanı ve ortalama por çapı sırasıyla 1.725 mg
g^-1 ve 1.75 nm olarak tespit edilmiştir. Biyosorpsiyonda rol almış olabilen
-CH, C-O, O-H, C=O ve COO- gibi kritik fonksiyonel gruplar kızıl ötesi
spektroskopisi ile aydınlatılmıştır. Sulu
çözeltilerden Eu(III) ayrılması ve kazanılmasında N. Tazetta yaprak tozunun etkili, maliyetsiz ve çevre dostu bir
biyosorbent olduğu sonucuna varılmıştır.

Anahtar Kelimeler

Narcissus Tazetta, Evropyum, Nadir Topraklar, Biyosorpsiyon, Ayırma

Biosorption of Eu(III) onto Narcissus Tazetta L. Leaf Powder

Öz

In the present study, biosorption
behaviours of novel biosorbent, Narcissus
Tazetta L. leaf powder, were investigated for the separation of Eu(III)
from aqueous solution. Batch experiments were conducted to examine the effect
of various parameters such as contact time, initial pH, initial Eu(III)
concentration, biosorbent dosage and temperature on the Eu(III) uptake. The
biosorption process is fast, and equilibrium was established in 30 min. of
contact time. It was found that the material has a significant biosorption
capacity for europium in the pH range of 4-7. The results showed that the biosorption
data fit Langmuir monolayer isotherm and pseudo-second order kinetic model
well. Biosorption capacity of leaf powder was obtained as 122.0 mg g^-1
at pH 7. Thermodynamic analysis indicates that the biosorption was spontaneous
and endothermic in nature. Desorption efficiency(%) of 97.17 was achieved in
single step using 0.1 mol L^-1 HNO₃ solution. Surface area
of the biosorbent and the average pore size were determined as 1.725 mg g^-1
and 1.75 nm, respectively. The critical functional groups -CH, C-O, O-H, C=O
and COO- which may have taken part for the biosorption were identified by
infrared spectra data. It was deduced that N.
Tazetta leaf powder can be used as an effective, costless, and eco-friendly
biosorbent for the separation and recovery of Eu(III) from aqueous solution.

Anahtar Kelimeler

Narcissus Tazetta, Europium, Rare Earths, Biosorption, Separation

Kaynakça

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