Bor Madeni ve Ensdüstriyel Uygulamaları

Öz

Doğada elemental olarak bulunmayan bor, yerkabuğunda yaygın olarak bulunur ve periyodik tablonun 5.elementidir. Yaklaşık 230 farklı bor mineralinin bulunduğu bilinmektedir ve farklı uygulamalarda bu çeşitlilik önemlidir. Türkiye, dünyadaki bor rezervlerinin en büyüğüne sahiptir. Buna ek olarak, Türkiye'nin bor mineralleri, diğer bor üreten ülkelere göre daha ekonomik olan en yüksek kalite ve üretim koşullarına sahiptir. Bu nedenle, bor ülkemiz için büyük önem taşır ve Türkiye'nin bu kaynaklarla ulusal ekonomiye katkıda bulunabilmesi için yeni kullanım alanlarına ve endüstrilerin oluşturulmasına yönelik önemli bir talep vardır. Mevcut bor rezervleri göz önüne alındığında, bor ile ilgili çevre dostu bir unsur olarak daha fazla araştırma ve geliştirme çalışmalarına duyulan ihtiyaç tüm endüstri dalları için açıktır. Türkiye'de bu amaçla BOREN (Ulusal Bor Araştırma Enstitüsü) kurulmuştur ve başta bu kuruluş olmak üzere dünya genelinde farklı çalışmalar yapılmıştır. Bu makale borun farklı disiplinlerde kullanımlarını ve bunları temel alarak yeni uygulama alanları oluşturulmasını amaçlamaktadır. Farklı sektörlerde bor uygulamalarının geliştirilmesi önemlidir.

Anahtar Kelimeler

• Bor
• Bor lifi
• Kompozit
• Bor minarelleri
• Bor bileşikleri

Boron and Industrial Applications

Abstract

Boron, which is not elemental in nature, is commonly found in the Earth's crust and is found in the 5th place of the periodic. About 230 different boron minerals are known to exist, and this diversity is important in different applications. Turkey has the largest boron reserves in the world. In addition, Turkey's boron minerals have the highest quality and production conditions, which are more economical than other boron producing countries. For this reason, boron is of great importance to our country and there is a significant demand for new uses and the creation of industries so that Turkey can contribute to the national economy with these resources. Given the existing boron reserves, the need for further research and development work as an environmentally friendly element related to boron is clear to all branches of industry. For this purpose, BOREN (National Boron Research Institute) was established in Turkey, and various studies have been conducted around the world, especially this organization. This article aims at the use of boron in different disciplines and the creation of new areas of application based on them. Developing boron applications in different sectors is important.

Keywords

• Boron
• Boron fiber
• Composite
• Boron minerals
• Boron compounds

Kaynakça

1. [1]. Sokmen N., Büyükakinci B. Y., The Use Of Boron / Boron Compounds In The Text Industry And Their Use In Turkey, Cbu International Innovation Conference Scıence And Educatıon, March 21-23, 2018, Prague, Czech Republic
2. [2]. Baker A., Dutton S., Kelly D., Composite Materials For Aircraft Structures, Properties Of Composite Systems, American Institute Of Aeronautics And Astronautics, Inc. 1801 Alexander Bell Drive, Reston, Va 20191-4344
3. [3]. Gelgeç, E., Yildirim, F. F., Tümru, Ş., Çerekcioğlu, M., Developing Flame Retardant Properties Of Cotton Factories With Boron Compounds, Mcbü Soma Profession School Of Technical Science Journal Of The Year: 2018 Issue: 26 Volume: II
4. [4]. Where Are Boron Mines Located And What Are Their Uses. (2020). Milliyet Newspaper (20.09.2020).
5. [5]. General Directorate Of Eti Mining Enterprises, Boron Sector Report, May 2020 Strategy Development Department
6. [6]. Y.F. Li, Z. Zhou, J. Zhou Journal of Chamical Physics, 127 (2007), p.184705
7. [7]. Hunter, H., Hassanin, A., Hamouda, T., Kılıç, A., A Review On The Current State Of Art And Future Problems, Journal Of The Faculty Of Engineering And Architecture Of Eskisehir Osmangazi University, HighPerformance Fibers: 27, 130-155, 2
8. [8]. Foltz, T. (2020). Business Development Director, Composites World, Specialty Materials, Boron Fiber: Original High Performance Fiber

9. [9]. M. Hagenbeek, C. Van Hengel, O.J. Bosker, G.A.J.R. Vermeeren Applied Composite Material, 10 (2003)pp. 207-222
10. [10]. Materials And Processes: Fibers For Composites. (2016, 17 March). Erişim adresi https://www.compositesworld.com/articles/the-fiber
11. [11]. Elmogahzy Y, Farag R (2018) Tensile Properties Of Cotton Fibers: Their İmportance, Research And Limitations. In: Handbook Of The Properties Of Textile And Technical Fibers, 2. Edn. Elsevier, P. 223-273
12. [12]. Horrocks Ar (1996) Advances İn Heat And Fire Resistant Flame Retardants Textiles— The Role Of Char Formation And İntumescence. Polym Degrad Stab 54(2–3):143–154
13. [13]. Xue C-H, Zhang L, Wei P, Jia S-T (2016) Fabrication Of Superhydrophobic Cotton Textiles With Flame Retardancy. Cellulose 23 (2):1471- 1480.
14. [14]. Qiu X, Li Z, Li X, Zhang Z (2017) Flame Retardant Coatings Prepared By Layer By Layer Assembly: A Review. Chem Eng J 334: 108-122
15. [15]. Ma Y, Cao C, Hou C (2018) Preparation Of Super-Hydrophobic Cotton Fabric With Crosslinkable Fluoropolymer. 477:955–962.
16. [16]. Tsafack Mj, Levalois-Grützmacher J (2006) Flame Retardancy Of Cotton Textiles By Plasmainduced Graft-Polymerization (Pıgp). Surf Coat Technol 201 (6): 2599-2610
17. [17]. Zhang D, Williams Bl, Shrestha Sb, Nasir Z, Becher Em, Lofink Bj, Santos Vh, Patel H, Peng X, Sun L (2017) Flame Retardant And Hydrophobic Coatings On Cotton Fabrics Via Sol–Gel And Selfassembly Techniques. J Colloid Interface Sci 505: 892-899. Https: / / Doi.Org/10.1016/J.Jcis.2017.06.087
18. [18]. Vasiljević J, Tomšič B, Jerman İ, Et Al. (2014) Novel Multifunctional Water-And Oilrepellent, Antibacterial, And Flameretardant Cellulose Fibers Created By The Sol–Gel Process. Cellulose 21(4): 2611-2623
19. [19]. Castellano A, Colleoni C, Iacono G, Et Al. (2019) Synthesis And Characterization Of A Phosphorous/Nitrogen Based Sol–Gel Coating As A Novel Halogen-And Formaldehyde-Free Flame Retardant Finishing For Cotton Fabric. Polym Gradient Stab 162:148-159
20. [20]. Luo X, Weng Y, Wang S, Et Al. (2019) Superhydrophobic And Oleophobic Textiles With Hierarchical Micro-Nano Structure Constructed By Sol–Gel Method. J Sol-Gel Sci Technol 89: 820- 829
21. [21]. Poly R, Colleoni C, Calvimontes A, Et Al. (2015) Innovative Sol–Gel Route İn Neutral Hydroalcoholic Condition To Obtain Antibacterial Cotton Finishing By Zinc Precursor. J Sol-Gel Sci Technol 74: 151-160
22. [22]. Camlibel No, Arik B (2017) Sol–Gel Applications İn Textile Finishing Processes. In: Recent Applications İn Sol–Gel Synthesis. Recent Appl Sol-Come Synth Intechopen Ltd Uk, Pp 253- 281
23. [23]. Rivero P, Goicoechea J (2016) Sol–Gel Technology For Antimicrobial Textiles. In: Antimicrobial Textiles. Elsevier, Cambridge, Pp 47-72.
24. [24]. Boukhriss A, Gmouh S, Hannach H, Roblin J-P, Cherkaoui O, Boyer D (2016) Treatment Of Cotton Fabrics By İonic Liquid With Pf6—Anion For Enhancing Their Flame Retardancy And Water Repellency. Cellulose 23 (5):3355-3364. Https://Doi.Org/10.1007 / S10570-016-1016-9
25. [25]. Bentis A, Boukhriss A, Grancaric Am, El Bouchti M, El Achaby M, Gmouh S (2019) Flammability And Combustion Behavior Of Cotton Fabrics Treated By The Left Gel Method Using İonic Liquids Combined With Different Anions. Cellulose
26. [26]. Boukhriss A, Boyer D, Hannache H, Roblin J-P, Mahiou R, Cherkaoui O, Therias S, Gmouh S (2015) Sol–Gel Based Water Repellent Coatings For Textiles. Cellulose 22 (2): 1415-1425
27. [27]. Bentis A, Boukhriss A, Boyer D, Gmouh S (2017) Development Of Flame Retardant Cotton Fabric Based On İonic Liquids Via Sol–Gel Technique. Iop Publishing, Uk, P 122001
28. [28]. Deh S, Gähr F, Buchmeiser Mr (2016) Synergistic Effects İn The Pyrolysis Of Phosphorus-Based Flame-Retardants: The Role Of Si-And N-Based Compounds. Polym Gradient Stab 130: 155-164
29. [29]. Rosace G, Castellano A, Trovato V, Et Al. (2018) Thermal And Flame Retardant Behavior Of Cotton Fabrics Treated With A Novel NitrogenContaining Carboxyl-Functionalized Organophosphorus System. Carbohydrin 196:348- 358
30. [30]. Axit A, Onar N, Kutlu B, Et Al. (2016) Synergistic Effect Of Phosphorus, Nitrogen And Silicon On Flame Retardancy Properties Of Cotton Fabric Treated By Sol–Gel Process. Int J Cloth Sci Technol 28: 319-327
31. [31]. Grancaric Am, Colleoni C, Guido E, Botteri L, Rosace G (2017) Thermal Behavior And Flame Retardancy Of Monoethanolaminedoped Sol–Gel Coatings Of Cotton Fabric. Prog Org Coat 103: 174-181
32. [32]. Zhang Q-H, Zhang W, Chen G-Q, Xing T (2015) Combustion Properties Of Cotton Fabric Treated By Boron Doped Silica Sol. Therm Sci 19: 1345-1348
33. [33]. Zhang Q, Gu J, Chen G, Xing T (2016) Durable Flame Retardant Finish For Silk Fabric Using Boron Hybrid Silica Sol. Appl Surf Sci 387: 446-453
34. [34]. Levan Sl, Tran Hc (1990) The Role Of Boron İn Flame-Retardant Treatments. In: First International Conference On Wood Protection With Diffusible Preservatives:... Nashville, Tennessee. Forest Products Research Society, Madison, Wı, Pp 39-41
35. [35]. Dogan Gbb (2018) Nano-Boron For Textiles. U.S. Patent Application No. 15/762,477
36. [36]. B. Walter Rosen, "Mechanics of Composite Strengthening," Fiber Composite Materials, American Society for Metals (1964).
37. [37]. N. J. Travis & E. J. Cocks, Tincal Trail, (Harrap Limited, London, 1984).
38. [38]. J. Steiner, Glastech. Ber. 66 (6/7) (1993), 165
39. [39]. J. Kunckel, Ars Vitraria Experimentalis (Frankfurt And Leipzig, 1679), Part I, P. 206; Part Iı P.57-9.
40. [40]. J. Cramer, Elementa Artis Documasticae (Leyden, 1739). English Translation Elements Of The Art Of Metal Analysis (London, 1741), P 440, N. 33.
41. [41]. R. E, Handmaid Ofthe Arts (London, 1796), New Edition, Vol N, Pp 171,188-9 Op. Fence. Proa Second Int. Conf. Glasses On Borates, Crystals And Melts 321
42. [42]. K. L. Loewenstein, Manufacturing Technology Of Continuous Glass Fibers, Glass Science And Technology 6, 3. Edition, (Elsevier 1993).
43. [43]. A. De Dani, Monthly Newsletter For The Glass Industry, C. E. Ramsden & Co. Co., 370 May (1965).
44. [44]. P. F. Aubourg & W W Wolf, İn: Commercial Glasses, Advances İn Ceramics Voll8, Eds. C. Boyd & J. F. Macdowell (Amer. Ceram S, Oc, Oh, İo, 1986), 51.
45. [45]. R. L. Tiede & F. V Tooley, Us Patent 2,571,074 (1951), Owens-Corning
46. [46]. U. E. Bowes, U. S. Patent 2,308,857 (1943), Owens-Corning
47. [47]. A. Krishna Chaitanya, Biplab Pal, Sajal Pati And Shrikant Badole, The Role And Management Of Boron In Plant Production, Popular Kheti, 2014
48. [48]. Çetinkaya, E., Dönmez, K. B., Deveci, S., Doğu, M., Şahin Y. (2014). Determination Of Plant Available Boron In Agricultural Soil By Using Voltammetric Method, Eurasian Soil Science
49. [49]. Tanaka M, Fujiwara T (2008) Physiological Roles And Transport Mechanisms Of Boron: Perspectives From Plants. Eur J Physiol
50. [50]. Goldbach He, Wimmer Ma (2007) Boron İn Plants And Animals: İs There A Role Beyond Cell Wall Structure? J Plant Nutr Soil Sci
51. [51]. Waqar Ahmad, A. Niaz, P. Kanwal, Rahmatullah And M. Khalid Rasheed, The Role Of Boron In Plant Growth: A Review, Journal Of Agricultural Research, January 2009
52. [52]. Kohorn Bd, Kobayashi M, Johansen S, Friedman Hp, Fischer A, Byers N (2006) WallBound Kinase 1 (Wak1) İs Cross-Linked İn Endomembranes And İts Transport To The Cell Surface Requires Accurate Cell Wall Synthesis. J Cell Sci
53. [53]. Barranco Wt, Eckhert Cd (2004) Boric Acid İnhibits Human Prostate Cancer Cell Proliferation. Cancer Lett
54. [54]. Ryden P, Sugimoto-Shirasu K, Smith Ac, Findlay K, Reiter Wd, Mccann Mc (2003) Tensile Properties Of Arabidopsis Cell Walls, And Ksilogluka Cross-Linked Borate Complex Depends On Both The Network Mikrofibri Ramnogalakturonan Iı. Plant Physiol
55. [55]. Brown Ph, Bellaloui N, Wimmer Ma, Bassil Es, Ruiz J, Hu H, Pfeffer H, Dannel F, Römheld V (2002) Boron İn Plant Biology. Plant Biol 4
56. [56]. Ma, Ishii T, Albersheim P, Darvill Ag (2004) Rhamnogalacturonan Iı: Structure And Function Of Borate Cross-Linked Cell Wall Pectic Polysaccharide. Ann Rev Plant Biol
57. [57]. Noguchi K, Ishii T, Matsunaga T, Kakegawa K, Hayashi H, Fujiwara T (2003) Biochemical Properties Of The Cell Wall İn Boridopsis Mutant Bor1–1. J Plant Nutr Soil Sci
58. [58]. Ishii T, Matsunaga T, Iwai H, Satoh S, Taoshita J (2002) Germanium Does Not Replace Boron İn The Crosslinking Of Ramnogalacturonan Iı İn Pumpkin Cell Walls. Plant Physiol
59. [59]. O'neill M, Eberhard S, Albersheim P, Darvill A (2001) Borate Cross-Binding Of Cell Wall Ramnogalacturonan Iı For Arabidopsis Growth.
60. [60]. Goldbach He, Yu Q, Wingender R, Schulz M, Wimmer M, Fineklee P, Baluska F (2001) Rapid Response Reactions To Boron Absence Of Roots. J Plant Nutr Soil Sci 164
61. [61]. Ozturk, M., Sakcali, S., Gucel, S., and Tombuloglu, H., Boron And Plants, March 2010
62. [62]. M. Saleem1, P.M. Khanif, C.I. Fauziah, A.W. Samsuri And B. Hafeez1, Efficiency Of Crushed Ore Colemanite As Boron Fertilizer For Rice Grown Under Calcareous Soil Conditions, Pak. J. Pain. Sci., Vol. 50(1), 37-42; 2013
63. [63]. Sahin, S. (2014). Effect Of Boron Fertilizer Applications On The Growth And B, N Uptake Of Maize (Zea Mays L.)) Under The Different Soils, Journal Of Food, Agriculture & Environment Vol.12 (2): 1323-1327.
64. [64]. Hosakere Shivanna Kumaraswamy1*, Vinjamuri Bharat2, T. Krishna Rao2, Effect Of Boron Fiber Powder And Graphite Supplements On Physical And Mechanical Properties Of Aluminum 2024 Alloy Manufactured By Mixing Casting, Journal Of Minerals And Materials Characterization And Engineering, 2019, 7, 103-116
65. [65]. N. Brack 1,, A. N. Rider2, B. Halstead 1 And P. J. Pigram 1, Surface Modification Of Boron Fibers To Increase Strength In Composite Materials, J. Adhesion Sci. Technol., V.Be. 19, No. 10, P. 857- 877 (2005)
66. [66]. Fatih Euphrates, Gas Phase Reaction Requirements For A Master's Degree İn Chemistry İn Boron Fiber Production, Partially Engıneerıng, June 2004
67. [67]. Sturwold, RJ. Cincinnati-Vulcan Co., U.S. Patent, 4,675,125, 1987.
68. [68]. 1998 The Soap and Detergent Association, Boron
69. [69]. Jy Huang And Yt Zhu, "Advances İn The Synthesis And Characterization Of Boron Nitride" Defect And Diffusion Forum, Vol. 186-187, No. 1, 2000, Pages 1-32.
70. [70]. Wj Yu, Wm Lau, Sp Chan, Zf Liu, And Qq Zheng, "Ab İnitial Study Of Phase Transformations İn Boron Nitride," Physical Review B, Vol. 67, No. 1, 2003, P. 14108-14116. Doi: 10.1103 / Physrevb.67.014108
71. [71]. Y. Chen, M. Conway, J. S. Williams, And J. Zou," Large Quantity Production Of High-Yield Boron Nitride Nanotubes", Journal Of Materials Research, Vol. 17, No. 8, 2002, P. 1896-1899. Doi: 10.1557 / Jmr.2002.0281
72. [72]. C. Zhi, Y. Marching Band, C. Tang And D. Golberg," Boron Nitride Nanotubes, " Materials Science And Engineering R, Vol. 70, No. 3-6, 2010, P. 92-111. Doi: 10.1016 / J.Mser.2010.06.004
73. [73]. S. Komatsu, Y. Shimizu, Y. Moriyoshi, K. Okada And M. Mitomo," Preparation Of Boron Nitride Nanocapsules By Plasma-Assisted Pulsed Laser Deposition, " Journal Of Applied Physics, Vol. 91, No. 9, 2002, P. 6181-6184. Doi: 10.1063 / 1.1461889 [Citation Time: 1]
74. [74]. T. Read, M. Kuno And H. Kitahara," Formation, Atomic Structures And Properties Of Boron Nitride And Carbon Nanosage Fullerene Materials, " Internacional Journal Of Inorganic Materials, Vol. 7, 2001, Page 597-612. Doi: 10.1016 / S1466-6049 (01) 00169-6
75. [75]. P. Dibandjo, L. Bois, F. Chassagneux And P. Miele," Thermal Stability Of Mesogespecific Boron Nitride Template With Cationic Surfactant", Journal Of The European Ceramic Society, Vol. 27, No. 1, 2007, P. 313-317. Doi: 10.1016 / J.Jeurceramsoc2006.04.178 [Citation Time: 1]
76. [76]. Ly Chen, Yi Gu, L. Shi, Zh Yang, Jh Ma, And Yt Qian, "Room Temperature Approach To Boron Nitride Hollow Spheres", Solid State Communication, Vol. 130, No. 8, 2004, P. 537-540. Doi: 10.1016 / J.Ssc.2004.03.009 [Citation Time: 1] 10.1007 / S13233-010-0601-2 [Citation Time: 1]
77. [77]. H. J. Hwang, Nam Barakat, Ma Kanjwal, Fa Sheikh And Hy Kim, "Boron Nitride Nonofibers With Electrospinning Technique," Macromolecular Research, Vol. 18, No. 6, 2010, P.551-557. Doi: 10.1007 / S13233-010-0601-2 [Citation Time: 1]
78. [78]. Rs Galleoncu," Bn Powder Synthesis At Low Temperatures " Ceramic Engineering And Science Proceedings, Vol. 6, No. 9-10, 1985, P. 1356-1363. Doi: 10.1002 / 9780470320297. Ch18 [Citation Time: 1]
79. [79]. L. Gao And J. Li," Preparation Of Nanostructured Hexagonal Boron Nitride Powder", Journal Of The American Ceramic Society, Vol. 86, No. 11, 2003, P. 1982-1984. Doi: 10.1111 / J.1151- 2916.2003.Tb03596.X [Citation Duration: 1]
80. [80]. J. E Costa And E. Lascaz," Fotoprotetores " Medicina Cutánea Ibero-Latino Americana A, Vol. 29, No. 3, 2001, P. 145-152. [Citation Time: 1]
81. [81]. Lh Kligman," İntensification Of Ultravioletİnduced Skin Damage By İnfrared Radiation, " Archives Of Dermatological Research, Vol. 272, No. 3-4, 1982, Pp. 229-238. Doi: 10.1007 / Bf00509050 Doi: 10.1007 / Bf00509050 [Citation Period: 1]
82. [82]. S. Cho, Mh Shin, Yk Kim, Je Seo, Ym Lee, Ch Park, And Jh Chung, "Effects Of İnfrared Radiation And Heat On Human Skin Aging İn Vivo", Journal Of Investigative Dermatology Symposium Proceedings, Vol. 14, No. 1, 2009, P. 15-19. Doi: 10.1038 / Jidsymp.2009.7
83. [83]. C. Calles, M. Schneider, F. Macaluso, T. Benesova, J. Krutmann And P. Schroeder," An İnfrared Radiation Affects Skin Fibroblast Transcriptoma: Mechanisms And Results, " Journal Of Investigative Dermatology, Vol. 130, No. 6, 2010, P. 1524-1536. Doi: 10.1038 / Jid.2010.9
84. [84]. Sm Schieke, P. Schroeder And J. Krutmann," Cutaneous Effects Of Infrared Radiation: From Clinical Observations To Molecular Response Mechanisms, " Photodermatology Photoimunology & Photomedicine, Vol. 19, No. 5, 2003, P. 228-234. Doi: 10.1034 / J.1600-0781.2003.00054.X [Citation Duration: 2]
85. [85]. J. Flor, M. R. Davolos And M. A. Correa, "Protetores Solares," Química Nova, Vol. 30, No. 1, 2007, P. 153-158. Doi: 10.1590 / S0100- 40422007000100027 [Citation Period: 1]
86. [86]. Ansell, JM, Ito, K. Report for International Cooperation of Cosmetic Regulation. Associations Survey of Nanomaterials Used in Cosmetic Products. 2011.
87. [87]. Devrian Ta, Volpe Sl (2003) Physiological Effects Of Dietary Pipe. Crit Rev Food Sci 43
88. [88]. Ricardo A, Carrigan Ma, Olcott An, Benner Tu (2004))
89. [89]. Naghii MR, Samman S. The effect of boron supplementation on its urinary excretion and selected cardiovascular risk factors in healthy male subjects. Biol Trace Elem Res. 1997;56(3):273–286.
90. [90]. Smith Ra, Mcbroom Rb (2000) Boron Oxides, Boric Acid And Borates. Kirk-Othmer Chemical Tecnology Encyclopedia
91. [91]. Mogoşanu Gd, Biţă A, Bejenaru Le, Bejenaru C, Croitoru O, Rău G, Rogoveanu Oc, Florescu Dn, Neamţu J, Scorei Id, Scorei Rı (2016) Calcium Fructoborate For Bone And Cardiovascular Health. Biol Trace Elem Res
92. [92]. Kurtoğlu F, Kurtoğlu V, Celik I, Kececi T, Nizamlioğlu M (2005) Adequate Or İnsufficient Cholecalciferol (Vitamin D3) Content Of Dietary Boron Supplements. Br Poult Sci
93. [93]. Kabu M, Civelek T (2012) Effects Of Propylene Glycol, Methionine And Sodium Borate On Metabolic Profile During Periparturient Period İn Dairy Cattle. Rev Med Vet 163 (8): 419-430
94. [94]. Haseeb K, Wang J, Xiao K, Yang Kl, Sun Pp, Wu Xt, Song H, Liu Hz, Zhong Jm, Peng Km (2017) Effects Of Boron Supplementation On Hsp70 Expression İn The Spleen Of African Ostrich
95. [95]. Nielsen Fh, Shuler Tr (1992) Studies On The İnteraction Between Boron And Calcium İn Rats And İts Modification By Magnesium And Potassium.
96. [96]. Volpe Sl, Taper Lj, Meacham S (1993) The Relationship Between Boron And Magnesium Status İn Humans And Bone Mineral Density: A Review. Magnes Res
97. [97]. Ghanizadeh G, Babaei M, Naghii Mr, Mofid M, Torkaman G, Hedayati M (2014) The Effect Of İncreased İntake Of Calcium, Vitamin D, Boron And Fluoride On Bone Mechanical Properties And Metabolic Hormones İn Rats. Toxicol Ind Health 30
98. [98]. Zanka T, Sigler K (2008) Biologically Active Compounds Of Semi-Metals. Breeder Nat
99. [99]. Chen X, Schauder S, Potier N, Van Dorsselaer A, Pelezer I, Bassler Bl, Hughson Fm (2002) Structural İdentification Of A Boron-Containing Bacterial Majority Detection Signal.
100. [100]. Amine Sa, Kupper Fc, Green Dh, Harris Wr, Carrano Cj (2007) Boron Binding By A Siderophore İsolated From Marine Bacteria Associated With The Toxic Dinoflagellate Gymnodinium Catenatum. J Am Chem Soc
101. [101]. Bolanos L, Lukaszewski K, Bonilla I, Blevins D (2004) Why Bor? Plant Physiol Biochemistry
102. [102]. Wolkenstein K, Gross Jh, Falk H (2010) Boron-Containing Organic Pigments From Jurassic Red Algae. Proc Natl Acad Sci
103. [103]. Miwa K, Fujiwara T (2010) Boron Transport İn Plants: Coordinated Regulation Of Shippers.
104. [104]. Ahmed I, Yokota A, Fujiwara T (2007) A New High Boron-Tolerant Bacterium, Bacillus Boroniphilus Sp. November, İsolated From Soil, Requiring Boron To Grow. Extremophiles 11
105. [105]. Bolaños L, Redondo-Nieto M, Bonilla İ, Wall Lg (2002) Boron İn The Symbiotic Relationship Of Discaria Trinervis (Rhamnaceae) And Frankia . Frankia Bcu110501 Growth And İts İmportance For Nitrogen Fixation
106. [106]. Bolaños L, Redondo-Nieto M, Rivilla R, Brewin Nj, Bonilla I (2004) Cell Surface İnteractions Of Rhizobium Bacteroids And Other Bacterial Strains With Symbiosomal And Peribacteroid Membrane Components From Pea Nodules. Mol Plant-Microbe Interact
107. [107]. Bonilla I, Garcia-González M, Mateo P (1990) Possible Role Of Boron İn The Early Evolution Of Photosynthetic Organisms İn Cyanobacteria.
108. [108]. Hunt Cd (2003) Dietary Boron: An Overview Of The Evidence For İts Role İn İmmune Function. J Trace Elem Exp Med
109. [109]. Moustafa Sr (2015) Clinical Relationship Between Boron, Caesium, Rhenium And Rubidium Changes And The Pathogenesis Of Atherosclerosis.
110. [110]. Söğüt I, Paltun So, Tuncdemir M, Ersoz M, Hurdag C (2017) Antioxidant And Anti-Apoptotic Effect Of Boric Acid On Hepatoxicity İn Chronic Alcohol-Fed Plasterers. Can J Physiol Pharmacol
111. [111]. Coates Pm, Blackman M, Betz Jm, Cragg Gm, Levine Ma, Moss J, White Jd (2010) Boron: İn The Encyclopedia Of Dietary Strategies.
112. [112]. Nielsen F. H. (2008). Is Boron Nutritionally Relevant? Nutrition Reviews® Vol. 66(4):183–191 183, https://doi.org/10.1111/j.1753-4887.2008.00023.x
113. [113]. Henderson K, Stella Sl, Kobylewski S, Eckhert Cd (2009) Receptor-Active Ca (2+) Sale İs İnhibited By Boric Acid İn Prostate Cancer Cells. Plos
114. [114]. Willow I, Capricorn A, Kartkaya K, Ol Kk, Willow Ms, Kanbak G, Inal Me (2015) The Effect Of Boric Acid On Oxidative Stress İn Fetal Alcohol Syndrome. Experiment Med 9
115. [115]. Üstündağ A, Behm C, Follmann W, Duydi Y, Degen Gh (2014) Protective Effect Of Boric Acid On Lead And Cadmium-İnduced Genotoxicity İn V79 Cells. Arch Toxicol 88
116. [116]. Çoban Fk, Ince S, Küçükkurt I, Demirel Hh, Hazman O (2015) Boron Reduces Malathionİnduced Oxidative Stress And Acetylcholinesterase İnhibition İn Blades. Drug Chem Toxicol 38
117. [117]. Ince S, Keles H, Erdoğan M, Hazman O, Küçükkurt I (2012) Protective Effect Of Boric Acid Against Carbon Tetrachloride-İnduced Hepatotoxicity İn Mice. Drug Chem Toxicol 35
118. [118]. Ince S, Küçükkurt I, Liğerci Ih, Fatih Fa, Eryavuz A (2010) Effects Of Dietary Boric Acid And Borax Tactics On Lipid Peroxidation, Antioxidant Activity And Dna Damage İn Ra